{"id":8869,"date":"2023-04-04T01:14:22","date_gmt":"2023-04-03T17:14:22","guid":{"rendered":"https:\/\/www.andrewsun.net\/panta_rhei\/?p=8869"},"modified":"2023-04-04T01:18:13","modified_gmt":"2023-04-03T17:18:13","slug":"%e7%94%b1%e4%b8%80%e4%bb%bd%e7%ae%80%e5%8e%86%e7%9a%84%e8%81%94%e6%83%b3","status":"publish","type":"post","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/8869","title":{"rendered":"\u7531\u4e00\u4efd\u7b80\u5386\u7684\u8054\u60f3"},"content":{"rendered":"
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\u6211\u770b\u5230\u4e00\u7bc7\u8bba\u6587<\/a>\uff0c\u89c9\u5f97\u4e0e\u6211\u7684\u7814\u7a76\u5341\u5206\u76f8\u5173\uff0c\u4e8e\u662f\u60f3\u627e\u627e\u770b\u4f5c\u8005Grigori Medvedev\u662f\u8c01\uff0c\u751a\u81f3\u8003\u8651\u5728\u65b9\u4fbf\u7684\u5951\u673a\u7ed9\u4ed6\u53d1\u5c01\u90ae\u4ef6\u3002\u7ed3\u679c\u53d1\u73b0\uff0c\u4ed6\u7684\u7b80\u5386<\/a>\u672c\u8eab\u900f\u9732\u51fa\u6765\u7684\u7ecf\u5386\u5c31\u5f88\u6709\u610f\u601d\u3002<\/p>\n\n\n\n

\u4ed6\u662f\u5728\u524d\u82cf\u8054\u5b8c\u6210\u535a\u58eb\u5b66\u4f4d\u7684\u3002\u5728\u5b66\u672f\u751f\u6daf\u7684\u521d\u671f\u78b0\u5230\u4e86\u82cf\u8054\u89e3\u4f53\u3002\u4ed6\u5148\u53bb\u4e86\u6ce2\u5170\u4e24\u5e74\uff0c\u7136\u540e\u5230\u4e86\u7f8e\u56fd\u7684\u666e\u6e21\u5927\u5b66\uff0c\u4efb\u804c\u81f3\u4eca\u3002<\/p>\n\n\n\n

\u4ed6\u535a\u58eb\u671f\u95f4\u662f\u5728\u4fc4\u7f57\u65af\u81ea\u7136\u79d1\u5b66\u9662\u9ad8\u5206\u5b50\u7269\u8d28\u7814\u7a76\u6240\uff08Institute of High-Molecular Compounds, Russian Academy of Sciences\uff09\uff0c\u5b66\u4f4d\u8bba\u6587\u9898\u76ee\u662f\u6db2\u6676\u805a\u5408\u7269\u7684\u677e\u5f1b\u8fc7\u7a0b\uff0c\u5bfc\u5e08\u662fYu Ya Gotlib\u3002<\/p>\n\n\n\n

\u663e\u7136\uff0cMedvedev\u7684\u80cc\u666f\u662f\u504f\u5411\u9ad8\u5206\u5b50\u7269\u7406\u7684\u3002\u4ed6\u7684\u5bfc\u5e08Gotlib\u672c\u4eba\u5728Amazon\u4e0a\u53ef\u4ee5\u641c\u5230\u4e00\u672c\u4e66\uff0c\u9898\u76ee\u662fMolecular Mobility and Order in Polymer Systems<\/em>\uff0c\u4e0eMedvedev\u7684\u535a\u58eb\u5b66\u4f4d\u8bba\u6587\u4e3b\u9898\u51e0\u4e4e\u76f8\u540c\u3002Gotlib\u7684\u65e9\u671f\u5de5\u4f5c\uff0c\u53ef\u4ee5\u5728Google Scholar\u7684\u641c\u7d22\u7ed3\u679c\u4e2d\u7aa5\u89c1\u4e00\u6591\u3002\u4ece\u8bba\u6587\u7684\u6700\u65e9\u5e74\u4efd\u6765\u770b\uff0cGotlib\u7684\u5b66\u672f\u751f\u6daf\u5927\u6982\u5f00\u59cb\u4e8e1950\u5e74\u4ee3\uff0c\u4e00\u5f00\u59cb\u5c31\u7814\u7a76\u9ad8\u805a\u7269\u3002\u6211\u80fd\u627e\u5230\u4ed6\u6700\u65e9\u53d1\u8868\u7684\u8bba\u6587\u662f1953\u5e74\u5728ZHURNAL TEKHNICHESKOI FIZIKI<\/em>\uff08\u82f1\u8bed\u8bd1\u4e3aJournal of Technical Physics\uff09\u4e0a\u7684\u9898\u4e3aTEORIYA RELAKSATSIONNOGO SPEKTRA POLIMERNOI TSEPOCHKI<\/em>\uff08\u805a\u5408\u7269\u94fe\u7684\u5f1b\u8c6b\u8c31\u7406\u8bba\uff09\u7684\u5de5\u4f5c\u3002\u4ed6\u662f\u7b2c\u4e00\u4f5c\u8005\uff0c\u7b2c\u4e8c\u4f5c\u8005\u662fM. V. Volkenstein\u3002<\/p>\n\n\n\n

\u4e0d\u5931\u516c\u5e73\u5730\u53ef\u4ee5\u8bf4Volkenstein\u6bd4\u66f4\u8457\u540d\u4e9b\uff0c\u4f46\u53ef\u80fd\u4eca\u5929\u7684\u9ad8\u5206\u5b50\u5b66\u8005\u4e5f\u672a\u5fc5\u4e86\u89e3\u4e86\u3002Volkenstein\u7406\u5e94\u8457\u540d\uff0c\u56e0\u4e3aFlory\u5728\u8bfa\u8d1d\u5c14\u5956\u7f51\u7ad9\u4e0a\u7684\u81ea\u8ff0\u4e2d\u5c31\u63d0\u5230\uff0c\u4ed6\u7684\u5de5\u4f5c\u5efa\u7acb\u5728Volkenstein\u7684\u57fa\u7840\u4e0a\u7684\u3002Volkenstein\u5728\u952e\u6784\u8c61\u7edf\u8ba1\u65b9\u9762\u7684\u5de5\u4f5c\uff0c\u6bd4Flory\u5f00\u5c55\u5f97\u65e9\u3002Flory\u7684\u4e13\u8457Statistical Mechanics of Chain Molecules<\/em>\u51fa\u7248\u540e\uff0cVolkenstein\u5728Biopolymers<\/em>\u4e0a\u53d1\u8868\u4e86\u4e66\u8bc4<\/a>\uff0c\u89c1\u8bc1\u4e86\u4e24\u4e2a\u5de8\u4eba\u7684\u4ea4\u6d41\u3002\u76f8\u4fe1\u8fd9\u662f\u8fd9\u4e2a\u4eca\u5929\u5c11\u6709\u4eba\u77e5\u5374\u6e0a\u6e90\u6df1\u8fdc\u7684\u671f\u520a\u4e0a\u4e3a\u6570\u4e0d\u5c11\u7684\u9ad8\u5149\u65f6\u523b\u4e4b\u4e00\u3002<\/p>\n\n\n\n

\u5728\u8fd9\u91cc\u6211\u63d2\u4e00\u53e5\u3002\u4ece\u6211\u7684\u89c2\u5bdf\u6765\u770b\uff0c\u6211\u6000\u7591\uff0c\u8bb8\u591a\u4eba\u5e76\u6ca1\u6709\u770b\u8fc7Flory\u7684\u90a3\u672cStatistical Mechanics of Chain Molecules<\/em>\u5c31\u53bb\u5f15\u7528\u3002\u8fd9\u672c\u4e66\u6709\u5341\u5206\u72ec\u7acb\u4e14\u4eca\u5929\u7f55\u89c1\u7684\u4e3b\u65e8\uff0c\u662f\u8d85\u51fa\u4e86\u4e00\u822c\u9ad8\u5206\u5b50\u7269\u7406\u6559\u79d1\u4e66\u4e2d\u7684\u94fe\u7edf\u8ba1\u7ae0\u8282\uff08\u5305\u62ecFlory\u672c\u4eba\u7684\u53e6\u4e00\u66f4\u4e3a\u6d41\u884c\u7684\u8457\u4f5cPrinciple of Polymer Chemistry<\/em>\uff09\u6240\u5173\u5fc3\u7684\u8303\u7574\u7684\u3002Flory\u5728Statistical ~<\/em>\u8fd9\u672c\u4e66\u4e2d\u4e3a\u4e86\u5b9e\u73b0\u4ed6\u6240\u4e0d\u540c\u4e8eKuhn\u7684\u7406\u8bba\u76ee\u6807\uff0c\u4f7f\u7528\u4e86\u5c11\u89c1\u4e8e\u5e38\u89c4\u6559\u79d1\u4e66\u7684\u6570\u5b66\u5de5\u5177\u3002\u6709\u65f6\u95f4\u6211\u518d\u53e6\u5916\u5199\u4e00\u7bc7\u4e1c\u897f\u6765\u804a\u804a\u8fd9\u4ef6\u4e8b\u3002<\/p>\n\n\n\n

\u4f46\u65e0\u5eb8\u7f6e\u7591\uff0c\u8fd9\u672c\u4e66\u6b63\u9762\u5f15\u7528\u4e86\u4e0d\u5c11Volkenstein\u7684\u5de5\u4f5c\uff0c\u4f7f\u540e\u8005\u5341\u5206\u5f00\u5fc3\u3002<\/p>\n\n\n\n

\u4e4b\u6240\u4ee5\u8bf4\u671f\u520aBiopolymers\u6709\u4e0d\u5c11\u9ad8\u5149\u65f6\u523b\uff0c\u662f\u56e0\u4e3a\u5b83\u6df1\u5ea6\u53c2\u4e0e\u4e86\u9ad8\u5206\u5b50\u7269\u7406\u7406\u8bba\u53d1\u5c55\u53f2\u7684\u4e3b\u7ebf\uff0c\u5f88\u591a\u91cd\u8981\u7684\u9ad8\u5206\u5b50\u7269\u7406\u57fa\u672c\u95ee\u9898\uff0c\u662f\u7269\u7406\u5b66\u5bb6\u5728\u7814\u7a76\u751f\u7269\u5927\u5206\u5b50\u7684\u65f6\u5019\u78b0\u5230\u7684\uff0c\u5f53\u65f6\u4ed6\u4eec\u628a\u8fd9\u4e9b\u5de5\u4f5c\u53d1\u8868\u5728\u4e86Biopolymers\uff0c\u540e\u6765\u6210\u4e3a\u4e86\u91cd\u8981\u7684\u666e\u9002\u7406\u8bba\u3002Volkenstein\u672c\u4eba\u5c31\u5341\u5206\u5173\u6ce8\u751f\u7269\u5927\u5206\u5b50\u3002\u4ed6\u505a\u7406\u8bba\u65f6\u5fc3\u91cc\u60f3\u7740\u7684\u5e94\u7528\u662f\u751f\u7269\u5927\u5206\u5b50\u3002<\/p>\n\n\n\n

\u4fc4\u7f57\u65af\u4eba\u7684\u8bba\u6587\u6709\u4e00\u4e2a\u7279\u70b9\uff0c\u5c31\u662f\u5341\u5206\u6ce8\u610f\u7a81\u51fa\u4fc4\u56fd\u79d1\u5b66\u5bb6\u5728\u4e16\u754c\u79d1\u5b66\u53d1\u5c55\u4e2d\u7684\u8d21\u732e\u3002\u4f8b\u5982\uff0c\u9ad8\u5206\u5b50\u4ea4\u8054\u7f51\u7edc\u7684\u6eb6\u80c0\u70ed\u529b\u5b66\u7684Flory-Rehner\u7406\u8bba\uff0c\u4f1a\u6539\u4e3aFrenkel-Flory-Rehner\u7406\u8bba\u3002Volkenstein\u5728\u8c08\u5230de Gennes\u7684\u6807\u5ea6\u7406\u8bba\u65f6\uff0c\u4e5f\u63d0\u5230\u4e86I. Lifshitz\uff08\u662f\u5199\u6559\u79d1\u4e66\u7684\u90a3\u4f4dE. Lifshitz\u7684\u5f1f\u5f1f\uff09\u5728\u8fd9\u65b9\u9762\u4e5f\u662f\u5148\u9a71\u3002Lifshitz\u57281978\u5e74\u53d1\u8868\u5728Rev. Mod. Phys.\u4e0a\u7684\u7efc\u8ff0\u63d0\u5230\u201c\u7528\u4e8c\u7ea7\u76f8\u53d8\u7684\u601d\u8def\u6765\u5904\u7406\u6392\u9664\u4f53\u79ef\u201d\uff0c\u4ee5\u53ca\u201cglobule\u201d\u7684\u6982\u5ff5\u3002\u5982\u679c\u5305\u62ec\u4fc4\u8bed\u4e16\u754c\uff0c\u90a3\u4e48Lifshitz\u65e9\u57281968\u5e74\u5c31\u63d0\u51fa\u8fd9\u4e9b\u4e86\uff0c\u6bd4de Gennes\u7684Scaling concepts<\/em>\u90a3\u672c\u4e66\u8981\u65e9\u3002Lifshitz\u5bf9\u9ad8\u5206\u5b50\u4f53\u7cfb\u7684\u5174\u8da3\u59cb\u4e8e1960\u5e74\uff0c\u4e5f\u662f\u4ece\u751f\u7269\u5927\u5206\u5b50\u5207\u5165\u7684\u3002\u9274\u4e8eLifshitz\u5bf9\u82cf\u8054\u51dd\u805a\u6001\u7269\u7406\u53d1\u5c55\u7684\u5f71\u54cd\uff0c\u4ed6\u5207\u5165\u9ad8\u5206\u5b50\u7269\u7406\u7684\u89d2\u5ea6\uff0c\u4e5f\u8bb8\u4e5f\u6df1\u6df1\u4e86\u5f71\u54cd\u4e86\u82cf\u8054\u9ad8\u5206\u5b50\u7814\u7a76\u540e\u7eed\u7684\u5174\u8da3\u7279\u70b9\u3002<\/p>\n\n\n\n

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\u6240\u4ee5\uff0c\u5f88\u53ef\u80fdLifshitz\u548cVolkenstein\u548cGotlib\u90fd\u8ddf\u6211\u56fd\u9ad8\u5206\u5b50\u524d\u8f88\u76f8\u8bc6\uff0c\u751a\u81f3\u6709\u5bc6\u5207\u4ea4\u6d41\uff0c\u56e0\u4e3a\u4ece\u6211\u521a\u624d\u7684\u8ffd\u6eaf\u53ef\u89c1\uff0c\u8fd9\u4e09\u4eba\u5728\u5f53\u65f6\u4ee3\u8868\u4e86\u82cf\u8054\u9ad8\u5206\u5b50\u5b66\u79d1\u7684\u8001\u3001\u4e2d\u3001\u9752\u4e09\u4ee3\u3002<\/p>\n\n\n\n

\u6709\u4e00\u672c\u4e66\u53eb\u300a\u82cf\u8054\u79d1\u5b66\u5bb6\u5728\u4e2d\u56fd\u300b\u4f5c\u8005\u6070\u597d\u4e5f\u662f\u5316\u5b66\u5bb6\uff0c\u4e3b\u8981\u641e\u65e0\u673a\u5316\u5b66\u7684\u3002\u8fd9\u672c\u4e66\u751f\u52a8\u5730\u5c55\u793a\u4e86\u4ece\u5171\u548c\u56fd\u5efa\u7acb\u52301960\u5e74\u671f\u95f4\uff0c\u6211\u56fd\u79d1\u5b66\u7814\u7a76\u7684\u72b6\u51b5\u2014\u2014\u4e3b\u8981\u662f\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u7684\u72b6\u51b5\u3002\u4f46\u662f\uff0c\u5728\u90a3\u4e2a\u671f\u95f4\uff0c\u8fd9\u4e2a\u4e2d\u56fd\u5316\u5b66\u7684\u6700\u6838\u5fc3\u7814\u7a76\u5355\u4f4d\u4e5f\u6b63\u5728\u4f5c\u9ad8\u5206\u5b50\u5b66\u79d1\u65b9\u9762\u7684\u5927\u578b\u6253\u7b97\uff0c\u8fd9\u662f\u6ca1\u6709\u5728\u8fd9\u672c\u4e66\u4e2d\u4f53\u73b0\u7684\u3002\u603b\u4e4b\u4e3a\u4e86\u8fd9\u4e2a\u9879\u76ee\uff0c1960\u5e74\uff0c\u4ee5\u94b1\u4fdd\u529f\u5148\u751f\u5f53\u7ec4\u957f\uff0c\u8fd8\u6709\u90dd\u67cf\u6797\u5148\u751f\u53c2\u52a0\u7684\u4e00\u4e2a\u9ad8\u5206\u5b50\u7269\u7406\u8003\u5bdf\u5c0f\u7ec4\uff0c\u88ab\u4e2d\u79d1\u9662\u6d3e\u5230\u82cf\u8054\u8bbf\u95ee\u3002<\/p>\n\n\n\n

\n

\u5728\u5217\u5b81\u683c\u52d2\u5927\u5b66\u90dd\u67cf\u6797\u89c1\u5230\u4e86\u5bf9\u9ad8\u5206\u5b50\u6784\u8c61\u7edf\u8ba1\u6709\u7a81\u51fa\u8d21\u732e\u7684\u751f\u7269\u7269\u7406\u5b66\u5bb6\u6c83\u80af\u65af\u5766\uff08M. V. Volkenstein\uff09\u2026\u2026\u3002<\/p>\n\u5f20\u6dd1\u8a89\u300a\u90dd\u67cf\u6797\u2014\u2014\u79d1\u5b66\u6e38\u51fb\u6218\u58eb\u300b<\/cite><\/blockquote>\n\n\n\n

\u539f\u672c\uff0c\u90dd\u67cf\u6797\u662f\u51c6\u5907\u7ee7\u7eed\u8fdb\u519b\u9ad8\u5206\u5b50\u79d1\u5b66\u7684\u3002\u4ed6\u548c\u540c\u65f6\u4eec\u4ece\u4fc4\u6587\u7ffb\u8bd1\u4e86\u5361\u5c14\u91d1\uff08V. A. Kargin\uff0c\u4eca\u5929\u7684\u4fc4\u56fd\u9ad8\u5206\u5b50\u5316\u5b66\u548c\u6280\u672f\u7814\u7a76\u6240\u4ee5\u4ed6\u7684\u59d3\u6c0f\u547d\u540d\uff09\u548c\u65af\u6d1b\u5c3c\u59c6\u65af\u57fa\uff08G. L. Slonimsky\uff09\u8d60\u7ed9\u7684\u300a\u9ad8\u805a\u7269\u7269\u7406\u5316\u5b66\u6982\u8bba\u300b\u4e00\u4e66\u3002\u94b1\u4eba\u5143\u5148\u751f\u4e5f\u7ed9\u8fc7\u8bb8\u591a\u6307\u5bfc\u3002\u4f46\u5f88\u5feb\u4ed6\u5c31\u88ab\u6d3e\u5f80\u82cf\u8054\u505a\u7814\u7a76\u751f\uff0c\u4ed6\u901a\u8fc7\u4e86\u6717\u9053\u80fd\u5792\u6d4b\u8bd5\uff0c\u4f46\u6210\u4e3a\u4e86\u963f\u5e03\u91cc\u79d1\u7d22\u592b\u5b66\u751f\uff0c\u5b66\u91cf\u5b50\u573a\u8bba\u4e86\u3002Volkenstein\u5728\u7814\u7a76\u751f\u6daf\u7684\u540e\u671f\u8fdb\u5165\u5230\u4e86\u751f\u7269\u4fe1\u606f\u5b66\u9886\u57df\uff0c\u65e0\u72ec\u6709\u5076\u90dd\u67cf\u6797\u4e5f\u5982\u6b64\u3002\u9ad8\u5206\u5b50\u7269\u7406\u7684\u65e9\u671f\u7ecf\u5386\uff0c\u4e5f\u8bb8\u662f\u4e00\u4e2a\u666e\u9002\u6027\u7684\u8bf1\u56e0\u3002<\/p>\n\n\n\n

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\u6211\u8fd9\u4e48\u8054\u60f3\u5e76\u975e\u51ed\u7a7a\u7684\u3002\u6bd4\u5982\uff0cVolkenstein\u7684\u94fe\u7edf\u8ba1\u7406\u8bba\uff0c\u66f4\u503e\u5411\u4e8e\u628a\u5316\u5b66\u4fe1\u606f\u5305\u62ec\u8fdb\u6765\uff0c\u5411\u7269\u7406\u4e0a\u7684\u96be\u5ea6\u6311\u6218\u3002\u5728\u8fd9\u4e00\u6218\u6597\u4e2d\uff0cVolkenstein\u4f5c\u51fa\u4e86\u4f18\u79c0\u7269\u7406\u5b66\u5bb6\u5e38\u6709\u7684\u806a\u660e\u8054\u60f3\u6765\u89e3\u51b3\u95ee\u9898\u3002Flory\u5341\u5206\u8d4f\u8bc6\u8fd9\u4e00\u70b9\u3002\u4ed6\u5728\u81ea\u5df1\u7684\u94fe\u7edf\u8ba1\u8457\u4f5c\u7684\u524d\u8a00\u91cc\uff0c\u66f4\u4e3a\u6e05\u695a\u5730\u89e3\u91ca\u4e86\uff0c\u4e3a\u4ec0\u4e48\u8981\u4e0d\u60dc\u514b\u670d\u7e41\u7410\u7684\u6570\u5b66\uff0c\u975e\u8981\u5b9e\u73b0\u4e00\u79cd\u7eb3\u5165\u5316\u5b66\u7ed3\u6784\u7ec6\u8282\u7684\u7269\u7406\u7ed3\u679c\u3002Flory\u7684\u8fd9\u7bc7\u524d\u8a00\uff0c\u9053\u51fa\u4e86\u6c9f\u901a\u5316\u5b66\u5bb6\u89c6\u89d2\u4e0e\u7269\u7406\u5b66\u5bb6\u89c6\u89d2\u4e4b\u96be\u3002\u4e0eVolkenstein\u548cFlory\u7684\u5b66\u672f\u54c1\u4f4d\u76f8\u53cd\u7684\uff0c\u662fKuhn\u548cde Gennes\u7684\uff0c\u5ffd\u7565\u7ec6\u8282\u7684\u3001\u91cd\u6574\u5316\u7684\u505a\u6cd5\u3002\u5f88\u591a\u4eba\u8ba4\u4e3a\uff0c\u540e\u9762\u8fd9\u7c7b\u505a\u6cd5\u201c\u66f4\u7269\u7406\u201d\uff0c\u56e0\u800c\u66f4\u9ad8\u7ea7\u3002Volkenstein\u548cFlory\u7684\u94fe\u7edf\u8ba1\u5de5\u4f5c\uff0c\u73b0\u5728\u51e0\u4e4e\u53ea\u6709\u80fd\u4e0eKuhn\u548cde Gennes\u7684\u5de5\u4f5c\u76f8\u878d\u7684\u90e8\u5206\u5f97\u4ee5\u5ef6\u7eed\uff1b\u4ed6\u4eec\u72ec\u7279\u7684\u52aa\u529b\u53ea\u7559\u5728\u4e86\u6545\u7eb8\u5806\u3002\u6211\u5728\u6700\u8fd1\u51e0\u5e74\u7ecf\u5e38\u8ddf\u8eab\u8fb9\u7684\u4eba\u8bf4\uff0c\u6211\u559c\u6b22Flory\uff0c\u4e0d\u559c\u6b22de Gennes\uff0c\u5e76\u975e\u620f\u8a00\u6216\u5984\u8a00\uff0c\u800c\u662f\u6709\u7740\u660e\u786e\u800c\u96be\u4ee5\u5c3d\u8ff0\u7684\u7406\u7531\u3002Flory\u66f4\u503e\u5411\u4e8e\u7eb3\u5165\u5316\u5b66\u5bb6\u8bed\u5883\u7684\u4fe1\u606f\u5230\u81ea\u5df1\u7684\u7406\u8bba\u5f53\u4e2d\uff08\u201c\u66f4\u5316\u5b66\u201d\uff09\uff0c\u5e76\u6ca1\u6709\u635f\u5931\u4ed6\u7684\u7269\u7406\u6027\u800c\u900a\u8272\u4e8e\u540e\u4eba\uff0c\u53cd\u800c\u4f53\u73b0\u4e86\u7269\u7406\u5b66\u7684\u5a01\u529b\u3002\u5982\u679c\u8981\u5ffd\u7565\u4fe1\u606f\u3001\u91cd\u6574\u5316\u624d\u80fd\u7ee7\u7eed\u4e0b\u53bb\uff0c\u82e5\u4e0d\u662f\u7269\u7406\u5b66\u7684\u65e0\u80fd\uff0c\u90a3\u5c31\u662f\u4eba\u7684\u65e0\u80fd\u3002<\/p>\n\n\n\n

<\/p>\n\n<\/div> ","protected":false},"excerpt":{"rendered":"

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V. 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Fujita\uff0c1922\u5e744\u670810\u65e5\u20142007\u5e743\u670828\u65e5\uff0c\u56fe1\uff09\u3002\u6211\u56fd\u9ad8\u5206\u5b50\u754c\u5bf9\u4ed6\u4e0d\u719f\u6089\uff0c\u56e0\u4e3a\u4ed6\u51fa\u8eab\u4e8e\u975e\u5e73\u8861\u70ed\u529b\u5b66\u9886\u57df\uff0c\u65e9\u57281986\u5e74\u5c31\u9000\u4f11\u4e0d\u518d\u53c2\u52a0\u5b66\u672f\u6d3b\u52a8\u4e86\uff08\u6ca1\u6709\u7ecf\u8d39\uff09\uff0c\u4e5f\u6ca1\u6709\u6765\u8fc7\u4e2d\u56fd\uff0c\u4e0e\u6211\u56fd\u5b66\u8005\u7684\u4ea4\u96c6\u5f88\u5c11\u3002\u85e4\u7530\u6559\u6388\u662f1942\u5e744\u6708\u8003\u5165\u65e5\u672c\u4eac\u90fd\u5927\u5b66\uff08\u5f53\u65f6\u7684\u5e1d\u56fd\u5927\u5b66\uff09\u7269\u7406\u5b66\u79d1\u7684\uff0c\u5f53\u65f6\u5904\u4e8e\u6218\u4e89\u65f6\u671f\uff0c\u5927\u5b66\u5b66\u5236\u4ece\u539f\u6765\u76843\u5e74\u7f29\u77ed\u52302\u5e74\u534a\uff0c\u6700\u540e1\u5e74\u8981\u8fdb\u5165\u4e00\u4e2a\u7814\u7a76\u5ba4\uff08\u65e5\u672c\u79f0\u4e3a\u201c\u8bb2\u5ea7\u201d\uff09\u5728\u6559\u6388\u6307\u5bfc\u4e0b\u53c2\u52a0\u5b66\u4e60\u548c\u79d1\u7814\u3002\u4ed6\u9009\u62e9\u4e86\u6d41\u4f53\u529b\u5b66\u7684\u7814\u7a76\u5ba4\uff0c1944\u5e749\u6708\uff08\u65e5\u672c\u7684\u5b66\u5e74\u6b63\u5e38\u60c5\u51b5\u4e0b\u662f\u57283\u6708\u5e95\u7ed3\u675f\uff09\u4eac\u90fd\u5927\u5b66\u7269\u7406\u5b66\u672c\u79d1\u6bd5\u4e1a\u83b7\u5f97\u7406\u5b66\u5b66\u58eb\u5b66\u4f4d\u3002\u65e5\u672c\u653f\u5e9c\u4e3a\u50a8\u5907\u5e74\u8f7b\u5de5\u7a0b\u5e08\u548c\u79d1\u5b66\u5bb6\u8bbe\u7acb\u4e86\u6218\u65f6\u201c\u7279\u522b\u7814\u7a76\u751f\u201d\uff0c\u7531\u653f\u5e9c\u63d0\u4f9b\u5956\u5b66\u91d1\u548c\u4eab\u6709\u514d\u4e8e\u88ab\u5f81\u5175\u7684\u7279\u6743\uff0c\u85e4\u7530\u5148\u751f\u88ab\u9009\u4e3a\u7279\u522b\u7814\u7a76\u751f\u5f97\u4ee5\u7ee7\u7eed\u4ece\u4e8b\u6d41\u4f53\u529b\u5b66\u7684\u8ba1\u7b97\u5de5\u4f5c\u3002\u56e0\u4e3a\u6d41\u4f53\u529b\u5b66\u548c\u7a7a\u6c14\u52a8\u529b\u5b66\u7684\u7814\u7a76\u53ef\u80fd\u5e2e\u52a9\u65e5\u672c\u590d\u5174\u822a\u7a7a\u5de5\u4e1a\uff0c1946\u5e74\u6218\u8d25\u540e\u7684\u65e5\u672c\u4e0d\u88ab\u5141\u8bb8\u4ece\u4e8b\u6d41\u4f53\u529b\u5b66\u9886\u57df\u7684\u7814\u7a76\u5de5\u4f5c\u3002\u7ecf\u8fc7\u534a\u5e74\u5e2e\u52a9\u7236\u4eb2\u52a1\u519c\u540e\uff0c\u85e4\u7530\u5148\u751f\u5230\u79c1\u7acb\u7acb\u547d\u9986\u5927\u5b66\u7684\u524d\u8eab\u517c\u4efb\u8bb2\u5e08\u30021948\u5e74\u8d77\u4efb\u4eac\u90fd\u5927\u5b66\u519c\u5b66\u90e8\u6c34\u4ea7\u5b66\u79d1\u52a9\u624b\u3001\u526f\u6559\u6388\uff0c\u5f00\u59cb\u4e86\u65e0\u4eba\u6307\u5bfc\u7684\u81ea\u7531\u63a2\u7d22\u3002\u9c7c\u5e72\u662f\u65e5\u672c\u4eba\u7684\u4f20\u7edf\u98df\u7269\uff0c\u4ed6\u5c31\u4ece\u9c7c\u7684\u5e72\u71e5\u5f00\u59cb\u4e86\u975e\u7ebf\u6027\u6269\u6563\u7684\u7814\u7a76\u30021953\u5e74\u85e4\u7530\u5148\u751f\u4ee5\u5173\u4e8e\u6269\u6563\u548c\u70ed\u4f20\u5bfc\u975e\u7ebf\u6027\u95ee\u9898\u7684\u8bba\u6587\u83b7\u5f97\u4eac\u90fd\u5927\u5b66\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\uff08\u4ed6\u575a\u6301\u7528Dr. Sci.\u800c\u4e0d\u662fPh.D.\uff09\u3002\u90a3\u65f6\uff0c\u65e5\u672c\u7684\u5927\u5b66\u6ca1\u6709\u7814\u7a76\u751f\u9662\uff0c\u535a\u58eb\u5b66\u4f4d\u4e0d\u662f\u901a\u8fc7\u4e0a\u5b66\u83b7\u5f97\u7684\uff0c\u800c\u662f\u4f5c\u4e3a\u5bf9\u7814\u7a76\u6210\u679c\u7684\u5956\u52b1\u83b7\u5f97\u7684\uff0c\u8981\u51ed\u53d1\u8868\u7684\u8bba\u6587\u6765\u7533\u8bf7\u3002\u8bf4\u4ed6\u81ea\u5b66\u6210\u6750\u662f\u56e0\u4e3a\u5411\u65e5\u672c\u7684\u5927\u5b66\u7533\u8bf7\u535a\u58eb\u5b66\u4f4d\u9700\u8981\u4e00\u4f4d\u6559\u6388\u6765\u4ecb\u7ecd\uff0c\u6c34\u4ea7\u5b66\u79d1\u6ca1\u6709\u4eba\u80fd\u591f\u7406\u89e3\u4ed6\u7684\u6210\u679c\u3002\u73b0\u5728\u79f0\u8fd9\u7c7b\u535a\u58eb\u4e3a\u201c\u8bba\u6587\u535a\u58eb\u201d\u3002\u4e8c\u6218\u540e\u65e5\u672c\u7684\u5927\u5b66\u624d\u5efa\u7acb\u7814\u7a76\u751f\u9662\uff08\u65e5\u8bed\u79f0\u201c\u5927\u5b66\u9662\u201d\uff09\uff0c\u5b66\u751f\u5728\u6559\u6388\u7684\u6307\u5bfc\u4e0b\u5b66\u4e60\u548c\u7814\u7a76\u4e00\u5b9a\u7684\u5e74\u6570\uff0c\u64b0\u5199\u8bba\u6587\u7533\u8bf7\u7855\u58eb\u6216\u535a\u58eb\u5b66\u4f4d\uff0c\u79f0\u4e3a\u201c\u8bfe\u7a0b\u535a\u58eb\u201d\u3002\u4ece1954\u5e74\u8d77\uff0c\u85e4\u7530\u5148\u751f\u591a\u6b21\u8d74\u8377\u5170\u3001\u7f8e\u56fd\u6e38\u5b66\u3001\u4efb\u6559\uff0c\u5f00\u5c55\u4e86\u8d85\u901f\u79bb\u5fc3\u5206\u6790\u7684\u57fa\u7840\u7814\u7a76\u3002\u53d1\u6325\u4e86\u4ed6\u5728\u6c42\u89e3\u6269\u6563\u65b9\u7a0b\u65b9\u9762\u7684\u7279\u957f\uff0c\u89e3\u51b3\u4e86\u6269\u6563\u7cfb\u6570\u548c\u6c89\u964d\u7cfb\u6570\u5177\u6709\u7684\u6d53\u5ea6\u4f9d\u8d56\u6027\u65f6\u5bf9\u6eb6\u8d28\u6c89\u964d\u8fb9\u754c\u533a\u57df\u5f62\u72b6\u7684\u5b9a\u91cf\u5f71\u54cd\uff0c\u5148\u540e\u51fa\u7248\u4e86\u4e24\u672c\u8d85\u901f\u79bb\u5fc3\u5206\u6790\u9886\u57df\u7684\u7ecf\u5178\u8457\u4f5c\uff1a\u201cMathematical Theory of Sedimentation Analysis\u201d\u00a0Academic Press 1962\u548c\u201cFoundations of Ultracentrifugal Analysis\u201dWiley-Interscience 1975\u3002\uff08H. Fujita, \u201cThe initial step in my science career\u201d,\u00a0Comprehensive Biochemistry, 2000, 41, 275\uff09\uff0c\u8fd8\u5efa\u7acb\u4e86Fujita--Doolittle equation\u3002 1961\u5e74\u65e5\u672c\u4ece\u7f8e\u56fdWisconsin\u5927\u5b66\u5f15\u8fdb\u85e4\u7530\u535a\u58eb\u5230\u5927\u962a\u5927\u5b66\uff0c\u62c5\u4efb\u9ad8\u5206\u5b50\u5b66\u79d1\u9ad8\u5206\u5b50\u6eb6\u6db2\u7406\u8bba\u8bb2\u5ea7\u7684\u6559\u6388\u3002\u65e5\u672c\u7684\u5927\u5b66\u662f\u8bb2\u5ea7\u5236\uff0c\u6bcf\u4e2a\u8bb2\u5ea7\u90fd\u6709\u7279\u5b9a\u7684\u5b66\u79d1\u65b9\u5411\uff0c\u4e00\u822c\u7f16\u5236\u662f1\u4f4d\u6559\u6388\u30011\u4f4d\u526f\u6559\u6388\u30012\u4f4d\u52a9\u624b\u3002\u8bb2\u5ea7\u662f\u4e00\u4e2a\u5751\u4e00\u4e2a\u841d\u535c\uff0c\u4e0d\u4f1a\u51fa\u73b0\u4e00\u4e2a\u9ad8\u5206\u5b50\u5b66\u79d1\u6709\u4e24\u4f4d\u6559\u6388\u5728\u540c\u4e00\u4e2a\u7814\u7a76\u65b9\u5411\u7684\u60c5\u51b5\u3002\u73b0\u5728\u5927\u962a\u5927\u5b66\u3001\u4eac\u90fd\u5927\u5b66\u90fd\u5c062~3\u4e2a\u8bb2\u5ea7\u5408\u5e76\u79f0\u4e3a\u201c\u5927\u8bb2\u5ea7\u201d\uff0c\u589e\u52a0\u4e86\u526f\u6559\u6388\u7684\u7f16\u5236\u6570\u800c\u51cf\u5c11\u4e86\u52a9\u624b\u7684\u7f16\u5236\u6570\u3002\u6559\u6388\u9000\u4f11\u540e\u8be5\u8bb2\u5ea7\u7684\u5b66\u79d1\u65b9\u5411\u53ef\u80fd\u88ab\u7ec8\u6b62\uff0c\u90a3\u6837\u526f\u6559\u6388\u3001\u52a9\u624b\u90fd\u8981\u53e6\u5bfb\u51fa\u8def\u3002\u4e3a\u4e86\u5411\u56fd\u5916\u4ecb\u7ecd\u65e5\u672c\u7684\u9ad8\u5206\u5b50\u7814\u7a76\uff0c\u85e4\u7530\u6559\u6388\u529b\u63a8\u5c06\u65e5\u672c\u7684\u300a\u9ad8\u5206\u5b50\u5b66\u62a5\u300b\u6539\u4e3a\u82f1\u8bed\u7684Polymer Journal\uff0c\u5728\u540c\u9f84\u4eba\u4e2d\u4ed6\u7684\u82f1\u8bed\u6700\u597d\uff0c\u4eb2\u4efb\u4e3b\u7f16\u76f4\u5230\u4ed6\u9000\u4f11\u3002\u6bcf\u5e74\u4ed6\u8981\u5ba1\u7a3f\u7ea680\u7bc7\u6587\u7a3f\uff0c\u90a3\u65f6\u6ca1\u6709\u7535\u8111\u3001\u7f51\u7edc\uff0c\u5168\u9760\u6253\u5b57\u673a\u3001\u90ae\u5bc4\u4fe1\u4ef6\uff0c\u6bcf\u5929\u5348\u996d\u540e\u90fd\u4f1a\u4ece\u4e00\u697c\u6536\u53d1\u5ba4\u62ff\u56de\u4e0d\u5c11\u7a3f\u4ef6\u3002\u7b2c\u4e00\u8981\u52a1\u662fpolish\u82f1\u8bed\uff0c\u8981\u8ba9native speaker\u80fd\u8bfb\u660e\u767d\uff0c\u5012\u662f\u6ca1\u6709\u4eca\u65e5\u201c\u5f71\u54cd\u56e0\u5b50\u201d\u7684\u70e6\u607c\u3002\u4ed6\u8fd8\u62c5\u4efb\u8fc7J.Polym. Sci.\u548cAdv. Polym. Sci.\u7684\u7f16\u8f91\u3002\u90a3\u65f6\u65e5\u672c\u5173\u897f\u5730\u533a\u7684\u56fd\u7acb\u5927\u5b66\u662f3\u6708\u5e95\u6ee163\u5c81\u5c31\u8981\u9000\u4f11\uff08\u73b0\u5728\u6539\u4e3a65\u5c81\u4e86\uff09\uff0c\u85e4\u7530\u6559\u63881986\u5e744\u6708\u4ece\u5927\u962a\u5927\u5b66\u9000\u4f11\u3002 \u9000\u4f11\u4ee5\u540e\u4ed6\u7684\u613f\u671b\u662f\u53d1\u8868\u4ee5\u5bb6\u5ead\u5730\u5740\u4e3a\u901a\u8baf\u5730\u5740\u7684\u7814\u7a76\u8bba\u6587\uff0c1988\u5e74\u548c1993\u5e74\u5728Macromolecules\u4e0a\u53d1\u8868\u4e86\u4e24\u7bc7\u8bba\u6587\uff08Macromolecules\u00a01988, 21,179;\u00a0Macromolecules\u00a01993, 26, 643\uff0c\u56fe2\uff09\uff0c2000\u5e74\u8fd8\u5728J. Phys. Chem.\u53d1\u8868\u4e86\u7535\u89e3\u8d28\u5728\u6c34\u4e2d\u6269\u6563\u7684\u8bba\u6587\uff08J. Phys. Chem. 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