{"id":6765,"date":"2015-12-04T03:25:20","date_gmt":"2015-12-03T19:25:20","guid":{"rendered":"http:\/\/www.andrewsun.net\/panta_rhei\/?p=6765"},"modified":"2020-01-01T20:24:24","modified_gmt":"2020-01-01T12:24:24","slug":"%e8%89%b0%e9%9a%be%e7%9a%84%e8%ae%ba%e6%96%87%e5%8f%91%e8%a1%a8%e4%b9%8b%e8%b7%af","status":"publish","type":"post","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/6765","title":{"rendered":"\u8270\u96be\u7684\u8bba\u6587\u53d1\u8868\u4e4b\u8def"},"content":{"rendered":"
\n

\u53c8\u4e00\u4efd\u5de5\u4f5c\u53d1\u8868\u4e86[1]<\/a><\/span>\u3002\u8fd9\u7bc7\u8bba\u6587\u5176\u5b9e\u662f\u63a5\u7740\u4e0a\u4e00\u7bc7\u5de5\u4f5c[2]<\/a><\/span>\u7684\u7ee7\u7eed\u3002\u6709\u4eba\u8bf4\uff0c\u81ea\u5df1\u7684\u8bba\u6587\uff0c\u53d1\u8868\u4e4b\u540e\u5c31\u4e0d\u60f3\u91cd\u770b\u4e86\u3002\u80fd\u591f\u53d1\u8868\u503c\u5f97\u81ea\u5df1\u80af\u5b9a\u7684\u8bba\u6587\uff0c\u90fd\u4e0d\u662f\u5bb9\u6613\u7684\u4e8b\u60c5\uff0c\u66f4\u4e0d\u7528\u8bf4\u8ba9\u522b\u4eba\u80af\u5b9a\u4e86\u3002\u54ea\u6015\u662f\u5982\u6b64\u65e0\u8da3\u7684\u5de5\u4f5c\uff0c\u6211\u7684publication rate\u4e5f\u7279\u522b\u4f4e\uff0c\u56e0\u4e3a\u6bcf\u4e00\u7bc7\u8bba\u6587\uff0c\u6211\u90fd\u5e0c\u671b\u63a8\u8fdb\u4e00\u6b65\uff0c\u800c\u6211\u57fa\u7840\u6bd4\u8f83\u8584\u5f31\uff0c\u8fd9\u63a8\u8fdb\u7684\u4e00\u6b65\u5f80\u5f80\u662f\u4ece\u8865\u4e60\u57fa\u672c\u77e5\u8bc6\u5f00\u59cb\uff1a\u5148\u5b66\u4e60\u57fa\u672c\u7406\u8bba\u7684\u76f8\u5173\u6559\u79d1\u4e66\u4e86\u89e3\u4e00\u822c\u7684\u60c5\u51b5\uff0c\u7136\u540e\u770b\u76f8\u5173\u7684\u6587\u732e\u4e86\u89e3\u8ddf\u6211\u7684\u95ee\u9898\u63a5\u8fd1\u7684\u60c5\u51b5\uff0c\u7136\u540e\u518d\u8003\u8651\u6211\u7684\u9700\u8981\u53d1\u8868\u7684\u95ee\u9898\u3002\u5982\u679c\u6211\u6bcf\u7bc7\u8bba\u6587\u90fd\u53ea\u6709\u5f53\u524d\u7684\u77e5\u8bc6\u7684\u7406\u89e3\uff0c\u90a3\u6211\u5c31\u4f1a\u66f4\u52a0\u5728\u6bd4\u8f83\u6e23\u7684\u6c34\u5e73\u4e0a\u505c\u6b65\u4e0d\u524d\u3002\u5728\u8fd9\u91cc\uff0c\u6211\u4e0d\u6015\u522b\u4eba\u7b11\u8bdd\u6211\u57fa\u7840\u6c34\u5e73\u66fe\u7ecf\u6709\u591a\u5dee\uff0c\u7b80\u5355\u8bb0\u5f55\u4e00\u4e0b\u6211\u600e\u4e48\u4ece\u83dc\u9e1f\u8d70\u8fc7\u6765\u7684\u3002\u5c06\u6765\u4e5f\u4f1a\u4e00\u76f4\u8d70\u4e0b\u53bb\u3002<\/p>\n

\u535a\u58eb\u751f\u671f\u95f4\u4ece\u96f6\u5f00\u59cb\u5b66\u4e60\u6d41\u53d8\u5b66\u4e4b\u540e\u8fdb\u884cLAOS\u7814\u7a76\u7684\u7ecf\u5386\uff0c\u5c31\u4e0d\u63d0\u4e86\u3002\u62112012\u5e74\u7684\u90a3\u7bc7J. Colloid Interf. Sci.<\/em>[3]<\/a><\/span>\uff0c\u662f\u6211\u53c2\u52a0\u5de5\u4f5c\u540e\u53d1\u8868\u7684\u7b2c\u4e00\u7bc7\uff08\u5f53\u7136\u662f\u535a\u58eb\u671f\u95f4\u7684\u5de5\u4f5c\uff09\u3002\u5b9e\u9a8c\u4e0a\u53ea\u662f\u5b66\u4eba\u5bb6\u5df2\u7ecf\u505a\u51fa\u6765\u7684\u7ed3\u679c\uff0c\u591a\u52a0\u4e86\u4e00\u4e2a\u6761\u4ef6\uff0c\u91cd\u590d\u4e86\u4e00\u6b21\u73b0\u8c61\uff0c\u5373Laponite\u51dd\u80f6\u5316\u7684\u52a8\u529b\u5b66\u66f2\u7ebf\u6709\u53e0\u52a0\u6027\u3002\u4f46\u662f\u4e3a\u4e86\u7406\u89e3\u5b83\uff0c\u6211\u627e\u4e86\u4e00\u4e9b\u8bba\u6587\uff0c\u53d1\u73b0\u8fd9\u7684\u786e\u662f\u53ef\u4ee5\u7531\u6a21\u578b\u9884\u6d4b\u7684\uff0c\u5c31\u5728\u5b9e\u9a8c\u7ed3\u679c\u62a5\u9053\u4e4b\u540e\u7eed\u4e86\u4e00\u4e2a\u6a21\u578b\u8ba1\u7b97\u3002<\/p>\n

\u5176\u5b9e\u5982\u679c\u4ece\u66f4\u9ad8\u7684\u54c1\u4f4d\u6765\u770b\uff0c\u6240\u6709\u80fd\u7531\u7ecf\u5178\u6a21\u578b\u7b80\u5355\u9884\u6d4b\u51fa\u6765\u7684\u73b0\u8c61\uff0c\u4e0d\u7b97\u4ec0\u4e48\u65b0\u53d1\u73b0\u3002\u56e0\u4e3a\u6240\u8c13\u7ecf\u5178\u5c31\u662f\u6307\u65e9\u5df2\u88ab\u63a5\u53d7\u7684\u6a21\u578b\uff0c\u5b9e\u9a8c\u7b26\u5408\u7684\u4f8b\u5b50\u4e5f\u8bb8\u5df2\u7ecf\u6709\u6210\u5343\u4e0a\u4e07\u4e86\uff0c\u4f60\u518d\u4e3e\u4e00\u4e2a\u4e5f\u5c31\u53ea\u662f\u7b2c\u4e00\u4e07\u96f6\u4e00\u3002\u9664\u975e\u4f60\u662f\u63d0\u51fa\u5b83\u7684\u53cd\u4f8b\uff08\u4e5f\u5f88\u96be\uff09\u53ef\u80fd\u624d\u6bd4\u8f83\u5f15\u4eba\u5173\u6ce8\u3002\u4e0d\u53ef\u9006\u805a\u96c6\u7684\u6a21\u578b\u7684\u7814\u7a76\u65e9\u5c31\u63d0\u51fa\u4e86\u4e0d\u7ba1\u662f\u4e8c\u805a\u8fd8\u662fN\u805a\u90fd\u53ef\u7528\u4e00\u4e2a\u53cd\u5e94\u901f\u7387\u5e38\u6570\u63cf\u8ff0\u7684\u60c5\u51b5\uff0c\u76f8\u5f53\u4e8e\u9884\u6d4b\u4e86\u52a8\u529b\u5b66\u66f2\u7ebf\u6709\u53e0\u52a0\u6027\u3002\u6211\u7528\u4e0d\u53ef\u9006\u805a\u96c6\u7684\u6a21\u578b\u8ba1\u7b97\u7ed3\u679c\u4e0e\u5b9e\u9a8c\u7ed3\u679c\u6bd4\u8f83\u4e00\u4e0b\uff0c\u53ea\u80fd\u8bf4\u660eLaponite\u51dd\u80f6\u5316\u662f\u4e00\u4e2a\u4e0d\u53ef\u9006\u805a\u96c6\u6210cluster\u7f51\u7edc\u7684\u8fc7\u7a0b\u3002<\/p>\n

\u4f46\u5c31\u4e3a\u8fd9\u4ef6\u4e8b\uff0c\u6211\u91cd\u5934\u5b66\u4e60\u4e86\u5982\u4f55\u63cf\u8ff0\u7c92\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u52bf\u80fd\u51fd\u6570\uff0c\u5305\u62ecDLVO\u52bf\u7684van der Waals\u4f5c\u7528\u52bf\u548c\u53cc\u7535\u5c42\u4f5c\u7528\u52bf\u3002\u66f4\u9ebb\u70e6\u7684\u5176\u5b9e\u662f\u8868\u9762\u5438\u9644\u805a\u5408\u7269\u5206\u5b50\u7684\u80f6\u4f53\u7c92\u5b50\uff0c\u805a\u5408\u7269\u94fe\u6392\u65a5\u7684\u8fd9\u90e8\u5206\u6548\u5e94\u3002\u8fd9\u4e2a\u6548\u5e94\u7684\u8ba1\u7b97\u5f0f\u9700\u8981\u77e5\u9053\u805a\u5408\u7269\u5c42\u7684\u7b49\u6548\u539a\u5ea6\u3002\u4ee5\u524d\u7684\u62a5\u9053\u5e94\u7528\u6b64\u5f0f\u65f6\u5f80\u5f80\u901a\u8fc7DLS\u6d4b\u91cf\u7c92\u5f84\u6216\u8005\u5176\u4ed6\u5404\u79cd\u6d4b\u91cf\u5438\u9644\u91cf\u7684\u529e\u6cd5\u6765\u8ba1\u7b97\u5438\u9644\u539a\u5ea6\uff0c\u800c\u8fd9\u4e9b\u65b9\u6cd5\u90fd\u4e0d\u9002\u7528\u4e8e\u6211\u7814\u7a76\u7684\u80f6\u4f53\u7c92\u5b50\uff08\u592a\u5c0f\u4e86\uff0c\u79bb\u5fc3\u4e0d\u51fa\u6765\uff1b\u53c8\u975e\u5e38\u5bb9\u6613\u805a\u96c6\uff0cDLS\u96be\u4ee5\u6d4b\u5230\u5355\u7c92\u5b50\u4fe1\u53f7\uff09\u3002\u53e6\u4e00\u6761\u8def\u662f\u7406\u8bba\u8ba1\u7b97\u3002\u805a\u5408\u7269\u5728\u7403\u8868\u9762\u4ee5\u5916\u7684\u5e73\u8861\u94fe\u5bc6\u5ea6\u5206\u5e03\u51fd\u6570\u9700\u8981\u901a\u8fc7\u94fe\u7edf\u8ba1\u6765\u89e3\u51fa\u3002\u4e3a\u6b64\u6211\u53bb\u56fe\u4e66\u9986\u501f\u9605\u4e86Fleer\u7b49\u4eba\u8457\u7684Polymers at Interfaces<\/em><\/a>\u5b66\u4e60\u8868\u9762\u9ad8\u5206\u5b50\u94fe\u7edf\u8ba1\u3002\u672c\u6765\u60f3\u76f4\u63a5\u901a\u8fc7\u94fe\u7edf\u8ba1\u6765\u8ba1\u7b97\u51fa\u8fd9\u4e2a\u539a\u5ea6\u7684\uff0c\u4f46\u5177\u4f53\u5b66\u4e60\u53d1\u73b0\u8fd9\u4e2a\u6d89\u53ca\u5230\u4e00\u4e2a\u9012\u5f52\u7684\u7b97\u6cd5\uff0c\u4ee5\u5f53\u65f6\u6211\u7684\u6570\u5b66\u548c\u7f16\u7a0b\u6c34\u5e73\u8fd8\u662f\u65e0\u6cd5\u89e6\u78b0\uff0c\u53ea\u597d\u81ea\u5df1\u60f3\u51fa\u4e00\u4e2a\u7b80\u5355\u7684\u8fd1\u4f3c\u5047\u8bbe\uff0c\u8bd5\u8bd5\u770b\u7ed3\u679c\u4e5f\u543b\u5408\uff0c\u5c31\u8fd9\u4e48\u8fc7\u53bb\u4e86\u3002\u73b0\u5728\u60f3\u60f3\u770b\u8fd9\u4e2a\u597d\u50cf\u662f\u5c0fcase\uff0c\u53cd\u5012\u6709\u70b9\u8822\u8822\u6b32\u52a8\u60f3\u56de\u8fc7\u5934\u53bb\u7b97\u7b97\uff0c\u53ef\u60dc\u6ca1\u8fd9\u95f2\u529f\u592b\uff0c\u4f46\u53ef\u89c1\u4e00\u4e2a\u4eba\u80fd\u529b\u7684\u63d0\u9ad8\uff0c\u5176\u89e6\u89d2\u548c\u89c6\u91ce\u4f1a\u6269\u5927\u5f88\u591a\uff0c\u8fd9\u662f\u540e\u8bdd\u3002<\/p>\n

\u5f97\u5230\u52bf\u80fd\u51fd\u6570\u4e4b\u540e\uff0c\u9a6c\u4e0a\u9762\u4e34\u7b2c\u4e8c\u4e2a\u96be\u5173\uff1a\u5f53\u65f6\u6211\u751a\u81f3\u4e0d\u61c2\u4f7f\u7528MATLAB\u8fdb\u884c\u7b80\u5355\u7684\u6570\u503c\u8ba1\u7b97\uff0c\u800c\u4e0d\u53ef\u9006\u805a\u96c6\u6a21\u578b\u9700\u8981\u4ece\u76f8\u4e92\u4f5c\u7528\u52bf\u80fd\u51fd\u6570\u79ef\u5206\u5f97\u5230\u7a33\u5b9a\u6bd4\uff0c\u5bf9\u4e8e\u590d\u6742\u7684\u52bf\u80fd\u51fd\u6570\u53ea\u80fd\u6570\u503c\u79ef\u5206\u4e00\u4e0b\u3002\u4e8e\u662f\u6211\u5b66\u4e60\u4f7f\u7528MATLAB\uff0c\u7ec8\u4e8e\u6b63\u786e\u5730\u5f97\u5230\u79ef\u5206\u7ed3\u679c\u3002<\/p>\n

\u6295\u7a3f\u4e4b\u540e\uff0c\u53c8\u6709\u5ba1\u7a3f\u4eba\u8d28\u7591\u6211Laponite\u7c92\u5b50\u540c\u65f6\u5e26\u6709\u6b63\u3001\u8d1f\u7535\u8377\uff0c\u662f\u5426\u53ef\u4ee5\u7b80\u5316\u4e3aDLVO\u52bf\u3002\u6211\u67e5\u4e86\u5f88\u4e45\u7684\u6587\u732e\uff0c\u5305\u62ec\u5982\u679c\u771f\u7684\u8003\u8651\u6b63\u8d1f\u7535\u8377\u600e\u4e48\u529e\u7684\u8bba\u6587\uff0c\u4f46\u6700\u540e\u4f46\u5230\u4e00\u7bc7\u901a\u8fc7\u6709\u9650\u5143\u6cd5\u89e3\u5706\u7247\u5e26\u7535\u7c92\u5b50\u7684Poisson-Boltzmann\u65b9\u7a0b\u7684\u5de5\u4f5c\uff0c\u8bf4\u9762\u4e0a\u7684\u8d1f\u7535\u52bf\u5206\u5e03\u4f1a\u628a\u8fb9\u4e0a\u7684\u6b63\u7535\u52bf\u5206\u5e03\u5b8c\u5168\u76d6\u4f4f\uff0c\u5bf9\u5916\u754c\u53ea\u663e\u793a\u6574\u4f53\u8d1f\u7535\u52bf\u3002\u6211\u5f53\u65f6\u4e0d\u61c2\u6709\u9650\u5143\u89e3\u65b9\u7a0b\uff0c\u4e8e\u662f\u5c31\u53c8\u73b0\u5b66\u4e86\u4e00\u904d\uff0c\u7ec8\u4e8e\u5f97\u51fa\u5bf9\u4e8e\u6211\u7684Laponite\u7247\u72b6\u7c92\u5b50\u7684\u7535\u52bf\u5206\u5e03\u56fe\uff0c\u8bc1\u660e\u4e86\u7b80\u5355\u5c06\u5176\u770b\u4f5c\u8d1f\u7535\u7c92\u5b50\u7684\u5408\u7406\u6027\u3002\u8fd9\u4e2a\u8bba\u6587\u8fd8\u56e0\u4e3a\u8fd9\u4e2a\u8865\u4e0a\u7684\u56fe\u8fd8\u88ab\u5f15\u7528\uff0c\u56e0\u4e3a\u8fd9\u4e2a\u7ed3\u679c\u4e3a\u540e\u6765\u7684\u4eba\u7ee7\u7eed\u7b80\u5355\u8003\u8651Laponite\u7684\u7535\u52bf\u63d0\u4f9b\u4e86\u65b9\u4fbf\u7684\u4f9d\u636e\u3002<\/p>\n

\u62112013\u5e74\u7684Soft Matter<\/em>[4]<\/a><\/span>\u662f\u63a5\u7740\u4e0a\u8ff0\u7684\u5de5\u4f5c\u7684\u3002\u4f46\u4e5f\u662f\u5b66\u4e60\u53e6\u4e00\u4e2a\u7ec4\u505a\u51fa\u7684\u52a8\u6001\u7c98\u5f39\u8c31\u7684\u53e0\u52a0\u6027\u7ed3\u679c\uff0c\u6362\u6210\u4e86\u8ddf2012\u5e74[3]<\/a><\/span>\u4e00\u6837\u7684\u4f53\u7cfb\uff0c\u628a\u4eba\u5bb6\u770b\u5230\u8fc7\u7684\u89c4\u5f8b\u91cd\u590d\u4e86\u4e00\u904d\u3002\u4f46\u662f\uff0c\u8fd9\u7bc7\u8bba\u6587\u7a81\u7834\u4e86time-aging time superposition\u7684\u5df2\u77e5\u884c\u4e3a\uff0c\u5c55\u793a\u4e86time-X superposition\u884c\u4e3a\uff0cX\u4ee3\u8868\u80fd\u4fee\u9970\u7c92\u5b50\u76f8\u4e92\u4f5c\u7528\u52bf\u7684\u5404\u7c7b\u6761\u4ef6\u3002\u4e00\u5f00\u59cb\u4e0d\u77e5\u5929\u9ad8\u5730\u539a\uff0c\u8bd5\u6295PRL<\/em>\uff0c\u7ed3\u679c\u7531\u4e8e\u9009\u53d6\u7684Laponite\u6d53\u5ea6\u4f53\u7cfb\u5728\u5df2\u62a5\u9053\u7684\u76f8\u56fe\u4e2d\u4f4d\u7f6e\u5c34\u5c2c\uff0c\u96be\u4ee5\u8bf4\u660e\u662fgel\u8fd8\u662fglass\u3002\u8fd9\u4e2a\u95ee\u9898\u73b0\u5728\u6211\u5176\u5b9e\u6709\u6bd4\u8f83\u81ea\u4fe1\u7684\u770b\u6cd5\uff0c\u540e\u9762\u6709\u65f6\u95f4\u4f1a\u63d0\u5230\u3002\u4f46\u5f53\u65f6\u6211\u81ea\u5df1\u5bf9\u5df2\u62a5\u9053\u7684Laponite\u76f8\u56fe\u4e5f\u7406\u89e3\u4e0d\u6df1\uff0c\u65e2\u65e0\u6cd5\u6279\u5224\u5b83\u4eec\uff0c\u53c8\u65e0\u6cd5\u89e3\u91ca\u81ea\u5df1\u7684\u4f53\u7cfb\uff0c\u7ed3\u679c\u5c31\u5728\u8fd9\u4e2a\u95ee\u9898\u4e0a\u5361\u4f4f\uff0cPRL<\/em>\u6295\u4e0d\u8fdb\u53bb\uff0c\u5c31\u6539\u6295\u4e86Soft Matter<\/em>\u63a5\u6536\u4e86\u3002\u5c3d\u7ba1\u63a5\u6536\u4e86\uff0c\u81f3\u4eca\u672a\u6709\u4ed6\u4eba\u5f15\u7528\u3002<\/p>\n

\u5f53\u65f6PRL <\/em>\u5ba1\u7a3f\u610f\u89c1\u8fd8\u63d0\u51fa\u6211\u4eec\u5e94\u8be5\u63d0\u51fa\u4e00\u4e2a\u6a21\u578b\u53bb\u63cf\u8ff0\u8fd9\u4e2a\u73b0\u8c61\uff0c\u4e0d\u80fd\u53ea\u662f\u5b9e\u9a8c\u3002\u4e8e\u662f\u6211\u53c8\u5728\u56de\u590d\u5ba1\u7a3f\u610f\u89c1\u7684\u9650\u671f\u5185\u67e5\u9605\u4e86\u5927\u91cf\u8bba\u6587\u3002\u73b0\u5728\u77e5\u9053\uff0c\u8981\u4ece\u80f6\u4f53\u76f8\u4e92\u4f5c\u7528\u52bf\u51fa\u53d1\uff0c\u9884\u6d4b\u5176\u51dd\u80f6\u6216\u73bb\u7483\u6001\u7684\u7ebf\u6027\u7c98\u5f39\u6027\u7684\u7406\u8bba\uff0c\u4e5f\u5c31\u53ea\u6709\u57fa\u4e8eschematic MCT\u7684F<\/em>12<\/sub>\u6a21\u578b\u3002\u8def\u5b50\u4e0d\u662f\u6ca1\u6709\u7684\uff0c\u4ece\u76f8\u4e92\u4f5c\u7528\u52bf\u80fd\u51fa\u53d1\uff0c\u91c7\u7528\u4e00\u4e2a\u5e38\u7528\u7684\u6bd4\u5982\u8bf4Percus\u2013Yevick\uff0c\u5f97\u5230\u76f8\u5e94\u7684\u9759\u6001\u7ed3\u6784\u56e0\u5b50\uff0c\u7136\u540e\u4ee3\u5165MCT\u7684kernal\u5f0f\u4e2d\u8ba1\u7b97memory function\uff1b\u7136\u540e\u4ee3\u5165\u5c0f\u5e45\u6b63\u5f26\u632f\u8361\u5e94\u53d8\uff0c\u8ba1\u7b97\u77ac\u6001\u5e94\u529b\u54cd\u5e94\uff0c\u5e76\u5f97\u5230\u76f8\u5e94\u7684\u590d\u6570\u6a21\u91cf\u3002\u8fd9\u4e00\u5927\u901a\u8ba1\u7b97\uff0c\u6211\u5f53\u65f6\u770b\u50bb\u773c\u4e86\uff0c\u6240\u4ee5\u653e\u5f03\u4e86\u3002\u73b0\u5728\uff0c\u867d\u7136\u5927\u81f4\u89c9\u5f97\u90fd\u61c2\u5f04\uff0c\u4f46\u6ca1\u6709\u7cbe\u529b\u5199\u8fd9\u4e2a\u7a0b\u5e8f\u3002<\/p>\n

\u7ecf\u8fc7\u5bf9Laponite\u4f53\u7cfb\u7684\u4e00\u6bb5\u65f6\u95f4\u63a5\u89e6\uff0c\u6211\u8d8a\u6765\u8d8a\u5f3a\u70c8\u5730\u89c9\u5f97\uff0c\u90a3\u4e9b\u5728\u5df2\u62a5\u9053\u76f8\u56fe\u4e2d\u6807\u660e\u4e3a\u201c\u73bb\u7483\u201d\u7684\u914d\u6bd4\u4f53\u7cfb\u5176\u5b9e\u5e94\u8be5\u662f\u51dd\u80f6\u3002\u4e3a\u6b64\uff0c\u6211\u5f00\u59cb\u9010\u7bc7\u67e5\u9605\u5173\u4e8eLaponite\u76f8\u56fe\u7684\u8bba\u6587\u3002\u4f46\u8fd9\u6d89\u53ca\u5230\u201c\u4f55\u4e3a\u80f6\u4f53\u73bb\u7483\/\u51dd\u80f6\u201d\u7684\u95ee\u9898\uff0c\u6211\u53c8\u6269\u5927\u5230\u4e86\u6240\u6709\u786c\u7403\u4f53\u7cfb\u7684\u5e73\u8861\u6001\u76f8\u8f6c\u53d8\u7814\u7a76\u3002\u8fd9\u4e00\u4e0b\u5b50\u6d89\u53ca\u9762\u5c31\u5927\u4e86\uff0c\u800c\u4e14\u6211\u4e00\u4e0b\u5b50\u610f\u8bc6\u4e0d\u5230\uff0c\u6211\u9996\u5148\u5e94\u8be5\u6709\u5e73\u8861\u6001\u7edf\u8ba1\u7269\u7406\u7684\u57fa\u7840\u4ee5\u53ca\u8ba1\u7b97\u673a\u6a21\u62df\u65b9\u6cd5\u7684\u57fa\u7840\uff0c\u4e00\u76f4\u901a\u8fc7\u6587\u732e\u603b\u7ed3\u77e5\u8bc6\uff0c\u8fd9\u6bb5\u65f6\u95f4\u5927\u6982\u662f\u4ece2013\u5e74\u52302014\u5e74\u8fd9\u4e00\u5e74\u7684\u65f6\u95f4\u3002\u6211\u5927\u6982\u4ece\u6982\u5ff5\u4e0a\u641e\u6e05\uff0c\u4e5f\u8c03\u67e5\u6e05\u695a\u628aLaponite\u4f53\u7cfb\u770b\u4f5c\u73bb\u7483\u7684\u89c2\u70b9\u53f2\u53ca\u8bc1\u636e\uff0c\u8ba4\u4e3a\u54ea\u6015\u7efc\u8ff0\u90fd\u53d1\u8868\u4e86\uff0c\u4f46\u8fd9\u4e2a\u89c2\u70b9\u662f\u7f3a\u4e4f\u652f\u6301\u7684\u3002<\/p>\n

\u4e0e\u6b64\u540c\u65f6\uff0c\u8ddf\u6211\u505a\u5b9e\u9a8c\u7684\u5e08\u5f1f\u53c8\u91cd\u590d\u6211\u5df2\u53d1\u8868\u5de5\u4f5c\u7684\u5957\u8def\uff0c\u8fd9\u6b21\u4ed6\u53d8\u5316\u4e86\u4e0d\u540c\u7684\u6e29\u5ea6\u505a\u52a8\u529b\u5b66\u66f2\u7ebf\uff0c\u7136\u540e\u53d1\u73b0\u53ef\u53e0\u52a0\u6027\u3002\u672c\u6765\u6211\u63d0\u4e0d\u8d77\u7cbe\u795e\u53bb\u6574\u7406\u8fd9\u79cd\u91cd\u590d\u7684\u5de5\u4f5c\uff0c\u4f46\u662f\u6bd5\u7adf\u5de5\u4f5c\u4e86\uff0c\u6ca1\u8d28\u91cf\u6709\u6570\u91cf\u4e5f\u597d\u554a\u3002\u8fd9\u4e2a\u5e08\u5f1f\u7684\u5b9e\u9a8c\u7ed3\u679c\u6709\u4e00\u4e2a\u5c0f\u5f02\u5e38\uff0c\u5c31\u662fLaponite\u51dd\u80f6\u5316\u5feb\u6162\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u4e0d\u662f\u5355\u8c03\u7684\u3002\u4e00\u5f00\u59cb\u6211\u89c9\u5f97\u8fd9\u4e5f\u5f88\u96be\u8bf4\u51fa\u4e2a\u4ec0\u4e48\uff0c\u800c\u4e14\u5047\u5982\u91c7\u7528\u4ee5\u524d\u7528\u8fc7\u7684\u4e0d\u53ef\u9006\u805a\u96c6\u6a21\u578b\u518d\u6765\u8ba1\u7b97\u4e00\u756a\uff0c\u4e5f\u65e0\u8bba\u5982\u4f55\u4e0d\u4f1a\u7b97\u51fa\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u3002\u4e8e\u662f\u60f3\u4e5f\u8bb8\u4e0d\u540c\u6e29\u5ea6\u4e0b\u4e5f\u8bb8\u7c92\u5b50\u8868\u9762\u7279\u6027\u4f1a\u4e0d\u540c\uff0c\u662f\u4ece\u76f8\u4e92\u4f5c\u7528\u52bf\u5c42\u9762\u5f71\u54cd\u5bfc\u81f4\u7684\u7ed3\u679c\uff0c\u4e8e\u662f\u5c31\u8ba9\u5e08\u5f1f\u8865\u6d4b\u4e86\u4e00\u4e0b\u4e0d\u540c\u7535\u5bfc\u7387\u548cpH\u503c\uff0c\u76f4\u63a5\u8ba1\u7b97\u8868\u9762\u7535\u8377\u5bc6\u5ea6\uff08\u800c\u4e0d\u662f\u7b80\u5355\u7528\u4e00\u4e2a\u6587\u732e\u62a5\u9053\u7684zeta\u7535\u52bf\u6765\u4ee3\u5165\u8ba1\u7b97\uff09\u3002\u867d\u7136\u4ecd\u7136\u6ca1\u53d1\u73b0\u4ec0\u4e48\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\uff0c\u4f46\u8fd8\u662f\u60f3\u786c\u7740\u5934\u76ae\u5f80\u4e0b\u7b97\uff0c\u9047\u5230\u4e86\u4e00\u4e2a\u65b0\u95ee\u9898\uff0c\u5c31\u662f\u8fd9\u6b21\u5e08\u5f1f\u7528\u7684\u662f\u65e0\u76d0\u7c92\u5b50\u60ac\u6d6e\u6db2\uff0c\u6db2\u4f53\u4e2d\u7684\u79bb\u5b50\u5168\u662f\u7c92\u5b50\u7535\u79bb\u7684\u53cd\u79bb\u5b50\u3002\u6211\u60f3\u4e86\u534a\u5929\u4e0d\u77e5\u9053\u600e\u4e48\u8003\u8651\uff0c\u7ffb\u9605H. Ohshima\u7684Theory of Colloid and Interfacial Electric Phenomena<\/em><\/a>\u4e0d\u6b62\u4e00\u6b21\uff0c\u4e5f\u627e\u4e0d\u5230\u4e66\u4e2d\u54ea\u79cd\u60c5\u51b5\u80fd\u591f\u4e0e\u6211\u7684\u5bf9\u5e94\u3002\u4e8e\u662f\u76f4\u63a5\u5199\u4fe1\u7ed9H. Ohshima\u8bf7\u6559\uff0c\u624d\u4e86\u89e3\u5230\u6211\u7684\u60c5\u51b5\u5c5e\u4e8esalt-free system\u6216\u8005counterions-only system\u3002\u4ed6\u8fd8\u4ecb\u7ecd\u6211\u770b\u4e86\u76f8\u5173\u7684\u8bba\u6587\u3002<\/p>\n

\u5176\u5b9e\uff0c\u8fd9\u7bc7\u6587\u7ae0\u5230\u6211\u77e5\u9053\u6b63\u786e\u5bf9\u5e94\u7684\u7269\u7406\u4f53\u7cfb\u65f6\uff0c\u5df2\u7ecf\u62d6\u4e86\u5f88\u4e45\uff0c\u6211\u8001\u677f\u603b\u662f\u89c9\u5f97\u4e00\u7bc7\u6587\u7ae0\u4e0d\u503c\u5f97\u5f04\u8fd9\u4e48\u4e45\u3002\u4f46\u4ed6\u4e0d\u77e5\u9053\uff0c\u4e4b\u6240\u4ee5\u4e45\uff0c\u662f\u56e0\u4e3a\u6211\u6c34\u5e73\u5dee\u3001\u5916\u884c\u3001\u8d70\u5f2f\u8def\u3002\u4ed6\u662f\u7ecf\u8fc7\u826f\u597d\u7684\u7814\u7a76\u751f\u8bad\u7ec3\u7684\u7814\u7a76\u8005\uff0c\u6709\u4ed6\u64c5\u957f\u7684\u4e13\u4e1a\uff0c\u5728\u4ed6\u64c5\u957f\u7684\u9886\u57df\u5185\uff0c\u80fd\u591f\u4e0d\u8d70\u4f4e\u7ea7\u7684\u5f2f\u8def\u3002\u800c\u6211\u6ca1\u6709\u4ec0\u4e48\u505a\u7269\u7406\u5e94\u6709\u7684\u7406\u8bba\u57fa\u7840\uff0c\u5c31\u4f1a\u8d70\u5f2f\u8def\u3002\u6240\u4ee5\uff0c\u5b66\u5230\u4e86\u6b63\u786e\u7684\u77e5\u8bc6\u4e4b\u540e\uff0c\u7518\u613f\u518d\u82b1\u4e00\u500d\u7684\u65f6\u95f4\u91cd\u65b0\u6309\u7167\u6b63\u786e\u7684\u6a21\u578b\u53bb\u8ba1\u7b97\u3002<\/p>\n

\u7ed3\u679c\u53d1\u73b0\uff0c\u901a\u8fc7\u5b9e\u9a8c\u6d4b\u5f97\u7684\u7c92\u5b50\u8868\u9762\u7279\u6027\uff0c\u518d\u6b63\u786e\u8003\u8651\u53cd\u79bb\u5b50\u51dd\u805a\uff0c\u5c31\u6070\u597d\u80fd\u9884\u6d4b\u51fa\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u3002\u8fd9\u662f\u8ba9\u6211\u5f88\u5174\u594b\u7684\u7ed3\u679c\u3002\u53ef\u662f\u4e00\u5f00\u59cb\u6295\u8fc7Langmuir<\/em>\u548cSoft Matter<\/em>\u90fd\u88ab\u79d2\u62d2\u4e86\uff0c\u5f88\u53d7\u632b\u3002\u540e\u6765\u8fd8\u662f\u6295J. Colloid Interf. Sci.<\/em>[2]<\/a><\/span>\u53cd\u800c\u83b7\u5f97\u4e86\u597d\u8bc4\u3002\u8fd9\u6bb5\u8fc7\u7a0b\u8ba9\u6211\u76f8\u4fe1\uff0c\u8bba\u6587\u5c31\u5e94\u8be5\u6295\u5230\u9886\u57df\u76f8\u7b26\u7684\u671f\u520a\uff0c\u4e00\u70b9\u4e5f\u4e0d\u8981\u8ffd\u6c42\u5f71\u54cd\u56e0\u5b50\u548cJCR\u5206\u533a\u3002\u56e0\u4e3a\u53ea\u6709\u5c3d\u53ef\u80fd\u5bf9\u53e3\u7684\u540c\u884c\u624d\u6709\u5f97\u61c2\u4f60\u7684\u5de5\u4f5c\uff0c\u7406\u89e3\u4f60\u5de5\u4f5c\u7684\u91cd\u8981\u6027\uff0c\u7ed9\u4e88\u6709\u5efa\u8bbe\u6027\u7684\u610f\u89c1\u5e76\u5efa\u8bae\u53d1\u8868\u3002<\/p>\n

\u521a\u521a\u53d1\u8868\u7684\u5de5\u4f5c[5]<\/a><\/span>\uff0c\u5219\u662f\u53c8\u5b66\u77402013\u5e74\u7684\u90a3\u7bc7Soft Matter<\/em>[4]<\/a><\/span>\u90a3\u6837\uff0c\u628a\u521a\u505a\u8fc7\u52a8\u529b\u5b66\u66f2\u7ebf\u53e0\u52a0\u7684\u4f53\u7cfb\uff0c\u518d\u505a\u4e00\u6b21\u7c98\u5f39\u8c31\u53e0\u52a0\u3002\u8fd9\u5728\u5b9e\u9a8c\u4e0a\u5b9e\u5728\u662f\u7eaf\u7cb9\u7684\u91cd\u590d\uff0c\u800c\u4e14\u8ddf2013\u5e74\u7684\u60c5\u51b5\u4e00\u6837\uff0c\u6211\u4ecd\u7136\u65e0\u6cd5\u5229\u7528schematic MCT\u6a21\u578b\u5bf9\u7c98\u5f39\u8c31\u8fdb\u884c\u7406\u8bba\u8ba1\u7b97\u6bd4\u8f83\uff0c\u6ca1\u529e\u6cd5\u7a81\u7834\u3002\u4f46\u662f\uff0c\u8fd9\u65f6\u6211\u6070\u597d\u770b\u5230\u4e86H. Winter\u7684\u4e00\u7bc7\u8bba\u6587[6]<\/a><\/span>\uff0c\u63d0\u9192\u6211\u867d\u7136\u4e0d\u80fd\u4ece\u7b2c\u4e00\u6027\u539f\u7406\u6a21\u578b\u53bb\u8ba1\u7b97\u7c98\u5f39\u8c31\uff0c\u81f3\u5c11\u53ef\u4ee5\u7528\u552f\u8c61\u6a21\u578b\u62df\u5408\u51fa\u4e00\u4e2a\u8c31\u6765\u7814\u7a76\u3002\u4e8e\u662f\u5c31\u5bf9\u7ed3\u679c\u8fdb\u884c\u4e86\u8bd5\u9a8c\uff0c\u53d1\u73b0\u5728\u6211\u7684\u7ed3\u679c\u4e2d\u5c31\u6709\u6240\u8c13\u7684\u51dd\u80f6\u5230\u73bb\u7483\u7684rheological inversion\u3002\u8fd9\u4e5f\u662f\u4ee4\u6211\u89c9\u5f97\u6709\u8da3\u7684\u7ed3\u679c\uff0c\u800c\u4e14\u7ec8\u4e8e\u4f7f\u8fd9\u90e8\u5206\u5de5\u4f5c\u4e0d\u518d\u6d41\u4e8e\u7b80\u5355\u91cd\u590d\u5df2\u6709\u5de5\u4f5c\u4e86\u3002\u7531\u4e8e\u662f\u7d27\u63a5\u7740[2]<\/a><\/span>\u505a\u7684\uff0c\u4e8e\u662f\u4e5f\u60f3\u518d\u6295\u540c\u4e00\u4e2a\u671f\u520a\uff0c\u4ee5\u4e3a\u5c31\u4f1a\u987a\u5229\u53d7\u5ba1\uff0c\u7ed3\u679c\u88ab\u79d2\u62d2\uff0c\u5341\u5206\u53d7\u632b\uff0c\u6295Colloids Surf. A\u3002\u56e0\u4e3a\u6211\u4e4b\u524d\u6709\u53e6\u5916\u4e00\u4e9b\u5b9e\u9a8c\u5de5\u4f5c\u51e0\u6b21\u6295\u4e0d\u51fa\u53bb\u6700\u540e\u90fd\u6295\u5230Colloids Surf. A\u89e3\u51b3\u7684\u3002\u8fd9\u6b21\u53ea\u597d\u53c8\u5982\u6cd5\u6ce1\u5236\u3002<\/p>\n

\u8fd8\u5728\u9001\u5ba1\u7684\u8fc7\u7a0b\u4e2d\uff0c\u6211\u53c2\u52a0\u4e86\u7f8e\u56fd\u6d41\u53d8\u5b66\u4f1a\uff0c\u5728Baltimore\u89c1\u5230\u4e86H. Winter\u672c\u4eba\u3002\u6211\u5411\u4ed6\u63cf\u8ff0\u4e86\u6211\u5bf9\u4ed6\u5de5\u4f5c\u7684\u5f15\u7528\uff0c\u4ed6\u5f88\u611f\u5174\u8da3\u3002\u4e8e\u662f\uff0c\u6211\u8868\u8fbe\u4e86\u76ee\u524d\u8fd9\u4e2a\u5de5\u4f5c\u7684\u6295\u7a3f\u72b6\u6001\uff0c\u610f\u601d\u5c31\u662f\u6c42\u4ed6\u5e2e\u5fd9\u3002\u4ed6\u7ed9\u6211\u975e\u5e38nice\u7684\u56de\u590d\u3002\u73b0\u5728\u8fd8\u662f\u987a\u5229\u53d1\u8868\u4e86\uff0c\u6211\u53ef\u4ee5\u544a\u8bc9\u4ed6\u8fd9\u4e00\u6d88\u606f\u3002<\/p>\n

\u5728\u4ee5\u4e0a\u4e24\u4e09\u5e74\u5bf9Laponite\u7684\u7814\u7a76\u8fc7\u7a0b\uff0c\u6211\u975e\u5e38\u5c0f\u5fc3\u5730\u8003\u8651\u4e86\u5b83\u7684\u76f8\u4e92\u4f5c\u7528\u52bf\uff0c\u4e5f\u4ece\u5bf9\u5176\u52a8\u529b\u5b66\u7684\u9884\u6d4b\u7ed3\u679c\u8bc1\u660e\u4e86\u8fd9\u79cd\u8003\u8651\u7684\u5408\u7406\u6027\uff0c\u6211\u7684\u7ed3\u679c\u8bf4\u660e\u522b\u4eba\u8bf4\u662f\u73bb\u7483\u7684Laponite\u4f53\u7cfb\u5176\u5b9e\u662f\u4e0d\u53ef\u9006\u805a\u96c6\u51dd\u80f6\u3002\u4e8e\u662f\uff0c\u4ee5\u524d\u8ba4\u4e3a\u56e0\u4e3a\u662f\u73bb\u7483\u6240\u4ee5\u4e0d\u5947\u602a\u7684time-aging time superposition\u73b0\u8c61\uff0c\u73b0\u5728\u5e94\u7406\u89e3\u4e3a\u4e0d\u53ef\u9006\u805a\u96c6\u51dd\u80f6\uff08\u5373\u5206\u5f62\u56e2\u7c07\u7f51\u7edc\uff09\u4e5f\u6709\u7684glassy behavior\u3002\u800c\u4e14\u6211\u8fd8\u8bc1\u5b9e\u4e86\u81f3\u5c11\u5728Laponite\u4f53\u7cfb\u7406\uff0c\u8fd8\u6709time-X superposition\uff0c\u5176\u4e2dX\u53ef\u7406\u89e3\u4e3a\u5e7f\u4e49\u6e29\u5ea6\u3002<\/p>\n

\u6211\u5e0c\u671b\u8fd9\u4e9b\u53d1\u73b0\u4e0d\u662fLaponite\u4f53\u7cfb\u7279\u6709\u7684\uff0c\u800c\u662f\u80f6\u4f53\u4f53\u7cfb\u975e\u5e73\u8861\u6001\u7684\u5171\u6027\uff0c\u4e8e\u662f\u6211\u5f00\u59cb\u5accLaponite\u4e0d\u591f\u5178\u578b\uff0c\u8003\u8651\u4f20\u7edf\u7684\u786c\u7403\u5438\u5f15\u4f53\u7cfb\u3002\u5f88\u81ea\u7136\uff0c\u6211\u53c8\u514d\u4e0d\u4e86\u4e00\u756a\u6587\u732e\u5b66\u4e60\u3002\u5438\u5f15\u529b\u7684\u6a21\u578b\u5b9e\u9a8c\u4f53\u7cfb\u65e0\u975e\u5c31\u662f\u63a5\u6709octadecyl\u7684\u4e8c\u6c27\u5316\u7845\u7c92\u5b50\u60ac\u6d6e\u6db2\u548c\u63a5\u6709PHSA\u7684PMMA\u7c92\u5b50\u60ac\u6d6e\u6db2\uff0c\u524d\u8005\u662f\u9760\u53d8\u6e29\u6539\u53d8\u6eb6\u5242\u6027\u8d28\u5f15\u5165\u5438\u5f15\u529b\u7684\uff0c\u8fd1\u4f3c\u4e8eBaxter’s sticky ball\u52bf\uff0c\u540e\u8005\u5219\u662f\u901a\u8fc7\u6dfb\u52a0\u7ebf\u5f62PS\u5f15\u5165\u6392\u7a7a\u529b\uff0c\u5bf9\u5e94\u7684\u662fAsakawa-Oosawa\u52bf\u3002\u6211\u770b\u4e86\u5927\u91cf\u8ba1\u7b97\u673a\u6a21\u62df\u548c\u5b9e\u9a8c\u7ed3\u679c\uff0c\u4e8e\u662f\u5411\u82f1\u56fd\u7684\u5b9e\u9a8c\u5ba4\u8d2d\u4e70\u4e86\u4e0d\u5c11PMMA\u7c92\u5b50\uff0c\u7ed3\u679c\u53d1\u73b0\uff0c\u8fd9\u79cd\u4f53\u7cfb\u5f62\u6210\u7684\u51dd\u80f6\u7f51\u7edc\u975e\u5e38\u5f31\u3002\u660e\u660e\u5728\u663e\u5fae\u955c\u4e0b\u770b\u5230\u4e86\u5f88\u597d\u7684\u51dd\u80f6\u7f51\u7edc\uff0c\u5b8f\u89c2\u6837\u54c1\u5374\u50cf\u6c34\u4e00\u6837\u5bb9\u6613\u6d41\u52a8\uff0c\u4e1d\u6beb\u65e0\u6cd5\u652f\u6301\u81ea\u8eab\u91cd\u91cf\u3002\u4e8e\u662f\u6ca1\u6709\u7ee7\u7eed\u8fdb\u884c\u6d41\u5b66\u6d4b\u8bd5\uff0c\u8fd9\u4ef6\u4e8b\u60c5\u5c31\u6401\u7f6e\u4e86\u3002<\/p>\n

\u4e5f\u662f\u5230\u4e86\u7f8e\u56fd\u6d41\u53d8\u5b66\u4f1a\uff0c\u5728\u8ddf\u505a\u6a21\u62df\u7684R. Zia\u4ea4\u6d41\u88ab\u6253\u8138\u4e4b\u540e\uff0c\u91cd\u65b0\u8003\u8651\u4e86\u4e00\u4e0b\uff0c\u624d\u53d1\u73b0\uff0c\u6a21\u62df\u548c\u5b9e\u9a8c\u62a5\u9053\u70ed\u706b\u671d\u5929\u7684\u77ed\u7a0b\u5438\u5f15\u786c\u7403\u4f53\u7cfb\uff0c\u8ddf\u6211\u5173\u5fc3\u7684Laponite\u5b8c\u5168\u662f\u4e24\u56de\u4e8b\u3002Laponite\u8fd9\u79cd\u9ad8\u5e26\u7535\u7684\u6c34\u5206\u6563\u80f6\u4f53\u7c92\u5b50\u662fDLVO\u52bf\uff0c\u662f\u901a\u8fc7\u8c03\u8282\u4e00\u4e2a\u6392\u65a5\u52bf\u5792\u6765\u95f4\u63a5\u8c03\u8282\u5f15\u529b\u7684\u4f5c\u7528\u8303\u56f4\u7684\uff0c\u800c\u4e14\u77ed\u7a0b\u5f15\u529b\u548c\u957f\u7a0b\u65a5\u529b\u5f80\u5f80\u540c\u65f6\u5b58\u5728\u3002\u57fa\u4e8e\u8fd9\u6837\u7684\u4f5c\u7528\u52bf\u7684\u6a21\u62df\u5de5\u4f5c\u5f88\u5c11\uff0c\u4e5f\u5c11\u6709\u6a21\u578b\u5b9e\u9a8c\u4f53\u7cfb\u4e0e\u4e4b\u5bf9\u5e94\uff0c\u53ea\u6709\u7f57\u9a6c\u5927\u5b66\u7684E. Zaccarelli\u505a\u8fc7\u4e00\u4e9b\u6a21\u62df\u5de5\u4f5c\u3002\u7ecf\u8fc7\u4e0e\u5979\u6240\u91c7\u7528\u7684\u52bf\u51fd\u6570\u5bf9\u6bd4\uff0c\u6211\u5b9e\u9a8c\u7528\u7684Laponite\u4f53\u7cfb\u7684\u5f15\u529b\u5f3a\u5ea6\u9ad8\u8fbe24k<\/i>B<\/sub>T<\/i>\uff0c\u5df2\u7ecf\u4e0d\u80fd\u8ddf\u77ed\u7a0b\u5438\u5f15\u52bf\u4f53\u7cfb\u7684\u675f\u7f1a\u76f8\u5206\u79bb\u51dd\u80f6\u6bd4\u4e86\uff0c\u800c\u662f\u5178\u578b\u7684\u5206\u5f62\u56e2\u7c07\u51dd\u80f6\u3002\u5b83\u5728\u975e\u7ebf\u6027\u6d41\u52a8\u4e0b\u7684\u7ed3\u6784\u548c\u52a8\u6001\uff0c\u6709\u5f85\u8fdb\u4e00\u6b65\u7684\u6a21\u62df\u5de5\u4f5c\u6765\u7ed9\u51fa\u3002\u5927\u90e8\u5206\u5df2\u6709\u62a5\u9053\u4e0d\u80fd\u4f5c\u4e3a\u53c2\u8003\u3002<\/p>\n

\u4e5f\u662f\u5728\u8fd9\u6bb5\u601d\u8003\u7684\u8fc7\u7a0b\u4e2d\uff0c\u6211\u6bd4\u8f83\u7cfb\u7edf\uff08\u4f46\u7c97\u7565\uff09\u5730\u7ffb\u9605\u4e86\u5e73\u8861\u6001\u7edf\u8ba1\u7269\u7406\u548c\u7279\u522b\u662f\u80f6\u4f53\u7edf\u8ba1\u7269\u7406\u7684\u4e66\uff0c\u5bf9\u80f6\u4f53\u7269\u7406\u76ee\u524d\u7684\u8ba4\u8bc6\u73b0\u72b6\u7406\u89e3\u4e5f\u66f4\u6e05\u6670\u4e86\u3002<\/p>\n

\u5176\u5b9e\u9664\u4e86Laponite\u76f8\u5173\u7684\u7814\u7a76\u5de5\u4f5c\u4e4b\u5916\uff0c\u6211\u5176\u4ed6\u51e0\u7bc7\u53d1\u8868\u7684\u5de5\u4f5c\uff0c\u6863\u6b21\u548c\u610f\u4e49\u66f4\u52a0\u4f4e\uff0c\u4f46\u5b66\u4e60\u91cf\u540c\u6837\u5f88\u5927\u30022013\u7684\u4e73\u6db2\u7684\u5de5\u4f5c\u4e3a\u4e86\u589e\u52a0\u5de5\u4f5c\u91cf\uff0c\u4e5f\u662f\u52a0\u5165\u4e86\u6a21\u578b\u8ba1\u7b97\uff0c\u4e3a\u6b64\u6211\u67e5\u9605\u4e86\u4e73\u6db2\u548c\u6ce1\u6cab\u7684\u6574\u4e2a\u7269\u7406\u7814\u7a76\u5386\u53f2\uff0c\u6700\u540e\u7528\u4e0a\u7684\u4e5f\u5c31\u662f\u4e00\u4e2a\u6700\u7b80\u5355\u7684\u6a21\u578b\uff1b\u540c\u5e74\u7684\u5fae\u51dd\u80f6Jamming\u7684\u5de5\u4f5c\uff0c\u4e5f\u662f\u9047\u5230\u4e86\u6e29\u5ea6\u548c\u4f53\u79ef\u5206\u6570\u76f8\u8026\u5408\u7684\u56f0\u60d1\uff0c\u601d\u8003\u4e86\u5f88\u4e45\u624d\u53d1\u73b0\u5bf9\u8fd9\u79cd\u5fae\u51dd\u80f6\u4e0d\u80fd\u4f7f\u7528\u4f53\u7cfb\u5206\u6570\u4f5cJamming\u76f8\u56fe\u7684\u5750\u6807\u8f74\u3002\u8fd8\u6709\u4e00\u7bc7\u53d1\u8868\u5728Chin. J. Polym. Sci.\u7684\u660e\u80f6\u6d41\u53d8\u5b66\uff0c\u4e3a\u4e86\u51d1\u5de5\u4f5c\u91cf\uff0c\u7528\u4e86\u4e09\u79cd\u6a61\u80f6\u5f39\u6027\u7f51\u7edc\u6a21\u578b\u6765\u62df\u5408\u3002\u5c31\u4e3a\u8fd9\u4e2a\uff0c\u6211\u51e0\u4e4e\u628a\u6574\u4e2a\u8c61\u80f6\u5f39\u6027\u7f51\u7edc\u6a21\u578b\u7684\u7814\u7a76\u53f2\u90fd\u770b\u4e86\u4e00\u904d\uff0c\u624d\u4e86\u89e3\u9664\u4e86Mooney-Rivlin\u4e4b\u5916\u8fd8\u6709\u4ec0\u4e484-chain\u30018-chain\u3001full-chain\u4e4b\u7c7b\u7684\u529b\u5b66\u6a21\u578b\u3002\u8fd9\u4e9b\u8bba\u6587\u90fd\u5f88\u6e23\uff0c\u5c31\u4e0d\u4e00\u4e00\u5217\u4e3e\u4e86\uff1b\u4f46\u53d1\u8868\u8fd9\u4e9b\u8bba\u6587\u7684\u8fc7\u7a0b\u5b66\u4e60\u5230\u7684\u4e1c\u897f\u90fd\u5bf9\u6211\u7684\u7269\u7406\u601d\u7ef4\u548c\u89c6\u91ce\u6709\u5f88\u5927\u7684\u76ca\u5904\u3002\u56de\u60f3\u5de5\u4f5c\u4e4b\u540e\u8fd9\u51e0\u5e74\u7684\u5b66\u4e60\u5386\u7a0b\uff0c\u771f\u7684\u4e0d\u4e9a\u4e8e\u91cd\u65b0\u8bfb\u4e86\u4e00\u4e2a\u535a\u58eb\u3002\u73b0\u5728\u6211\u8ba4\u4e3a\u6211\u79bb\u4e00\u4e2a\u5408\u683c\u7684\u7269\u7406\u7814\u7a76\u8005\u8fd8\u5f88\u8fdc\uff0c\u4eca\u540e\u4ecd\u7136\u4e0d\u80fd\u653e\u5f03\u8fd9\u79cd\u8865\u4e60\uff0c\u54ea\u6015publication rate\u53d7\u5230\u9650\u5236\uff0c\u4e5f\u53ea\u5e0c\u671b\u6211\u7684\u8bba\u6587\u4e00\u7bc7\u6bd4\u4e00\u7bc7\u786c\uff0c\u4e0d\u8981\u8d8a\u6765\u8d8a\u6c34\u4e0b\u53bb\u3002<\/p>\n

References<\/h2>\n
    \n
  1. <\/a>\nC. Liang, W. Sun, T. Wang, X. Liu, and Z. Tong, \"Rheological inversion of the universal aging dynamics of hectorite clay suspensions\", Colloids and Surfaces A: Physicochemical and Engineering Aspects<\/i>, vol. 490, pp. 300-306, 2016. http:\/\/dx.doi.org\/10.1016\/j.colsurfa.2015.11.048<\/a>\n\n\n<\/li>\n
  2. <\/a>\nR. Shu, W. Sun, X. Liu, and Z. Tong, \"Temperature dependence of aging kinetics of hectorite clay suspensions\", Journal of Colloid and Interface Science<\/i>, vol. 444, pp. 132-140, 2015. http:\/\/dx.doi.org\/10.1016\/j.jcis.2014.12.073<\/a>\n\n\n<\/li>\n
  3. <\/a>\nW. Sun, Y. Yang, T. Wang, H. Huang, X. Liu, and Z. Tong, \"Effect of adsorbed poly(ethylene glycol) on the gelation evolution of Laponite suspensions: Aging time-polymer concentration superposition\", Journal of Colloid and Interface Science<\/i>, vol. 376, pp. 76-82, 2012. http:\/\/dx.doi.org\/10.1016\/j.jcis.2012.01.064<\/a>\n\n\n<\/li>\n
  4. <\/a>\nW. Sun, T. Wang, C. Wang, X. Liu, and Z. Tong, \"Scaling of the dynamic response of hectorite clay suspensions containing poly(ethylene glycol) along the universal route of aging\", Soft Matter<\/i>, vol. 9, pp. 6263, 2013. http:\/\/dx.doi.org\/10.1039\/C3SM50436K<\/a>\n\n\n<\/li>\n
  5. <\/a>\nH.H. Winter, \"Glass Transition as the Rheological Inverse of Gelation\", Macromolecules<\/i>, vol. 46, pp. 2425-2432, 2013. http:\/\/dx.doi.org\/10.1021\/ma400086v<\/a>\n\n\n<\/li>\n<\/ol>\n\n<\/div> ","protected":false},"excerpt":{"rendered":"

    \u53c8\u4e00\u4efd\u5de5\u4f5c\u53d1\u8868\u4e86\u3002\u8fd9\u7bc7\u8bba\u6587\u5176\u5b9e\u662f\u63a5\u7740\u4e0a\u4e00\u7bc7\u5de5\u4f5c\u7684\u7ee7\u7eed\u3002\u6709\u4eba\u8bf4\uff0c\u81ea\u5df1\u7684\u8bba\u6587\uff0c\u53d1\u8868\u4e4b\u540e\u5c31\u4e0d\u60f3\u91cd\u770b\u4e86\u3002\u80fd\u591f\u53d1\u8868\u503c\u5f97\u81ea\u5df1\u80af\u5b9a\u7684\u8bba\u6587\uff0c\u90fd\u4e0d\u662f\u5bb9\u6613\u7684\u4e8b\u60c5\uff0c\u66f4\u4e0d\u7528\u8bf4\u8ba9\u522b\u4eba\u80af\u5b9a\u4e86\u3002\u54ea\u6015\u662f\u5982\u6b64\u65e0\u8da3\u7684\u5de5\u4f5c\uff0c\u6211\u7684publication rate\u4e5f\u7279\u522b\u4f4e\uff0c\u56e0\u4e3a\u6bcf\u4e00\u7bc7\u8bba\u6587\uff0c\u6211\u90fd\u5e0c\u671b\u63a8\u8fdb\u4e00\u6b65\uff0c\u800c\u6211\u57fa\u7840\u6bd4\u8f83\u8584\u5f31\uff0c\u8fd9\u63a8\u8fdb\u7684\u4e00\u6b65\u5f80\u5f80\u662f\u4ece\u8865\u4e60\u57fa\u672c\u77e5\u8bc6\u5f00\u59cb\uff1a\u5148\u5b66\u4e60\u57fa\u672c\u7406\u8bba\u7684\u76f8\u5173\u6559\u79d1\u4e66\u4e86\u89e3\u4e00\u822c\u7684\u60c5\u51b5\uff0c\u7136\u540e\u770b\u76f8\u5173\u7684\u6587\u732e\u4e86\u89e3\u8ddf\u6211\u7684\u95ee\u9898\u63a5\u8fd1\u7684\u60c5\u51b5\uff0c\u7136\u540e\u518d\u8003\u8651\u6211\u7684\u9700\u8981\u53d1\u8868\u7684\u95ee\u9898\u3002\u5982\u679c\u6211\u6bcf\u7bc7\u8bba\u6587\u90fd\u53ea\u6709\u5f53\u524d\u7684\u77e5\u8bc6\u7684\u7406\u89e3\uff0c\u90a3\u6211\u5c31\u4f1a\u66f4\u52a0\u5728\u6bd4\u8f83\u6e23\u7684\u6c34\u5e73\u4e0a\u505c\u6b65\u4e0d\u524d\u3002\u5728\u8fd9\u91cc\uff0c\u6211\u4e0d\u6015\u522b\u4eba\u7b11\u8bdd\u6211\u57fa\u7840\u6c34\u5e73\u66fe\u7ecf\u6709\u591a\u5dee\uff0c\u7b80\u5355\u8bb0\u5f55\u4e00\u4e0b\u6211\u600e\u4e48\u4ece\u83dc\u9e1f\u8d70\u8fc7\u6765\u7684\u3002\u5c06\u6765\u4e5f\u4f1a\u4e00\u76f4\u8d70\u4e0b\u53bb\u3002 \u535a\u58eb\u751f\u671f\u95f4\u4ece\u96f6\u5f00\u59cb\u5b66\u4e60\u6d41\u53d8\u5b66\u4e4b\u540e\u8fdb\u884cLAOS\u7814\u7a76\u7684\u7ecf\u5386\uff0c\u5c31\u4e0d\u63d0\u4e86\u3002\u62112012\u5e74\u7684\u90a3\u7bc7J. Colloid Interf. Sci.\uff0c\u662f\u6211\u53c2\u52a0\u5de5\u4f5c\u540e\u53d1\u8868\u7684\u7b2c\u4e00\u7bc7\uff08\u5f53\u7136\u662f\u535a\u58eb\u671f\u95f4\u7684\u5de5\u4f5c\uff09\u3002\u5b9e\u9a8c\u4e0a\u53ea\u662f\u5b66\u4eba\u5bb6\u5df2\u7ecf\u505a\u51fa\u6765\u7684\u7ed3\u679c\uff0c\u591a\u52a0\u4e86\u4e00\u4e2a\u6761\u4ef6\uff0c\u91cd\u590d\u4e86\u4e00\u6b21\u73b0\u8c61\uff0c\u5373Laponite\u51dd\u80f6\u5316\u7684\u52a8\u529b\u5b66\u66f2\u7ebf\u6709\u53e0\u52a0\u6027\u3002\u4f46\u662f\u4e3a\u4e86\u7406\u89e3\u5b83\uff0c\u6211\u627e\u4e86\u4e00\u4e9b\u8bba\u6587\uff0c\u53d1\u73b0\u8fd9\u7684\u786e\u662f\u53ef\u4ee5\u7531\u6a21\u578b\u9884\u6d4b\u7684\uff0c\u5c31\u5728\u5b9e\u9a8c\u7ed3\u679c\u62a5\u9053\u4e4b\u540e\u7eed\u4e86\u4e00\u4e2a\u6a21\u578b\u8ba1\u7b97\u3002 \u5176\u5b9e\u5982\u679c\u4ece\u66f4\u9ad8\u7684\u54c1\u4f4d\u6765\u770b\uff0c\u6240\u6709\u80fd\u7531\u7ecf\u5178\u6a21\u578b\u7b80\u5355\u9884\u6d4b\u51fa\u6765\u7684\u73b0\u8c61\uff0c\u4e0d\u7b97\u4ec0\u4e48\u65b0\u53d1\u73b0\u3002\u56e0\u4e3a\u6240\u8c13\u7ecf\u5178\u5c31\u662f\u6307\u65e9\u5df2\u88ab\u63a5\u53d7\u7684\u6a21\u578b\uff0c\u5b9e\u9a8c\u7b26\u5408\u7684\u4f8b\u5b50\u4e5f\u8bb8\u5df2\u7ecf\u6709\u6210\u5343\u4e0a\u4e07\u4e86\uff0c\u4f60\u518d\u4e3e\u4e00\u4e2a\u4e5f\u5c31\u53ea\u662f\u7b2c\u4e00\u4e07\u96f6\u4e00\u3002\u9664\u975e\u4f60\u662f\u63d0\u51fa\u5b83\u7684\u53cd\u4f8b\uff08\u4e5f\u5f88\u96be\uff09\u53ef\u80fd\u624d\u6bd4\u8f83\u5f15\u4eba\u5173\u6ce8\u3002\u4e0d\u53ef\u9006\u805a\u96c6\u7684\u6a21\u578b\u7684\u7814\u7a76\u65e9\u5c31\u63d0\u51fa\u4e86\u4e0d\u7ba1\u662f\u4e8c\u805a\u8fd8\u662fN\u805a\u90fd\u53ef\u7528\u4e00\u4e2a\u53cd\u5e94\u901f\u7387\u5e38\u6570\u63cf\u8ff0\u7684\u60c5\u51b5\uff0c\u76f8\u5f53\u4e8e\u9884\u6d4b\u4e86\u52a8\u529b\u5b66\u66f2\u7ebf\u6709\u53e0\u52a0\u6027\u3002\u6211\u7528\u4e0d\u53ef\u9006\u805a\u96c6\u7684\u6a21\u578b\u8ba1\u7b97\u7ed3\u679c\u4e0e\u5b9e\u9a8c\u7ed3\u679c\u6bd4\u8f83\u4e00\u4e0b\uff0c\u53ea\u80fd\u8bf4\u660eLaponite\u51dd\u80f6\u5316\u662f\u4e00\u4e2a\u4e0d\u53ef\u9006\u805a\u96c6\u6210cluster\u7f51\u7edc\u7684\u8fc7\u7a0b\u3002 \u4f46\u5c31\u4e3a\u8fd9\u4ef6\u4e8b\uff0c\u6211\u91cd\u5934\u5b66\u4e60\u4e86\u5982\u4f55\u63cf\u8ff0\u7c92\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u52bf\u80fd\u51fd\u6570\uff0c\u5305\u62ecDLVO\u52bf\u7684van der Waals\u4f5c\u7528\u52bf\u548c\u53cc\u7535\u5c42\u4f5c\u7528\u52bf\u3002\u66f4\u9ebb\u70e6\u7684\u5176\u5b9e\u662f\u8868\u9762\u5438\u9644\u805a\u5408\u7269\u5206\u5b50\u7684\u80f6\u4f53\u7c92\u5b50\uff0c\u805a\u5408\u7269\u94fe\u6392\u65a5\u7684\u8fd9\u90e8\u5206\u6548\u5e94\u3002\u8fd9\u4e2a\u6548\u5e94\u7684\u8ba1\u7b97\u5f0f\u9700\u8981\u77e5\u9053\u805a\u5408\u7269\u5c42\u7684\u7b49\u6548\u539a\u5ea6\u3002\u4ee5\u524d\u7684\u62a5\u9053\u5e94\u7528\u6b64\u5f0f\u65f6\u5f80\u5f80\u901a\u8fc7DLS\u6d4b\u91cf\u7c92\u5f84\u6216\u8005\u5176\u4ed6\u5404\u79cd\u6d4b\u91cf\u5438\u9644\u91cf\u7684\u529e\u6cd5\u6765\u8ba1\u7b97\u5438\u9644\u539a\u5ea6\uff0c\u800c\u8fd9\u4e9b\u65b9\u6cd5\u90fd\u4e0d\u9002\u7528\u4e8e\u6211\u7814\u7a76\u7684\u80f6\u4f53\u7c92\u5b50\uff08\u592a\u5c0f\u4e86\uff0c\u79bb\u5fc3\u4e0d\u51fa\u6765\uff1b\u53c8\u975e\u5e38\u5bb9\u6613\u805a\u96c6\uff0cDLS\u96be\u4ee5\u6d4b\u5230\u5355\u7c92\u5b50\u4fe1\u53f7\uff09\u3002\u53e6\u4e00\u6761\u8def\u662f\u7406\u8bba\u8ba1\u7b97\u3002\u805a\u5408\u7269\u5728\u7403\u8868\u9762\u4ee5\u5916\u7684\u5e73\u8861\u94fe\u5bc6\u5ea6\u5206\u5e03\u51fd\u6570\u9700\u8981\u901a\u8fc7\u94fe\u7edf\u8ba1\u6765\u89e3\u51fa\u3002\u4e3a\u6b64\u6211\u53bb\u56fe\u4e66\u9986\u501f\u9605\u4e86Fleer\u7b49\u4eba\u8457\u7684Polymers at Interfaces\u5b66\u4e60\u8868\u9762\u9ad8\u5206\u5b50\u94fe\u7edf\u8ba1\u3002\u672c\u6765\u60f3\u76f4\u63a5\u901a\u8fc7\u94fe\u7edf\u8ba1\u6765\u8ba1\u7b97\u51fa\u8fd9\u4e2a\u539a\u5ea6\u7684\uff0c\u4f46\u5177\u4f53\u5b66\u4e60\u53d1\u73b0\u8fd9\u4e2a\u6d89\u53ca\u5230\u4e00\u4e2a\u9012\u5f52\u7684\u7b97\u6cd5\uff0c\u4ee5\u5f53\u65f6\u6211\u7684\u6570\u5b66\u548c\u7f16\u7a0b\u6c34\u5e73\u8fd8\u662f\u65e0\u6cd5\u89e6\u78b0\uff0c\u53ea\u597d\u81ea\u5df1\u60f3\u51fa\u4e00\u4e2a\u7b80\u5355\u7684\u8fd1\u4f3c\u5047\u8bbe\uff0c\u8bd5\u8bd5\u770b\u7ed3\u679c\u4e5f\u543b\u5408\uff0c\u5c31\u8fd9\u4e48\u8fc7\u53bb\u4e86\u3002\u73b0\u5728\u60f3\u60f3\u770b\u8fd9\u4e2a\u597d\u50cf\u662f\u5c0fcase\uff0c\u53cd\u5012\u6709\u70b9\u8822\u8822\u6b32\u52a8\u60f3\u56de\u8fc7\u5934\u53bb\u7b97\u7b97\uff0c\u53ef\u60dc\u6ca1\u8fd9\u95f2\u529f\u592b\uff0c\u4f46\u53ef\u89c1\u4e00\u4e2a\u4eba\u80fd\u529b\u7684\u63d0\u9ad8\uff0c\u5176\u89e6\u89d2\u548c\u89c6\u91ce\u4f1a\u6269\u5927\u5f88\u591a\uff0c\u8fd9\u662f\u540e\u8bdd\u3002 \u5f97\u5230\u52bf\u80fd\u51fd\u6570\u4e4b\u540e\uff0c\u9a6c\u4e0a\u9762\u4e34\u7b2c\u4e8c\u4e2a\u96be\u5173\uff1a\u5f53\u65f6\u6211\u751a\u81f3\u4e0d\u61c2\u4f7f\u7528MATLAB\u8fdb\u884c\u7b80\u5355\u7684\u6570\u503c\u8ba1\u7b97\uff0c\u800c\u4e0d\u53ef\u9006\u805a\u96c6\u6a21\u578b\u9700\u8981\u4ece\u76f8\u4e92\u4f5c\u7528\u52bf\u80fd\u51fd\u6570\u79ef\u5206\u5f97\u5230\u7a33\u5b9a\u6bd4\uff0c\u5bf9\u4e8e\u590d\u6742\u7684\u52bf\u80fd\u51fd\u6570\u53ea\u80fd\u6570\u503c\u79ef\u5206\u4e00\u4e0b\u3002\u4e8e\u662f\u6211\u5b66\u4e60\u4f7f\u7528MATLAB\uff0c\u7ec8\u4e8e\u6b63\u786e\u5730\u5f97\u5230\u79ef\u5206\u7ed3\u679c\u3002 \u6295\u7a3f\u4e4b\u540e\uff0c\u53c8\u6709\u5ba1\u7a3f\u4eba\u8d28\u7591\u6211Laponite\u7c92\u5b50\u540c\u65f6\u5e26\u6709\u6b63\u3001\u8d1f\u7535\u8377\uff0c\u662f\u5426\u53ef\u4ee5\u7b80\u5316\u4e3aDLVO\u52bf\u3002\u6211\u67e5\u4e86\u5f88\u4e45\u7684\u6587\u732e\uff0c\u5305\u62ec\u5982\u679c\u771f\u7684\u8003\u8651\u6b63\u8d1f\u7535\u8377\u600e\u4e48\u529e\u7684\u8bba\u6587\uff0c\u4f46\u6700\u540e\u4f46\u5230\u4e00\u7bc7\u901a\u8fc7\u6709\u9650\u5143\u6cd5\u89e3\u5706\u7247\u5e26\u7535\u7c92\u5b50\u7684Poisson-Boltzmann\u65b9\u7a0b\u7684\u5de5\u4f5c\uff0c\u8bf4\u9762\u4e0a\u7684\u8d1f\u7535\u52bf\u5206\u5e03\u4f1a\u628a\u8fb9\u4e0a\u7684\u6b63\u7535\u52bf\u5206\u5e03\u5b8c\u5168\u76d6\u4f4f\uff0c\u5bf9\u5916\u754c\u53ea\u663e\u793a\u6574\u4f53\u8d1f\u7535\u52bf\u3002\u6211\u5f53\u65f6\u4e0d\u61c2\u6709\u9650\u5143\u89e3\u65b9\u7a0b\uff0c\u4e8e\u662f\u5c31\u53c8\u73b0\u5b66\u4e86\u4e00\u904d\uff0c\u7ec8\u4e8e\u5f97\u51fa\u5bf9\u4e8e\u6211\u7684Laponite\u7247\u72b6\u7c92\u5b50\u7684\u7535\u52bf\u5206\u5e03\u56fe\uff0c\u8bc1\u660e\u4e86\u7b80\u5355\u5c06\u5176\u770b\u4f5c\u8d1f\u7535\u7c92\u5b50\u7684\u5408\u7406\u6027\u3002\u8fd9\u4e2a\u8bba\u6587\u8fd8\u56e0\u4e3a\u8fd9\u4e2a\u8865\u4e0a\u7684\u56fe\u8fd8\u88ab\u5f15\u7528\uff0c\u56e0\u4e3a\u8fd9\u4e2a\u7ed3\u679c\u4e3a\u540e\u6765\u7684\u4eba\u7ee7\u7eed\u7b80\u5355\u8003\u8651Laponite\u7684\u7535\u52bf\u63d0\u4f9b\u4e86\u65b9\u4fbf\u7684\u4f9d\u636e\u3002 \u62112013\u5e74\u7684Soft Matter\u662f\u63a5\u7740\u4e0a\u8ff0\u7684\u5de5\u4f5c\u7684\u3002\u4f46\u4e5f\u662f\u5b66\u4e60\u53e6\u4e00\u4e2a\u7ec4\u505a\u51fa\u7684\u52a8\u6001\u7c98\u5f39\u8c31\u7684\u53e0\u52a0\u6027\u7ed3\u679c\uff0c\u6362\u6210\u4e86\u8ddf2012\u5e74\u4e00\u6837\u7684\u4f53\u7cfb\uff0c\u628a\u4eba\u5bb6\u770b\u5230\u8fc7\u7684\u89c4\u5f8b\u91cd\u590d\u4e86\u4e00\u904d\u3002\u4f46\u662f\uff0c\u8fd9\u7bc7\u8bba\u6587\u7a81\u7834\u4e86time-aging time superposition\u7684\u5df2\u77e5\u884c\u4e3a\uff0c\u5c55\u793a\u4e86time-X superposition\u884c\u4e3a\uff0cX\u4ee3\u8868\u80fd\u4fee\u9970\u7c92\u5b50\u76f8\u4e92\u4f5c\u7528\u52bf\u7684\u5404\u7c7b\u6761\u4ef6\u3002\u4e00\u5f00\u59cb\u4e0d\u77e5\u5929\u9ad8\u5730\u539a\uff0c\u8bd5\u6295PRL\uff0c\u7ed3\u679c\u7531\u4e8e\u9009\u53d6\u7684Laponite\u6d53\u5ea6\u4f53\u7cfb\u5728\u5df2\u62a5\u9053\u7684\u76f8\u56fe\u4e2d\u4f4d\u7f6e\u5c34\u5c2c\uff0c\u96be\u4ee5\u8bf4\u660e\u662fgel\u8fd8\u662fglass\u3002\u8fd9\u4e2a\u95ee\u9898\u73b0\u5728\u6211\u5176\u5b9e\u6709\u6bd4\u8f83\u81ea\u4fe1\u7684\u770b\u6cd5\uff0c\u540e\u9762\u6709\u65f6\u95f4\u4f1a\u63d0\u5230\u3002\u4f46\u5f53\u65f6\u6211\u81ea\u5df1\u5bf9\u5df2\u62a5\u9053\u7684Laponite\u76f8\u56fe\u4e5f\u7406\u89e3\u4e0d\u6df1\uff0c\u65e2\u65e0\u6cd5\u6279\u5224\u5b83\u4eec\uff0c\u53c8\u65e0\u6cd5\u89e3\u91ca\u81ea\u5df1\u7684\u4f53\u7cfb\uff0c\u7ed3\u679c\u5c31\u5728\u8fd9\u4e2a\u95ee\u9898\u4e0a\u5361\u4f4f\uff0cPRL\u6295\u4e0d\u8fdb\u53bb\uff0c\u5c31\u6539\u6295\u4e86Soft Matter\u63a5\u6536\u4e86\u3002\u5c3d\u7ba1\u63a5\u6536\u4e86\uff0c\u81f3\u4eca\u672a\u6709\u4ed6\u4eba\u5f15\u7528\u3002 \u5f53\u65f6PRL \u5ba1\u7a3f\u610f\u89c1\u8fd8\u63d0\u51fa\u6211\u4eec\u5e94\u8be5\u63d0\u51fa\u4e00\u4e2a\u6a21\u578b\u53bb\u63cf\u8ff0\u8fd9\u4e2a\u73b0\u8c61\uff0c\u4e0d\u80fd\u53ea\u662f\u5b9e\u9a8c\u3002\u4e8e\u662f\u6211\u53c8\u5728\u56de\u590d\u5ba1\u7a3f\u610f\u89c1\u7684\u9650\u671f\u5185\u67e5\u9605\u4e86\u5927\u91cf\u8bba\u6587\u3002\u73b0\u5728\u77e5\u9053\uff0c\u8981\u4ece\u80f6\u4f53\u76f8\u4e92\u4f5c\u7528\u52bf\u51fa\u53d1\uff0c\u9884\u6d4b\u5176\u51dd\u80f6\u6216\u73bb\u7483\u6001\u7684\u7ebf\u6027\u7c98\u5f39\u6027\u7684\u7406\u8bba\uff0c\u4e5f\u5c31\u53ea\u6709\u57fa\u4e8eschematic MCT\u7684F12\u6a21\u578b\u3002\u8def\u5b50\u4e0d\u662f\u6ca1\u6709\u7684\uff0c\u4ece\u76f8\u4e92\u4f5c\u7528\u52bf\u80fd\u51fa\u53d1\uff0c\u91c7\u7528\u4e00\u4e2a\u5e38\u7528\u7684\u6bd4\u5982\u8bf4Percus\u2013Yevick\uff0c\u5f97\u5230\u76f8\u5e94\u7684\u9759\u6001\u7ed3\u6784\u56e0\u5b50\uff0c\u7136\u540e\u4ee3\u5165MCT\u7684kernal\u5f0f\u4e2d\u8ba1\u7b97memory function\uff1b\u7136\u540e\u4ee3\u5165\u5c0f\u5e45\u6b63\u5f26\u632f\u8361\u5e94\u53d8\uff0c\u8ba1\u7b97\u77ac\u6001\u5e94\u529b\u54cd\u5e94\uff0c\u5e76\u5f97\u5230\u76f8\u5e94\u7684\u590d\u6570\u6a21\u91cf\u3002\u8fd9\u4e00\u5927\u901a\u8ba1\u7b97\uff0c\u6211\u5f53\u65f6\u770b\u50bb\u773c\u4e86\uff0c\u6240\u4ee5\u653e\u5f03\u4e86\u3002\u73b0\u5728\uff0c\u867d\u7136\u5927\u81f4\u89c9\u5f97\u90fd\u61c2\u5f04\uff0c\u4f46\u6ca1\u6709\u7cbe\u529b\u5199\u8fd9\u4e2a\u7a0b\u5e8f\u3002 \u7ecf\u8fc7\u5bf9Laponite\u4f53\u7cfb\u7684\u4e00\u6bb5\u65f6\u95f4\u63a5\u89e6\uff0c\u6211\u8d8a\u6765\u8d8a\u5f3a\u70c8\u5730\u89c9\u5f97\uff0c\u90a3\u4e9b\u5728\u5df2\u62a5\u9053\u76f8\u56fe\u4e2d\u6807\u660e\u4e3a\u201c\u73bb\u7483\u201d\u7684\u914d\u6bd4\u4f53\u7cfb\u5176\u5b9e\u5e94\u8be5\u662f\u51dd\u80f6\u3002\u4e3a\u6b64\uff0c\u6211\u5f00\u59cb\u9010\u7bc7\u67e5\u9605\u5173\u4e8eLaponite\u76f8\u56fe\u7684\u8bba\u6587\u3002\u4f46\u8fd9\u6d89\u53ca\u5230\u201c\u4f55\u4e3a\u80f6\u4f53\u73bb\u7483\/\u51dd\u80f6\u201d\u7684\u95ee\u9898\uff0c\u6211\u53c8\u6269\u5927\u5230\u4e86\u6240\u6709\u786c\u7403\u4f53\u7cfb\u7684\u5e73\u8861\u6001\u76f8\u8f6c\u53d8\u7814\u7a76\u3002\u8fd9\u4e00\u4e0b\u5b50\u6d89\u53ca\u9762\u5c31\u5927\u4e86\uff0c\u800c\u4e14\u6211\u4e00\u4e0b\u5b50\u610f\u8bc6\u4e0d\u5230\uff0c\u6211\u9996\u5148\u5e94\u8be5\u6709\u5e73\u8861\u6001\u7edf\u8ba1\u7269\u7406\u7684\u57fa\u7840\u4ee5\u53ca\u8ba1\u7b97\u673a\u6a21\u62df\u65b9\u6cd5\u7684\u57fa\u7840\uff0c\u4e00\u76f4\u901a\u8fc7\u6587\u732e\u603b\u7ed3\u77e5\u8bc6\uff0c\u8fd9\u6bb5\u65f6\u95f4\u5927\u6982\u662f\u4ece2013\u5e74\u52302014\u5e74\u8fd9\u4e00\u5e74\u7684\u65f6\u95f4\u3002\u6211\u5927\u6982\u4ece\u6982\u5ff5\u4e0a\u641e\u6e05\uff0c\u4e5f\u8c03\u67e5\u6e05\u695a\u628aLaponite\u4f53\u7cfb\u770b\u4f5c\u73bb\u7483\u7684\u89c2\u70b9\u53f2\u53ca\u8bc1\u636e\uff0c\u8ba4\u4e3a\u54ea\u6015\u7efc\u8ff0\u90fd\u53d1\u8868\u4e86\uff0c\u4f46\u8fd9\u4e2a\u89c2\u70b9\u662f\u7f3a\u4e4f\u652f\u6301\u7684\u3002 \u4e0e\u6b64\u540c\u65f6\uff0c\u8ddf\u6211\u505a\u5b9e\u9a8c\u7684\u5e08\u5f1f\u53c8\u91cd\u590d\u6211\u5df2\u53d1\u8868\u5de5\u4f5c\u7684\u5957\u8def\uff0c\u8fd9\u6b21\u4ed6\u53d8\u5316\u4e86\u4e0d\u540c\u7684\u6e29\u5ea6\u505a\u52a8\u529b\u5b66\u66f2\u7ebf\uff0c\u7136\u540e\u53d1\u73b0\u53ef\u53e0\u52a0\u6027\u3002\u672c\u6765\u6211\u63d0\u4e0d\u8d77\u7cbe\u795e\u53bb\u6574\u7406\u8fd9\u79cd\u91cd\u590d\u7684\u5de5\u4f5c\uff0c\u4f46\u662f\u6bd5\u7adf\u5de5\u4f5c\u4e86\uff0c\u6ca1\u8d28\u91cf\u6709\u6570\u91cf\u4e5f\u597d\u554a\u3002\u8fd9\u4e2a\u5e08\u5f1f\u7684\u5b9e\u9a8c\u7ed3\u679c\u6709\u4e00\u4e2a\u5c0f\u5f02\u5e38\uff0c\u5c31\u662fLaponite\u51dd\u80f6\u5316\u5feb\u6162\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u4e0d\u662f\u5355\u8c03\u7684\u3002\u4e00\u5f00\u59cb\u6211\u89c9\u5f97\u8fd9\u4e5f\u5f88\u96be\u8bf4\u51fa\u4e2a\u4ec0\u4e48\uff0c\u800c\u4e14\u5047\u5982\u91c7\u7528\u4ee5\u524d\u7528\u8fc7\u7684\u4e0d\u53ef\u9006\u805a\u96c6\u6a21\u578b\u518d\u6765\u8ba1\u7b97\u4e00\u756a\uff0c\u4e5f\u65e0\u8bba\u5982\u4f55\u4e0d\u4f1a\u7b97\u51fa\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u3002\u4e8e\u662f\u60f3\u4e5f\u8bb8\u4e0d\u540c\u6e29\u5ea6\u4e0b\u4e5f\u8bb8\u7c92\u5b50\u8868\u9762\u7279\u6027\u4f1a\u4e0d\u540c\uff0c\u662f\u4ece\u76f8\u4e92\u4f5c\u7528\u52bf\u5c42\u9762\u5f71\u54cd\u5bfc\u81f4\u7684\u7ed3\u679c\uff0c\u4e8e\u662f\u5c31\u8ba9\u5e08\u5f1f\u8865\u6d4b\u4e86\u4e00\u4e0b\u4e0d\u540c\u7535\u5bfc\u7387\u548cpH\u503c\uff0c\u76f4\u63a5\u8ba1\u7b97\u8868\u9762\u7535\u8377\u5bc6\u5ea6\uff08\u800c\u4e0d\u662f\u7b80\u5355\u7528\u4e00\u4e2a\u6587\u732e\u62a5\u9053\u7684zeta\u7535\u52bf\u6765\u4ee3\u5165\u8ba1\u7b97\uff09\u3002\u867d\u7136\u4ecd\u7136\u6ca1\u53d1\u73b0\u4ec0\u4e48\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\uff0c\u4f46\u8fd8\u662f\u60f3\u786c\u7740\u5934\u76ae\u5f80\u4e0b\u7b97\uff0c\u9047\u5230\u4e86\u4e00\u4e2a\u65b0\u95ee\u9898\uff0c\u5c31\u662f\u8fd9\u6b21\u5e08\u5f1f\u7528\u7684\u662f\u65e0\u76d0\u7c92\u5b50\u60ac\u6d6e\u6db2\uff0c\u6db2\u4f53\u4e2d\u7684\u79bb\u5b50\u5168\u662f\u7c92\u5b50\u7535\u79bb\u7684\u53cd\u79bb\u5b50\u3002\u6211\u60f3\u4e86\u534a\u5929\u4e0d\u77e5\u9053\u600e\u4e48\u8003\u8651\uff0c\u7ffb\u9605H. Ohshima\u7684Theory of Colloid and Interfacial Electric Phenomena\u4e0d\u6b62\u4e00\u6b21\uff0c\u4e5f\u627e\u4e0d\u5230\u4e66\u4e2d\u54ea\u79cd\u60c5\u51b5\u80fd\u591f\u4e0e\u6211\u7684\u5bf9\u5e94\u3002\u4e8e\u662f\u76f4\u63a5\u5199\u4fe1\u7ed9H. Ohshima\u8bf7\u6559\uff0c\u624d\u4e86\u89e3\u5230\u6211\u7684\u60c5\u51b5\u5c5e\u4e8esalt-free system\u6216\u8005counterions-only system\u3002\u4ed6\u8fd8\u4ecb\u7ecd\u6211\u770b\u4e86\u76f8\u5173\u7684\u8bba\u6587\u3002 \u5176\u5b9e\uff0c\u8fd9\u7bc7\u6587\u7ae0\u5230\u6211\u77e5\u9053\u6b63\u786e\u5bf9\u5e94\u7684\u7269\u7406\u4f53\u7cfb\u65f6\uff0c\u5df2\u7ecf\u62d6\u4e86\u5f88\u4e45\uff0c\u6211\u8001\u677f\u603b\u662f\u89c9\u5f97\u4e00\u7bc7\u6587\u7ae0\u4e0d\u503c\u5f97\u5f04\u8fd9\u4e48\u4e45\u3002\u4f46\u4ed6\u4e0d\u77e5\u9053\uff0c\u4e4b\u6240\u4ee5\u4e45\uff0c\u662f\u56e0\u4e3a\u6211\u6c34\u5e73\u5dee\u3001\u5916\u884c\u3001\u8d70\u5f2f\u8def\u3002\u4ed6\u662f\u7ecf\u8fc7\u826f\u597d\u7684\u7814\u7a76\u751f\u8bad\u7ec3\u7684\u7814\u7a76\u8005\uff0c\u6709\u4ed6\u64c5\u957f\u7684\u4e13\u4e1a\uff0c\u5728\u4ed6\u64c5\u957f\u7684\u9886\u57df\u5185\uff0c\u80fd\u591f\u4e0d\u8d70\u4f4e\u7ea7\u7684\u5f2f\u8def\u3002\u800c\u6211\u6ca1\u6709\u4ec0\u4e48\u505a\u7269\u7406\u5e94\u6709\u7684\u7406\u8bba\u57fa\u7840\uff0c\u5c31\u4f1a\u8d70\u5f2f\u8def\u3002\u6240\u4ee5\uff0c\u5b66\u5230\u4e86\u6b63\u786e\u7684\u77e5\u8bc6\u4e4b\u540e\uff0c\u7518\u613f\u518d\u82b1\u4e00\u500d\u7684\u65f6\u95f4\u91cd\u65b0\u6309\u7167\u6b63\u786e\u7684\u6a21\u578b\u53bb\u8ba1\u7b97\u3002 \u7ed3\u679c\u53d1\u73b0\uff0c\u901a\u8fc7\u5b9e\u9a8c\u6d4b\u5f97\u7684\u7c92\u5b50\u8868\u9762\u7279\u6027\uff0c\u518d\u6b63\u786e\u8003\u8651\u53cd\u79bb\u5b50\u51dd\u805a\uff0c\u5c31\u6070\u597d\u80fd\u9884\u6d4b\u51fa\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u3002\u8fd9\u662f\u8ba9\u6211\u5f88\u5174\u594b\u7684\u7ed3\u679c\u3002\u53ef\u662f\u4e00\u5f00\u59cb\u6295\u8fc7Langmuir\u548cSoft Matter\u90fd\u88ab\u79d2\u62d2\u4e86\uff0c\u5f88\u53d7\u632b\u3002\u540e\u6765\u8fd8\u662f\u6295J. Colloid Interf. Sci.\u53cd\u800c\u83b7\u5f97\u4e86\u597d\u8bc4\u3002\u8fd9\u6bb5\u8fc7\u7a0b\u8ba9\u6211\u76f8\u4fe1\uff0c\u8bba\u6587\u5c31\u5e94\u8be5\u6295\u5230\u9886\u57df\u76f8\u7b26\u7684\u671f\u520a\uff0c\u4e00\u70b9\u4e5f\u4e0d\u8981\u8ffd\u6c42\u5f71\u54cd\u56e0\u5b50\u548cJCR\u5206\u533a\u3002\u56e0\u4e3a\u53ea\u6709\u5c3d\u53ef\u80fd\u5bf9\u53e3\u7684\u540c\u884c\u624d\u6709\u5f97\u61c2\u4f60\u7684\u5de5\u4f5c\uff0c\u7406\u89e3\u4f60\u5de5\u4f5c\u7684\u91cd\u8981\u6027\uff0c\u7ed9\u4e88\u6709\u5efa\u8bbe\u6027\u7684\u610f\u89c1\u5e76\u5efa\u8bae\u53d1\u8868\u3002 \u521a\u521a\u53d1\u8868\u7684\u5de5\u4f5c\uff0c\u5219\u662f\u53c8\u5b66\u77402013\u5e74\u7684\u90a3\u7bc7Soft Matter\u90a3\u6837\uff0c\u628a\u521a\u505a\u8fc7\u52a8\u529b\u5b66\u66f2\u7ebf\u53e0\u52a0\u7684\u4f53\u7cfb\uff0c\u518d\u505a\u4e00\u6b21\u7c98\u5f39\u8c31\u53e0\u52a0\u3002\u8fd9\u5728\u5b9e\u9a8c\u4e0a\u5b9e\u5728\u662f\u7eaf\u7cb9\u7684\u91cd\u590d\uff0c\u800c\u4e14\u8ddf2013\u5e74\u7684\u60c5\u51b5\u4e00\u6837\uff0c\u6211\u4ecd\u7136\u65e0\u6cd5\u5229\u7528schematic MCT\u6a21\u578b\u5bf9\u7c98\u5f39\u8c31\u8fdb\u884c\u7406\u8bba\u8ba1\u7b97\u6bd4\u8f83\uff0c\u6ca1\u529e\u6cd5\u7a81\u7834\u3002\u4f46\u662f\uff0c\u8fd9\u65f6\u6211\u6070\u597d\u770b\u5230\u4e86H. Winter\u7684\u4e00\u7bc7\u8bba\u6587\uff0c\u63d0\u9192\u6211\u867d\u7136\u4e0d\u80fd\u4ece\u7b2c\u4e00\u6027\u539f\u7406\u6a21\u578b\u53bb\u8ba1\u7b97\u7c98\u5f39\u8c31\uff0c\u81f3\u5c11\u53ef\u4ee5\u7528\u552f\u8c61\u6a21\u578b\u62df\u5408\u51fa\u4e00\u4e2a\u8c31\u6765\u7814\u7a76\u3002\u4e8e\u662f\u5c31\u5bf9\u7ed3\u679c\u8fdb\u884c\u4e86\u8bd5\u9a8c\uff0c\u53d1\u73b0\u5728\u6211\u7684\u7ed3\u679c\u4e2d\u5c31\u6709\u6240\u8c13\u7684\u51dd\u80f6\u5230\u73bb\u7483\u7684rheological inversion\u3002\u8fd9\u4e5f\u662f\u4ee4\u6211\u89c9\u5f97\u6709\u8da3\u7684\u7ed3\u679c\uff0c\u800c\u4e14\u7ec8\u4e8e\u4f7f\u8fd9\u90e8\u5206\u5de5\u4f5c\u4e0d\u518d\u6d41\u4e8e\u7b80\u5355\u91cd\u590d\u5df2\u6709\u5de5\u4f5c\u4e86\u3002\u7531\u4e8e\u662f\u7d27\u63a5\u7740\u505a\u7684\uff0c\u4e8e\u662f\u4e5f\u60f3\u518d\u6295\u540c\u4e00\u4e2a\u671f\u520a\uff0c\u4ee5\u4e3a\u5c31\u4f1a\u987a\u5229\u53d7\u5ba1\uff0c\u7ed3\u679c\u88ab\u79d2\u62d2\uff0c\u5341\u5206\u53d7\u632b\uff0c\u6295Colloids Surf. A\u3002\u56e0\u4e3a\u6211\u4e4b\u524d\u6709\u53e6\u5916\u4e00\u4e9b\u5b9e\u9a8c\u5de5\u4f5c\u51e0\u6b21\u6295\u4e0d\u51fa\u53bb\u6700\u540e\u90fd\u6295\u5230Colloids Surf. A\u89e3\u51b3\u7684\u3002\u8fd9\u6b21\u53ea\u597d\u53c8\u5982\u6cd5\u6ce1\u5236\u3002 \u8fd8\u5728\u9001\u5ba1\u7684\u8fc7\u7a0b\u4e2d\uff0c\u6211\u53c2\u52a0\u4e86\u7f8e\u56fd\u6d41\u53d8\u5b66\u4f1a\uff0c\u5728Baltimore\u89c1\u5230\u4e86H. Winter\u672c\u4eba\u3002\u6211\u5411\u4ed6\u63cf\u8ff0\u4e86\u6211\u5bf9\u4ed6\u5de5\u4f5c\u7684\u5f15\u7528\uff0c\u4ed6\u5f88\u611f\u5174\u8da3\u3002\u4e8e\u662f\uff0c\u6211\u8868\u8fbe\u4e86\u76ee\u524d\u8fd9\u4e2a\u5de5\u4f5c\u7684\u6295\u7a3f\u72b6\u6001\uff0c\u610f\u601d\u5c31\u662f\u6c42\u4ed6\u5e2e\u5fd9\u3002\u4ed6\u7ed9\u6211\u975e\u5e38nice\u7684\u56de\u590d\u3002\u73b0\u5728\u8fd8\u662f\u987a\u5229\u53d1\u8868\u4e86\uff0c\u6211\u53ef\u4ee5\u544a\u8bc9\u4ed6\u8fd9\u4e00\u6d88\u606f\u3002 \u5728\u4ee5\u4e0a\u4e24\u4e09\u5e74\u5bf9Laponite\u7684\u7814\u7a76\u8fc7\u7a0b\uff0c\u6211\u975e\u5e38\u5c0f\u5fc3\u5730\u8003\u8651\u4e86\u5b83\u7684\u76f8\u4e92\u4f5c\u7528\u52bf\uff0c\u4e5f\u4ece\u5bf9\u5176\u52a8\u529b\u5b66\u7684\u9884\u6d4b\u7ed3\u679c\u8bc1\u660e\u4e86\u8fd9\u79cd\u8003\u8651\u7684\u5408\u7406\u6027\uff0c\u6211\u7684\u7ed3\u679c\u8bf4\u660e\u522b\u4eba\u8bf4\u662f\u73bb\u7483\u7684Laponite\u4f53\u7cfb\u5176\u5b9e\u662f\u4e0d\u53ef\u9006\u805a\u96c6\u51dd\u80f6\u3002\u4e8e\u662f\uff0c\u4ee5\u524d\u8ba4\u4e3a\u56e0\u4e3a\u662f\u73bb\u7483\u6240\u4ee5\u4e0d\u5947\u602a\u7684time-aging time […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"templates\/template-full-width.php","format":"aside","meta":{"inline_featured_image":false,"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[279],"tags":[],"class_list":["post-6765","post","type-post","status-publish","format-aside","hentry","category-279","post_format-post-format-aside"],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"","jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/p1aPvF-1L7","jetpack-related-posts":[{"id":6662,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/6662","url_meta":{"origin":6765,"position":0},"title":"\u6211\u73b0\u5728\u505a\u7814\u7a76\u7684\u65b9\u6cd5","author":"Andrew","date":"2015\u5e748\u670815\u65e5","format":"aside","excerpt":"\u7559\u610f\u5230\u4e86\u4e24\u7bc7\u7814\u7a76\u8682\u8681\u884c\u8d70\u8f68\u8ff9\u7684\u8bba\u6587\u3002\u7b2c\u4e00\u7bc7\u662f\u5b9e\u9a8c\u89c2\u5bdf\uff0c\u7b2c\u4e8c\u7bc7\u662f\u5efa\u6a21\u7684\u5de5\u4f5c\u3002\u4e3b\u8981\u7684\u53d1\u73b0\u662f\u8682\u8681\u7684\u884c\u961f\u968f\u7740\u5bc6\u5ea6\u4e0d\u65ad\u5347\u9ad8\u6ca1\u6709\u53d1\u73b0\u201c\u585e\u8f66\u201d\u7684\u73b0\u8c61\u3002\u8fd9\u4e2a\u7ed3\u8bba\u5728\u79d1\u666e\u7684\u610f\u4e49\u4e0a\u662f\u4e00\u4e2a\u5174\u594b\u70b9\uff0c\u4f46\u6211\u53ea\u6709\u65f6\u95f4\u804a\u804a\u6211\u81ea\u5df1\u7684\u4e00\u4e9b\u5fc3\u5f97\u3002 \u8fd9\u4e24\u7bc7\u6587\u7ae0\u4e2d\u7684jamming\u8ddf\u80f6\u4f53\u4f53\u7cfb\u7684jamming\u662f\u4e24\u56de\u4e8b\u3002\u524d\u8005\u662f\u6307\u4ea4\u901a\u5835\u585e\uff0c\u5c5e\u4e8eself-propelled\u4f53\u7cfb\u7684\u6027\u8d28\u3002\u4f46\u6211\u7531\u4e8e\u6b63\u5728\u505aparticle tracking\u7684\u7814\u7a76\uff0c\u6240\u4ee5\u5bf9\u8fd9\u79cd\u79bb\u6563\u4f53\u7cfb\u7684\u73b0\u8c61\u90fd\u4f1a\u5173\u6ce8\u4e00\u4e0b\u3002\u5c24\u5176\u662f\u60f3\u5411\u5404\u7c7b\u4f53\u7cfb\u7684\u7814\u7a76\u5b66\u4e60\u5982\u4f55\u91cf\u5316\u4e00\u4e2a\u73b0\u8c61\u6216\u4f53\u7cfb\u7684\u4e00\u79cd\u884c\u4e3a\uff0c\u5f97\u5230\u7269\u7406\u4e0a\u7684\u7ed3\u8bba\u3002 \u4e00\u4e2a\u7269\u7406\u4f53\u7cfb\u6216\u8005\u8fc7\u7a0b\uff0c\u4e0d\u540c\u7684\u7814\u7a76\u8005\u5728\u5b9e\u9a8c\u5ba4\u91cd\u73b0\u7684\u7ed3\u679c\u90fd\u4f1a\u6709\u4e9b\u533a\u522b\u3002\u5c5e\u4e8e\u8bef\u5dee\u7684\u90e8\u5206\uff0c\u6211\u4eec\u5c31\u4e0d\u5173\u5fc3\u4e86\uff0c\u8fd9\u4e9b\u90fd\u5c5e\u4e8e\u7269\u7406\u4e0a\u7684\u4e0d\u7406\u60f3\u6027\u3002\u4f46\u6709\u4e9b\u533a\u522b\u662f\u6765\u81ea\u4e8e\u4e0d\u540c\u7814\u7a76\u8005\u7684\u77e5\u8bc6\u80cc\u666f\u548c\u7814\u7a76\u610f\u56fe\u7684\uff0c\u6709\u4e9b\u533a\u522b\u5219\u662f\u6765\u81ea\u7279\u5b9a\u5b9e\u9a8c\u5ba4\u7684\u957f\u5904\u6216\u8005\u9650\u5236\u7684\u3002\u6211\u89c9\u5f97\u8fd9\u4e9b\u533a\u522b\u503c\u5f97\u91cd\u89c6\u3002\u6253\u4e2a\u6bd4\u65b9\uff0c\u80f6\u4f53\u60ac\u6d6e\u6db2\u4e0d\u540c\u6d53\u5ea6\u548c\u7c92\u5b50\u76f8\u4e92\u4f5c\u7528\u7684\u4f53\u7cfb\u6027\u8d28\u5927\u81f4\u90fd\u5df2\u7ecf\u4e86\u89e3\uff0c\u4f46\u6709\u4e00\u4f4d\u7814\u7a76\u8005\u7531\u4e8e\u5176\u7814\u7a76\u80cc\u666f\u7684\u60ef\u6027\u6216\u7279\u6b8a\u76ee\u7684\uff0c\u7814\u7a76\u76f8\u4e92\u4f5c\u7528\u6781\u5f3a\uff0c\u6216\u8005\u7279\u6b8a\u60ac\u6d6e\u4ecb\u8d28\u7684\u60c5\u51b5\u3002\u539f\u672c\u8be5\u7814\u7a76\u8005\u6ca1\u4ec0\u4e48\u539f\u521b\u6027\u7684\u6253\u7b97\uff0c\u51c6\u5907\u6309\u7167\u80f6\u4f53\u7684\u4e00\u822c\u7269\u7406\u6a21\u578b\u5927\u81f4\u5957\u4e00\u5957\uff0c\u5374\u53d1\u73b0\u5b8c\u5168\u65e0\u6cd5\u7406\u89e3\u81ea\u5df1\u7684\u5b9e\u9a8c\u7ed3\u679c\uff0c\u4e8e\u662f\u4e0d\u5f97\u4e0d\u91cd\u65b0\u5206\u6790\uff0c\u5f97\u51fa\u4e86\u4e00\u4e2a\u7279\u6b8a\u60c5\u51b5\u7684\u6a21\u578b\u3002\u8fd9\u79cd\u4e3a\u4e86\u8ba4\u8bc6\u81ea\u5df1\u60f3\u8981\u8ba4\u8bc6\u7684\u7279\u5b9a\u95ee\u9898\u800c\u201c\u88ab\u8feb\u201d\u4f5c\u51fa\u7684\u539f\u521b\u6027\u5de5\u4f5c\uff0c\u5e94\u8be5\u624d\u662f\u6240\u8c13\u201c\u521b\u65b0\u201d\u7684\u5e38\u89c4\u6027\u6765\u6e90\uff0c\u4e5f\u662f\u6211\u4ece\u81ea\u5df1\u6709\u9650\u7684\u7814\u7a76\u7ecf\u5386\u7684\u4f53\u4f1a\u3002\u56e0\u4e3a\uff0c\u4ee5\u6211\u7684\u8d44\u8d28\uff0c\u4ece\u9009\u9898\u4e0a\u5c31\u80fd\u505a\u5230\u6a2a\u7a7a\u51fa\u4e16\uff0c\u8fdb\u884c\u6e90\u5934\u521b\u65b0\uff0c\u6bd4\u8f83\u56f0\u96be\u3002\u6211\u4e5f\u4e0d\u662f\u90a3\u79cd\u4e00\u5929\u5230\u665a\u82e6\u601d\u51a5\u60f3\u600e\u6837\u6807\u65b0\u7acb\u5f02\u7684\u6027\u683c\uff0c\u6240\u4ee5\u6211\u867d\u7136\u662f\u6750\u6599\u5b66\u9662\u51fa\u8eab\uff0c\u4f46\u5b9e\u5728\u4e0d\u9002\u5e94\u529f\u80fd\u6750\u6599\u7814\u7a76\uff0c\u8d8a\u505a\u8d8a\u9760\u7269\u7406\u7684\u7f18\u6545\u3002\u66f4\u591a\u7684\u65f6\u5019\uff0c\u6211\u90fd\u662f\u4ece\u6211\u7684\u5b9e\u9a8c\u4e2d\u53d1\u73b0\u4e86\u67e5\u6587\u732e\u65e0\u6cd5\u5f88\u597d\u5730\u56de\u7b54\u7684\u5c0f\u73b0\u8c61\uff0c\u5b83\u4e5f\u8bb8\u5f88\u6b21\u8981\uff0c\u5728\u5927\u7269\u7406\u5b66\u5bb6\u773c\u4e2d\u5c5e\u4e8e\u975e\u5e38trivial\u7684\u95ee\u9898\uff0c\u4f46\u5f53\u65f6\u4f5c\u4e3a\u5b66\u751f\u8fd9\u662f\u6211\u63d0\u51fa\u731c\u60f3\uff08hypothesis\uff09\uff0c\u8fdb\u884c\u7b80\u5355\u63a8\u7406\uff0c\u7136\u540e\u5b9e\u9a8c\u9a8c\u8bc1\u7684\u7ec3\u4e60\u673a\u4f1a\uff0c\u4e5f\u662f\u8003\u9a8c\u6211\u5404\u65b9\u9762\u57fa\u672c\u529f\u7684\u673a\u4f1a\uff0c\u6240\u4ee5\u6211\u7279\u522b\u559c\u6b22\u94bb\u8fd9\u4e9b\u95ee\u9898\u3002 \u6709\u65f6\uff0c\u4f60\u770b\u7684\u7269\u7406\u8fc7\u7a0b\u662f\u5f88\u591a\u4eba\u62a5\u5bfc\u8fc7\u7684\u3002\u4f46\u662f\u4f60\u4eb2\u81ea\u505a\u8fd9\u4e2a\u5b9e\u9a8c\uff0c\u5c31\u4f1a\u89c9\u5f97\u539f\u59cb\u6570\u636e\u4e2d\u7684\u4fe1\u606f\u8fdc\u6bd4\u4f60\u4ece\u8bba\u6587\u770b\u5230\u7684\u8981\u4e30\u5bcc\u5f97\u591a\u3002\u8bba\u6587\u5f80\u5f80\u90fd\u6293\u4f4f\u6700\u91cd\u8981\u7684\u7279\u5f81\u8fdb\u884c\u62bd\u8c61\u548c\u91cf\u5316\u3002\u4f60\u53ea\u770b\u8bba\u6587\uff0c\u5c31\u4ee5\u4e3a\u8fd9\u4e2a\u7269\u7406\u73b0\u8c61\u9664\u4e86\u8fd9\u4ef6\u4e8b\u5c31\u6ca1\u522b\u7684\u4e8b\u4e86\u3002\u4eb2\u81ea\u770b\u4e86\u539f\u59cb\u73b0\u8c61\uff0c\u4f60\u5f80\u5f80\u4f1a\u88ab\u53e6\u4e00\u4e9b\u62a5\u9053\u5f88\u5c11\u5173\u6ce8\u7684\u7279\u5f81\u6240\u5438\u5f15\u3002\u8fd9\u65f6\uff0c\u5982\u4f55\u91cf\u5316\u8fd9\u4e9b\u7279\u6b8a\u7684\u884c\u4e3a\u7279\u5f81\uff0c\u4f60\u6ca1\u6709\u8303\u4f8b\uff0c\u4e0d\u80fd\u201c\u7167\u7740\u522b\u4eba\u53d1\u8868\u7684\u8bba\u6587\u6765\u505a\u201d\u3002\u5230\u5e95Fig. 1\u662f\u4ec0\u4e48\u7269\u7406\u91cf\uff0cFig. 2\u53c8\u63a8\u5bfc\u51fa\u4ec0\u4e48\u7269\u7406\u91cf\uff0c\u600e\u6837\u80fd\u591f\u6df1\u5165\u5730\u5206\u6790\uff0c\u4ee5\u8fbe\u5230\u8981\u7528\u4e09\u5230\u4e94\u4e2afigure\u7684\u6df1\u5ea6\uff1f\u5f52\u6839\u7ed3\u5e95\u5c31\u662f\u505a\u8fd9\u4e09\u4ef6\u4e8b\uff1a\u627e\u7eb5\u5750\u6807\u3001\u627e\u6a2a\u5750\u6807\u548c\u6c42\u5bfc\u3002\u8fd9\u4e2a\u91cf\u5316\u7684\u8fc7\u7a0b\uff0c\u662f\u4e00\u4e2a\u6570\u5b66\u5206\u6790\u7684\u57fa\u672c\u529f\u3002\u6240\u4ee5\uff0c\u73b0\u5728\u6211\u770b\u8bba\u6587\uff0c\u90fd\u60f3\u4ece\u5176\u4ed6\u9886\u57df\u7684\u7814\u7a76\u4e2d\u5b66\u4e60\u8fd9\u65b9\u9762\u7684\u7ecf\u9a8c\u3002","rel":"","context":"In "\u5de5\u4f5c\u7b14\u8bb0"","block_context":{"text":"\u5de5\u4f5c\u7b14\u8bb0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/personal\/%e5%b7%a5%e4%bd%9c%e7%ac%94%e8%ae%b0"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":6205,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/6205","url_meta":{"origin":6765,"position":1},"title":"\u65b0\u53d1\u8868\u6587\u7ae0\u7684\u81f4\u8c22","author":"Andrew","date":"2015\u5e741\u670817\u65e5","format":"aside","excerpt":"[latexpage] \u6211\u7684\u4e00\u7bc7\u6587\u7ae0\u5728Journal of Colloid and Interface Science\u4e0a\u53d1\u8868\u4e86\u3002\u7b2c\u4e00\u4f5c\u8005\u662f\u5b9e\u9a8c\u7684\u5b8c\u6210\u4eba\uff0c\u6211\u5bf9\u5b9e\u9a8c\u7ed3\u679c\u8fdb\u884c\u4e86\u7406\u8bba\u5206\u6790\u3002\u5177\u4f53\u5185\u5bb9\u53ef\u4ee5\u76f4\u63a5\u53bb\u4e0b\u8f7d\u8bba\u6587\u770b\u3002 \u8fd9\u4e2a\u5de5\u4f5c\u4ece\u5b9e\u9a8c\u5b8c\u6210\u5230\u53d1\u8868\u62d6\u4e86\u5f88\u957f\uff0c\u4e3b\u8981\u65f6\u95f4\u82b1\u5728\u7406\u8bba\u5206\u6790\u90e8\u5206\u3002\u4e00\u5f00\u59cb\u6211\u5e76\u4e0d\u6e05\u695a\u53cd\u79bb\u5b50\u51dd\u805a\uff0c\u53ea\u662f\u53d1\u73b0\u7c98\u571f\u8868\u9762\u7535\u8377\u5bc6\u5ea6\u592a\u5927\uff0c\u800c\u4e14\u5904\u4e8e\u975e\u5bf9\u79f0\uff08asymmetric\uff09\u7684\u7535\u89e3\u8d28\u73af\u5883\uff0c\u56e0\u6b64\u7c92\u5b50\u95f4\u7684\u53cc\u7535\u5c42\u4f5c\u7528\u4e0d\u80fd\u91c7\u7528Debye-H\u00fcckel\u8fd1\u4f3c\uff0c\u4e8e\u662f\u67e5\u5230\u4e86Ohshima\u63a8\u5bfc\u7684\u4e00\u4e2aPoisson-Boltzmann\u7684\u7cbe\u786e\u89e3\u3002\u53ef\u662f\u7528\u8fd9\u4e2a\u89e3\u6765\u8ba1\u7b97\u76f8\u4e92\u4f5c\u7528\u7684\u65f6\u5019\u603b\u662f\u5f97\u51fanonphysical\u7684\u7ed3\u679c\u3002\u6709\u6000\u7591\u8fc7\u81ea\u5df1\u6570\u503c\u8ba1\u7b97\u7684\u4ee3\u7801\u6709\u95ee\u9898\uff0c\u518d\u4e09\u68c0\u9a8c\u548c\u8bf7\u6559\u8fc7\u6bd4\u8f83\u719f\u7684\u4eba\u4e4b\u540e\u4e5f\u6392\u9664\u4e86\u3002\u8fd9\u671f\u95f4\u8001\u677f\u4e5f\u50ac\u8fc7\uff0c\u4ed6\u4e0d\u77e5\u9053\u8fd9\u4e9b\u5177\u4f53\u7684\u7ec6\u8282\uff0c\u5c31\u53ea\u89c9\u5f97\u6ca1\u5fc5\u8981\u62d6\u8fd9\u4e48\u4e45\uff0c\u6211\u4e0d\u5f97\u4e0d\u76f4\u63a5\u8bf4\u6211\u8fd9\u4e2a\u53ef\u80fd\u4f1a\u62d6\u5f88\u4e45\uff0c\u56e0\u4e3a\u6211\u8981\u8ba4\u771f\u641e\u61c2\u8fd9\u4e2a\u95ee\u9898\u3002\u7b2c\u4e00\u4f5c\u8005\u7684\u5b66\u751f\u5bf9\u6211\u5c31\u66f4\u6ca1\u64a4\u4e86\u3002\u73b0\u5728\u6211\u8fd8\u5f97\u8c22\u8c22\u4ed6\u5e2e\u6211\u505a\u4e86\u8fd9\u4e48\u591a\u5b9e\u9a8c\uff0c\u8fd8\u5f97\u88ab\u6211\u538b\u7740\u4e0d\u53d1\u8868\u3002\u8981\u4e0d\u662f\u4ed6\u62fc\u547d\u505a\u5b9e\u9a8c\uff0c\u6211\u521a\u5de5\u4f5c\u7684\u8fd9\u4e24\u5e74\u53ef\u80fd\u90fd\u6ca1\u529e\u6cd5\u6709\u8fd9\u4e48\u51e0\u7bc7\u6587\u7ae0\u5411\u5916\u754c\u4ea4\u5dee\u3002\u8bf4\u56de\u5230\u8ba1\u7b97\u7684\u95ee\u9898\uff0c\u540e\u6765\u6211\u5b9e\u5728\u6ca1\u529e\u6cd5\uff0c\u60f3\u627eOhshima\u672c\u4eba\u95ee\u4e00\u4e0b\u3002\u5176\u5b9e\u4e4b\u524d\u4e00\u76f4\u4ee5\u4e3aOhshima\u662f\u4e00\u4e2a\u8fc7\u4e16\u4e86\u7684\u4eba\uff0c\u6240\u4ee5\u9047\u5230\u95ee\u9898\u4e00\u76f4\u90fd\u6ca1\u60f3\u8fc7\u53bb\u95ee\u672c\u4eba\u3002\u76f4\u5230\u6700\u540e\u6211\u60f3\u67e5\u4ed6\u7684\u5de5\u4f5c\u7684\u540e\u7eed\u5f15\u7528\u60c5\u51b5\uff0c\u770b\u770b\u522b\u4eba\u662f\u600e\u4e48\u4f7f\u7528\u4ed6\u7684\u7ed3\u679c\u7684\uff0c\u53d1\u73b0\u4f7f\u7528\u4ed6\u7ed3\u679c\u7684\u4eba\u51e0\u4e4e\u6ca1\u6709\uff0c\u4f46\u4ed6\u81ea\u5df1\u6709\u53d1\u8868\u65b0\u7684\u6587\u7ae0\uff0c\u6700\u65b0\u7684\u6709\u5230200X\u5e74\uff0c\u4e8e\u662f\u624d\u611f\u89c9\u8fd9\u4e2a\u4eba\u53ef\u80fd\u662f\u8fd8\u5728\u751f\u7684\u4eba\u3002\u7ecf\u8fc7\u4e00\u756a\u641c\u7d22\uff0c\u624d\u627e\u5230\u4ed6\u7684\u9875\u9762\u4ee5\u53caemail\uff0c\u539f\u6765\u662f\u4e2a\u521a\u9000\u4f11\u7684\u7814\u7a76\u6240\u6240\u957f\u3002\u5f88\u5feb\u5c31\u6536\u5230\u4e86\u4ed6\u7684\u56de\u4fe1\uff0c\u591a\u6b21\u6765\u5f80\u4e4b\u540e\uff0c\u6211\u624d\u77e5\u9053\uff0c\u6211\u7684\u4f53\u7cfb\u5c5e\u4e8esalt-free systems\u6216\u8005counterions only system\uff0c\u6240\u4ee5\u53cd\u79bb\u5b50\u6d53\u5ea6\u662f\u4e0d\u53ef\u5ffd\u7565\u7684\uff0c\u9ad8\u7535\u8377\u5bc6\u5ea6\u65f6\u4f1a\u53d1\u751f\u53cd\u79bb\u5b50\u51dd\u805a\u3002\u8fd9\u5e94\u8be5\u662f\u4e2a\u5e38\u8bc6\u4e86\uff0c\u65e0\u5948\u6211\u77e5\u8bc6\u8fd8\u662f\u6b20\u7f3a\uff0c\u5168\u8d56\u4ed6\u7684\u6307\u70b9\u3002\u4e8e\u662f\u6211\u624d\u91cd\u65b0\u6309\u7167\u53cd\u79bb\u5b50\u51dd\u805a\u7684\u89d2\u5ea6\u6765\u601d\u8003\u6211\u7684\u4f53\u7cfb\u3002 \u5728\u53cd\u79bb\u5b50\u51dd\u805a\u7684\u7814\u7a76\u4e2d\uff0c\u5927\u90e8\u5206\u662f\u8003\u8651\u67f1\u72b6\u7684\u5e26\u7535\u8868\u9762\u7684\uff0c\u4e3b\u8981\u9762\u5411\u7684\u5b9e\u9645\u4f53\u7cfb\u662f\u805a\u7535\u89e3\u8d28\uff08\u5305\u62ecDNA\uff09\u6eb6\u6db2\uff0c\u53c8\u53ebManning condensation\u3002\u7403\u72b6\u7684\u7814\u7a76\u6bd4\u8f83\u5c11\uff0c\u7ecf\u5e38\u53eb\u6210charge renormalization\u3002Manning\u81ea\u5df1\u4e5f\u8003\u8651\u8fc7\u7403\u72b6\u7684\u4f53\u7cfb\uff0c\u4ed6\u7684two-state model\u662f\u4ece\u8003\u8651\u81ea\u7531\u80fd\u51fa\u53d1\uff0c\u8ba4\u4e3a\u7cbe\u786e\u7684\u7ed3\u679c\u8ddfDH\u8fd1\u4f3c\u4e4b\u95f4\u5c31\u662f\u5dee\u4e00\u4e2a\u7cfb\u6570\uff0c\u8fd9\u4e2a\u7cfb\u6570\u7b80\u5355\u5730\u8ba4\u4e3a\u662f\u4e2a\u975e\u51dd\u805a\u79bb\u5b50\u7684\u6bd4\u4f8b\u7cfb\u6570$(1-z\\theta)$\uff0c\u5176\u4e2d$\\theta$\u662f\u51dd\u805a\u79bb\u5b50\u6240\u5360\u6bd4\u4f8b\u3002\u4ed6\u7684\u903b\u8f91\u5176\u5b9e\u662f\u975e\u5e38\u7b03\u5b9a\u201c\u53cd\u79bb\u5b50\u51dd\u805a\u201d\u7684\u56fe\u50cf\uff0c\u8ba4\u4e3a\u6709\u975e\u5e38\u786e\u5b9a\u6570\u91cf\u7684\u53cd\u79bb\u5b50\u53d1\u751f\u4e86\u201c\u51dd\u805a\u201d\u3002\u7136\u540e\uff0c\u901a\u8fc7\u81ea\u7531\u80fd\u6700\u5c0f\u5316\u6765\u6c42\u5f97$\\theta$\u7684\u8868\u8fbe\u5f0f\u3002\u800c\u5219\u662f\u7528cell model\u6765\u6c42\u89e3Poisson-Boltzmann\u65b9\u7a0b\uff0c\u8bc1\u5b9e\u4e86\u7684\u786e\u53ef\u4ee5\u8fdb\u884c\u8868\u9762\u7535\u8377\uff08\u52bf\uff09\u7684\u7b49\u6548\u3002\u7684\u5de5\u4f5c\u867d\u7136\u88ab\u591a\u6b21\u5f15\u7528\uff0c\u4f46\u5c40\u9650\u4e8e\u7406\u8bba\u7814\u7a76\u7684\u5708\u5b50\u4e4b\u5185\u3002\u5f88\u5c11\u6709\u7528\u4ed6\u7684\u7ed3\u679c\u89e3\u91ca\u5b9e\u9a8c\u7684\u5de5\u4f5c\u3002\u505a\u4e86\u4e00\u4e2asalt-free\u4f53\u7cfb\u7684\u7535\u6cf3\u5b9e\u9a8c\u5e76\u4e14\u8fdb\u884c\u4e86\u7406\u8bba\u63cf\u8ff0\uff0c\u4f7f\u7528\u4e86\u4e00\u4e2a\u4e0e\u7c7b\u4f3c\u7684approach\u3002\u6211\u7684\u8bba\u6587\u76f4\u63a5\u7528\u4e86\u7684\u7ed3\u679c\u6765\u8ba1\u7b97\u76f8\u4e92\u4f5c\u7528\u52bf\u80fd$U\\left(h\\right)$\uff0c\u7136\u540e\u8fdb\u4e00\u6b65\u8ba1\u7b97RLCA\u7684stability ratio\uff0c\u5f97\u51fa\u4e0e\u5b9e\u9a8c\u6bd4\u8f83\u543b\u5408\u7684\u7ed3\u679c\uff0c\u5e94\u8be5\u662f\u7b2c\u4e00\u4e2a\u3002 \u6211\u7684\u6587\u7ae0\u53d1\u8868\u65f6\uff0c\u5ba1\u7a3f\u4eba\u4e5f\u663e\u793a\u51fa\u6bd4\u8f83\u9ad8\u7684\u5174\u8da3\uff0c\u8bf4\u6211\u8fd9\u662f\u4e00\u7bc7excellent paper\uff0c\u6709\u4e00\u6761\u4fee\u6539\u610f\u89c1\u8fd8\u662f\u201cThis is an interesting point that should be explored and highlighted further.\u201d \u867d\u7136\u6211\u6587\u7ae0\u7684\u81f4\u8c22\u91cc\u5df2\u7ecf\u611f\u8c22\u4e86Ohshima\uff0c\u4f46\u603b\u89c9\u5f97\u8fd8\u662f\u8981\u4eb2\u81ea\u611f\u8c22\u4ed6\u3002\u6587\u7ae0\u53d1\u8868\u540e\uff0c\u6211\u7ed9Ohshima\u56de\u4fe1\u611f\u8c22\u4ed6\uff0c\u628a\u6587\u7ae0\u7684PDF\u7ed9\u4ed6\u770b\u4e86\u3002\u4ed6\u4e5f\u56de\u4fe1\u5bf9\u6211\u8fdb\u884c\u4e86\u9f13\u52b1\uff1a Dear Dr. Weixiang Sun Thank you very much for sending me your excellent work. Congratulations! I have read your\u2026","rel":"","context":"In "\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0"","block_context":{"text":"\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/tagged"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":9291,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/9291","url_meta":{"origin":6765,"position":2},"title":"\u201c\u5fae\u6d41\u53d8\u201d\u672f\u8bed\u53f2","author":"Andrew","date":"2025\u5e7410\u670819\u65e5","format":false,"excerpt":"\u201c\u5fae\u6d41\u53d8\u201d\uff08microrheology\uff09\u5728\u6700\u8fd1\u51e0\u5e74\u7684\u6587\u732e\u4e2d\u662f\u4e13\u6307III. \u901a\u8fc7\u80f6\u4f53\u7c92\u5b50\u7684\u70ed\u8fd0\u52a8\u7edf\u8ba1\u89c4\u5f8b\u53cd\u63a8\u60ac\u6d6e\u4ecb\u8d28\u7684\u6d41\u53d8\u6027\u8d28\u7684\u4e00\u79cd\u5b9e\u9a8c\u7814\u7a76\u3002\u8fd9\u4e5f\u662f\u6211\u73b0\u5728\u7814\u7a76\u65b9\u5411\u4e4b\u4e00\u3002\u4f46\u662f\uff0c\u8fd9\u4e2a\u672f\u8bed\u6700\u65e9\u7684\u610f\u4e49\u8ddf\u73b0\u5728\u6709\u4e9b\u533a\u522b\u3002 \u6839\u636e\u6211\u67e5\u5230\u7684\u7ed3\u679c\uff0c\u201cmicrorheology\u201d\u4e00\u8bcd\u6700\u65e9\u51fa\u73b0\u5728M. Reiner\u7684\u6d41\u53d8\u5b66\u8bb2\u4e49\uff08Markus Reiner (1943), Ten Lectures on Theoretical Rheology, Rubin Mass\uff09\u4e2d\u7684\u7b2c\u4e03\u8bb2\u3002\u8fd9\u4e2a\u5957\u8bb2\u4e49\u540e\u6765\u5206\u522b\u57281949\u5e74\u548c1960\u5e74\u51fa\u4e86\u7b2c\u4e8c\u548c\u7b2c\u4e09\u7248\u3002\u7b2c\u4e09\u7248\u6709\u4e2d\u8bd1\u672c\uff1aM. \u96f7\u8bb7\u8457\uff0c\u90ed\u6709\u4e2d\u7b49\u8bd1\u300a\u7406\u8bba\u6d41\u53d8\u5b66\u8bb2\u4e49\u300b\uff0c\u7531\u79d1\u5b66\u51fa\u7248\u793e\u4e8e1965\u51fa\u7248\u3002\u5728\u5f53\u65f6\u8fd9\u4e2a\u8bcd\u5927\u6982\u662f\u6307I. \u4ece\u5fae\u89c2\u7ed3\u6784\u63a8\u51fa\u5b8f\u89c2\u7cfb\u7edf\u6d41\u53d8\u5b66\u6027\u8d28\u7684\u7406\u8bba\u7814\u7a76\uff0c\u4f3c\u4e4e\u662f\u7528\u4e8e\u4e0e\u57fa\u4e8e\u8fde\u7eed\u4ecb\u8d28\u5047\u5b9a\u7684\u7406\u8bba\u76f8\u533a\u522b\u3002\u540e\u8005\u88ab\u79f0\u4f5c\u201cmacrorheology\u201d\u3002 \u5927\u6982\u76f8\u540c\u7684\u65f6\u671f\uff0c\u80f6\u4f53\u7c92\u5b50\u60ac\u6d6e\u6db2\u6d41\u53d8\u5b66\u7684\u5148\u9a71Stanley G. Mason\uff081914-1987\uff09\u5927\u91cf\u4f7f\u7528\u8fd9\u4e2a\u8bcd\u6765\u63cf\u8ff0\u4ed6\u7814\u7a76\u7684\u95ee\u9898\u3002\u5173\u4e8eMason\u7ecf\u5386\u7684\u4e00\u4e9b\u8d44\u6599\u53ef\u89c1\u4ed6\u7684\u81ea\u8ff0\u548c\u540e\u8f88\u5199\u7684appreciation\u3002Mason\u57281950\u5e74\u4ee3\u5c31\u5f00\u59cb\u6b63\u5f0f\u7814\u7a76\u60ac\u6d6e\u7c92\u5b50\u7684\u6d41\u4f53\u52a8\u529b\u5b66\u3002\u4ed6\u521b\u7acb\u7684\u7814\u7a76\u65b9\u6cd5\u662fII. \u901a\u8fc7\u5b9e\u9a8c\u89c2\u5bdf\u7c92\u5b50\u5468\u56f4\u7684\u6d41\u573a\u6765\u9a8c\u8bc1\u6d41\u4f53\u52a8\u529b\u5b66\u7406\u8bba\u3002\u56e0\u6b64\uff0c\u5230\u4e86Mason\u8fd9\u91cc\uff0c\u201cmicrorheology\u201d\u7684\u610f\u4e49\u5c31\u4ece\u7406\u8bba\u6a21\u578b\u53d8\u4e3a\u5b9e\u9a8c\u624b\u6bb5\u3002Mason\u4e5f\u63a8\u5bfc\u8fc7\u80f6\u4f53\u6d41\u53d8\u5b66\u7406\u8bba\uff0c\u4f46\u4ed6\u548c\u4ed6\u7684\u5b66\u751f\u4e0d\u7528\u201cmicrorheology\u201d\u4e00\u8bcd\u63cf\u8481\u8fd9\u4e9b\u7406\u8bba\u5de5\u4f5c\u3002 Mason\u7684\u53ca\u5176\u5b66\u751f\u7684\u540e\u7eed\u5de5\u4f5c\u4e00\u76f4\u6301\u7eed\u52301970\u5e74\u4ee3\u3002\u5728\u8fd9\u6bb5\u65f6\u95f4\uff0c\u201cmicrorheology\u201d\u4e00\u8bcd\u51e0\u4e4e\u53ea\u51fa\u73b0\u5728\u4ed6\u4eec\u53d1\u8868\u7684\u5de5\u4f5c\u5f53\u4e2d\u3002\u4e5f\u6709\u96f6\u661f\u613f\u610f\u4f7f\u7528Reiner\u8bb2\u4e49\u7684\u8001\u610f\u4e49\u7684\u8bba\u6587\uff0c\u5305\u62ec\u51af\u5143\u6862\u5148\u751f\u30021970\u5e74\u4ee3\uff0c\u201cmicrorheology\u201d\u4e00\u8bcd\u88ab\u8840\u6db2\u6d41\u53d8\u5b66\u9886\u57df\u5927\u91cf\u91c7\u7528\uff0c\u8fd9\u4e5f\u4ecd\u662f\u5f52\u56e0\u4e8eMason\u7684\u5de5\u4f5c\u5bf9\u8fd9\u4e00\u9886\u57df\u7684\u5f71\u54cd\u529b\u3002 \u6211\u80fd\u627e\u5230\u7684\u7b2c\u4e00\u4e2a\u610f\u4e49\u53d8\u6210\u73b0\u5728\u7684\u7b2cIII\u79cd\u7684\u6700\u65e9\u8bba\u6587\u662f1985\u5e74\u7684\u4e00\u7bc7\u8bba\u6587\u3002 \u4e0e\u201cmicrorheology\u201d\u4e00\u8bcd\u5341\u5206\u76f8\u5173\u7684\u8fd8\u6709\u201cmicroviscosity\u201d\u3002\u8fd9\u4e2a\u8bcd\u53cd\u800c\u6700\u65e9\u5c31\u8fbe\u5230\u4e86\u4eca\u5929\u5bf9microrheology\u5e94\u8be5\u8fbe\u5230\u7684\u7406\u89e3\u3002\u57281929\u5e74\u7684\u7b2c\u4e00\u5c4a\u7f8e\u56fd\u6d41\u53d8\u5b66\u5e74\u4f1a\u4e0a\uff0cE. Kraemer & R. Williamson\u533a\u5206\u4e86\u51e0\u4e2a\u5c42\u6b21\u7684\u201c\u6469\u64e6\u201d\uff08friction\uff09\u3002\u4e00\u662f\u5b8f\u89c2\u4f53\u7cfb\u7684\u7c98\u5ea6\uff0c\u4e8c\u662f\u7c92\u5b50\u4e0e\u5468\u56f4\u6d41\u573a\u754c\u9762\u5904\u7684\u6469\u64e6\uff0c\u4e09\u662f\u7c92\u5b50\u5f62\u53d8\u7684\u5185\u90e8\u6469\u64e6\u3002\u201cmicroviscosity\u201d\u6307\u7684\u5c31\u662f\u5728IV. \u5fae\u89c2\u5c3a\u5ea6\u4e0b\u7684\u7c98\u5ea6\u2014\u2014\u5b83\u5e38\u5e38\u4e0e\u5b8f\u89c2\u5c3a\u5ea6\u4e0b\u5bf9\u540c\u4e00\u7cfb\u7edf\u6d4b\u5f97\u7684\u7c98\u5ea6\u660e\u663e\u4e0d\u540c\u3002\u8fd9\u4ef6\u4e8b\u65e9\u5728\u201c\u80f6\u4f53\u201d\uff08colloid\uff09\u4e00\u8bcd\u7684\u675c\u64b0\u8005Thomas Graham\u57281861\u5e74\u7684\u7814\u7a76\u4e2d\u5c31\u53d1\u73b0\u4e86\u3002\u76d0\u5728\u660e\u80f6\u6216\u743c\u8102\u51dd\u80f6\u4e2d\u7684\u6269\u6563\u6bd4\u5c11\u6162\u4e0d\u4e86\u591a\u5c11\uff0c\u4f46\u524d\u8005\u7684\u7c98\u5ea6\u6bd4\u6c34\u9ad8\u597d\u51e0\u4e2a\u6570\u91cf\u7ea7\u3002\u56e0\u6b64\u8fd9\u4ee4\u4eba\u76f8\u4fe1\uff0c\u5fae\u89c2\u5c3a\u5ea6\u7269\u4f53\u611f\u53d7\u5230\u7684\u6db2\u4f53\u7684\u7c98\u5ea6\u662f\u8ddf\u5b8f\u89c2\u6d4b\u91cf\u503c\u4e0d\u540c\u7684\u3002\u5177\u4f53\u5728\u8fd9\u4e00\u5b9e\u9a8c\u73b0\u8c61\u4e2d\uff0c\u7814\u7a76\u8005\u751a\u81f3\u662f\u901a\u8fc7\u6269\u6563\u7684\u6548\u679c\u6765\u7406\u89e3\u7c98\u5ea6\u3002\u8fd9\u662f\u5728Einstein--Stokes\u5173\u7cfb\u7684\u7406\u8bba\u57fa\u7840\u4e0a\u7684\u8ba4\u8bc6\u89d2\u5ea6\uff0c\u628a\u5b9e\u9a8c\u7ed3\u679c\u5173\u4e8eEinstein--Stokes\u5173\u7cfb\u7684\u504f\u79bb\u5f53\u4f5c\u7c98\u5ea6\u4e0d\u540c\u3002\u4eca\u5929\u6211\u4eec\u8fd8\u6709\u53e6\u4e00\u79cd\u505a\u6cd5\uff0c\u90a3\u5c31\u662f\u628a\u5b9e\u9a8c\u7ed3\u679c\u5173\u4e8eEinstein--Stokes\u5173\u7cfb\u7684\u504f\u79bb\u5f53\u4f5c\u534a\u5f84\u4e0d\u540c\uff0c\u5b9a\u4e49\u51fa\u201c\u6d41\u4f53\u52a8\u529b\u5b66\u534a\u5f84\u201d\u3002\u8fd9\u4e24\u54b1\u505a\u6cd5\u7684\u4eba\u4e4b\u95f4\u5f88\u5c11\u770b\u5230\u6709\u4ea4\u53c9\u7684\uff0c\u66f4\u522b\u8bf4\u6709\u4eba\u53bbreconcile\u8fd9\u4e24\u8005\u3002\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u5b9e\u9a8c\u65b9\u6cd5\u4e0d\u540c\u3002\u4e00\u6d3e\u4eba\u6d4b\u91cf\u5b8f\u89c2\u7cfb\u7edf\u7684\u7c98\u5ea6\uff0c\u548c\u5206\u5b50\u7684\u6269\u6563\u7cfb\u6570\u3002\u7531\u4e8e\u5206\u5b50\u7ed3\u6784\u662f\u660e\u786e\u7684\uff0c\u8fd9\u6d3e\u4eba\u662f\u4e0d\u4f1a\u6000\u7591\u5206\u5b50\u8fd8\u6709\u53e6\u4e00\u79cd\u201c\u534a\u5f84\u201d\u3002\u53e6\u4e00\u6d3e\u4eba\u7528\u52a8\u6001\u5149\u6563\u5c04\u6d4b\u80f6\u4f53\u7c92\u5b50\u5728\u60ac\u6d6e\u6db2\u4e2d\u6216\u805a\u5408\u7269\u5728\u6eb6\u6db2\u4e2d\u7684\u534a\u5f84\uff0c\u5e76\u4e0e\u7535\u5b50\u663e\u5fae\u955c\u6216\u89d2\u5ea6\u4f9d\u8d56\u6563\u5c04\u7684\u7ed3\u679c\uff08\u5747\u65b9\u56de\u8f6c\u534a\u5f84\uff09\u76f8\u6bd4\u8f83\u3002\u7279\u522b\u662f\u5bf9\u4e8e\u805a\u5408\u7269\u8bd5\u6837\uff0c\u7531\u4e8e\u5176\u5206\u5b50\u5c3a\u5bf8\u53ea\u6709\u5e73\u5747\u6982\u5ff5\uff0c\u5728\u6eb6\u6db2\u4e2d\u7684\u5e73\u5747\u5c3a\u5bf8\u8fd8\u53d7\u6eb6\u5242\u6eb6\u8d28\u76f8\u4e92\u4f5c\u7528\u4ee5\u53ca\u6d41\u4f53\u52a8\u529b\u5b66\u76f8\u4e92\u4f5c\u7528\u7684\u5f71\u54cd\u3002\u800c\u6269\u6563\u7cfb\u6570\u88ab\u9690\u542b\u5728\u52a8\u6001\u5149\u6563\u5c04\u7684\u57fa\u672c\u539f\u7406\u5f53\u4e2d\u3002","rel":"","context":"In "\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0"","block_context":{"text":"\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/tagged"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":5675,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/5675","url_meta":{"origin":6765,"position":3},"title":"\u7a33\u6001\u526a\u5207\u4e0b\u7684\u7ed3\u6784\u677e\u5f1b","author":"Andrew","date":"2013\u5e749\u670819\u65e5","format":false,"excerpt":"\u4e2d\u79cb\u8fd9\u4e24\u5929\u5047\u671f\uff0c\u6211\u90fd\u5728\u770bmode coupling theory\u7684\u6587\u732e\u3002\u82b1\u4e86\u5f88\u591a\u529f\u592b\uff0c\u7ed3\u679c\u5565\u4e5f\u6ca1\u771f\u6b63\u770b\u61c2\u3002\u4ee5\u540e\u53ef\u80fd\u4e0d\u4f1a\u518d\u50cf\u8fd9\u4e24\u5929\u8fd9\u4e48\u8ba4\u771f\u5730\u53bb\u770b\u8fd9\u73a9\u610f\u4e86\uff0c\u6240\u4ee5\u597d\u6b79\u8bb0\u5f55\u4e00\u4e0b\u3002 Time-shear superposition \u5bf9\u8fc7\u51b7\u6db2\u4f53\u7684\u6a21\u62df\u7814\u7a76\u53d1\u73b0\uff0c\u5728\u65bd\u52a0\u4e00\u4e2a\u7a33\u6001\u526a\u5207\u65f6\uff0c\u5176\u5bc6\u5ea6\u6216\u6563\u5c04\u81ea\u76f8\u5173\u51fd\u6570\u7684\u03b1\u677e\u5f1b\u968f\u589e\u5927\u5411\u77ed\u65f6\u95f4\u65b9\u5411\u79fb\u52a8\uff0c\u677e\u5f1b\u65f6\u95f4\u51cf\u5c0f\u3002\u5982\u679c\u628a\u4e0d\u540c\u7684\u81ea\u76f8\u5173\u51fd\u6570\u6539\u5bf9\u4e00\u4e2a\u7ea6\u5316\u7684\u65f6\u95f4t\/\u03c4\u4f5c\u56fe\uff0c\u5404\u66f2\u7ebf\u7684\u03b1\u677e\u5f1b\u90e8\u5206\u80fd\u591f\u53e0\u52a0\u6210\u4e00\u6761\u4e3b\u66f2\u7ebf\u3002\u03c4\u8ddf\u7684\u5173\u7cfb\u5f80\u5f80\u5177\u6709\u7684\u5f62\u5f0f\uff0ca\u5f88\u63a5\u8fd11\u3002\u8fd9\u4e2a\u73b0\u8c61\u8bf4\u660e\uff0c\u7a33\u6001\u526a\u5207\u80fd\u591f\u7f29\u77ed\u03b1\u677e\u5f1b\u7684\u65f6\u95f4\u5c3a\u5ea6\uff0c\u4f46\u4e0d\u6539\u53d8\u677e\u5f1b\u66f2\u7ebf\u7684\u5f62\u72b6\uff0c\u8fd9\u4e00\u73b0\u8c61\u53c8\u88ab\u79f0\u4e3atime-shear superposition\u3002 Strain rate-frequency superposition 2007\u5e74Wyss\u7b49\u62a5\u9053\uff0c\u5728\u51e0\u79cd\u4e0d\u540c\u7684\u6d53\u80f6\u4f53\u4f53\u7cfb\u90fd\u5448\u73b0\u6240\u8c13strain rate-frequency superposition\uff08SRFS\uff09\uff1a\u5bf9\u6837\u54c1\u65bd\u52a0\u632f\u8361\u526a\u5207\uff0c\u5728\u6052\u5b9a\u5e94\u53d8\u901f\u7387\u5e45\u503c\u6761\u4ef6\u4e0b\u626b\u9891\u7387\uff0c\u5f97\u5230G'(\u03c9)\u3001G''(\u03c9)\u66f2\u7ebf\u3002\u6052\u5b9a\u4e0d\u540c\u5927\u5c0f\u7684\u7684\u66f2\u7ebf\u53ef\u5e73\u79fb\u53e0\u52a0\u6210\u4e00\u6761\u4e3b\u66f2\u7ebf\u3002\u5e73\u79fb\u56e0\u5b50\u03c4\u4e0e\u7684\u5173\u7cfb\u4e5f\u6709\u7684\u89c4\u5f8b\u3002\u800c\u4e14\u4e3b\u66f2\u7ebf\u7684\u5f62\u72b6\u8ddf\u5178\u578b\u7684\u7ebf\u6027\u626b\u9891\u8c31\u56fe\u76f8\u4f3c\uff0c\u53ef\u4ee5\u770b\u5230\u201c\u672b\u7aef\u533a\u201d\u3002Wyss\u8ba4\u4e3a\u8fd9\u5c31\u662f\u5916\u90e8\u526a\u5207\u52a0\u901f\u4e86\u6837\u54c1\u7684\u7ed3\u6784\u677e\u5f1b\uff0c\u5e73\u79fb\u56e0\u5b50\u03c4\u5c31\u662f\u677e\u5f1b\u65f6\u95f4\uff0c\u5b83\u8ddf\u7684\u5173\u7cfb\u8ddf\u4e0a\u8ff0\u7684\u7a33\u6001\u526a\u5207\u7684\u62a5\u9053\u7ed3\u679c\u662f\u6765\u81ea\u540c\u4e00\u4e2a\u7269\u7406\u673a\u5236\u3002\u5f88\u591a\u4eba\u8ffd\u968fWyss\u7684\u8bf4\u6cd5\uff0c\u5bf9\u66f4\u591a\u7684\u4f53\u7cfb\u8fdb\u884c\u4e86\u76f8\u540c\u7684\u5b9e\u9a8c\uff0c\u6700\u8fd1\u7684\u4e00\u4e2a\u62a5\u9053\u662f\uff0c\u8bf4\u660eSRFS\u73b0\u8c61\u662f\u5177\u6709\u666e\u904d\u6027\u7684\u3002 \u9996\u5148\uff0c\u6211\u89c9\u5f97\u6240\u8c13\u7684strain rate-frequency superposition\u4e25\u683c\u6765\u8bb2\u5e94\u8be5\u79f0\u4e3atime-shear rate superposition\u3002\u5047\u5982\u6309\u7167Wyss\u7684\u610f\u89c1\uff0c\u8fd9\u6837\u7684\u6052\u5b9a\u7684\u626b\u9891\u7ed3\u679c\u786e\u5b9e\u662f\u4e00\u79cd\u677e\u5f1b\u8c31\u7684\u8bdd\uff0c\u90a3\u4e48\u9891\u7387\u53ea\u662f\u65f6\u95f4\u5728Fourier\u53d8\u6362\u4e4b\u540e\u7684\u5750\u6807\u800c\u5df2\u3002\u201c\u65f6\u6e29\u53e0\u52a0\u539f\u7406\u201d\u4e0d\u4f1a\u56e0\u4e3a\u505a\u4e86\u5c0f\u5e45\u626b\u9891\u5b9e\u9a8c\u5c31\u6539\u79f0\u201c\u6e29\u9891\u53e0\u52a0\u201d\u3002 \u5176\u6b21\uff0c\u867d\u7136\u8bf4SRFS\u7684\u73b0\u8c61\u5927\u4f53\u4e0a\u53ef\u4ee5\u8bf4\u662f\u526a\u5207\u52a0\u901f\u677e\u5f1b\uff0c\u770b\u5230\u4e86\u6837\u54c1\u7684\u6d41\u52a8\u3002\u4f46\u662f\u662f\u5426\u80fd\u591f\u76f4\u63a5\u628a\u6052\u5b9a\u7684\u626b\u9891\u7ed3\u679c\u5f53\u4f5c\u6052\u5b9a\u7684\u7ebf\u6027\u626b\u9891\u6765\u770b\u5f85\uff0c\u628a\u5e73\u79fb\u56e0\u5b50\u03c4\u5f53\u6210\u7ebf\u6027\u54cd\u5e94\u7406\u8bba\u6846\u67b6\u5185\u7684\u677e\u5f1b\u65f6\u95f4\uff1f\u6211\u89c9\u5f97\u8fd9\u4e48\u505a\u662f\u6709\u95ee\u9898\u7684\u3002\u4e00\u7ec4SRFS\u4e3b\u66f2\u7ebf\u4e2d\uff0c\u4f4e\u9891\u90e8\u5206\u7c7b\u4f3c\u201c\u672b\u7aef\u201d\u7684\u533a\u57df\uff0c\u4e8b\u5b9e\u4e0a\u5bf9\u5e94\u7684\u5e94\u53d8\u5e45\u5ea6\u65e9\u5df2\u8d85\u8fc7\u7ebf\u6027\u7c98\u5f39\u6027\u7684\u8303\u56f4\uff0c\u662f\u5927\u5e45\u632f\u8361\u526a\u5207\uff08LAOS\uff09\u7684\u7ed3\u679c\u3002\u7b2c\u4e00\u4e2a\u62c5\u5fe7\u662f\uff0c\u6837\u54c1\u7684\u54cd\u5e94\u542b\u6709\u591a\u4e2a\u9ad8\u6b21\u8c10\u6ce2\u5206\u91cf\uff0cG'\u548cG''\u53ea\u662f\u57fa\u9891\u8c10\u6ce2\u5206\u91cf\u3002\u56e0\u6b64\u81f3\u5c11\u5b83\u4eec\u6ca1\u6709\u53cd\u6620\u6837\u54c1\u54cd\u5e94\u7684\u5168\u90e8\u4fe1\u606f\uff0c\u4e0d\u8db3\u4ee5\u4f5c\u4efb\u4f55\u8ba8\u8bba\u3002\u4f46\u8fd9\u4e00\u62c5\u5fe7\u5df2\u7ecf\u53ef\u4ee5\u6d88\u9664\uff0c\u6709\u4eba\u62a5\u9053\u5728\u8fd9\u4e00\u533a\u57df\uff0cLAOS\u7684\u4e00\u4e9b\u975e\u7ebf\u6027\u7c98\u5f39\u6027\u53c2\u6570\u4e5f\u662f\u7b26\u5408SRFS\u7684\uff0c\u6211\u6700\u8fd1\u505a\u4e86\u4e00\u4e9b\u5b9e\u9a8c\u518d\u6b21\u8bc1\u5b9e\u4e86\u8fd9\u4e00\u70b9\u3002\u8fd9\u8bf4\u660eSRFS\u7684\u6027\u8d28\u662f\u8d2f\u7a7f\u4e86\u7ebf\u6027\u4e0e\u975e\u7ebf\u6027\u533a\u57df\u7684\u3002\u7b2c\u4e8c\u62c5\u5fe7\u662f\uff0c\u901a\u8fc7LAOS\u89c2\u5bdf\u5230\u7684\u672b\u7aef\uff0c\u662f\u5426\u5bf9\u5e94\u4f53\u7cfb\u7684\u7ed3\u6784\u677e\u5f1b\uff1f\u8fd9\u79cd\u5bf9\u5e94\u662f\u7f3a\u4e4f\u7406\u8bba\u57fa\u7840\u7684\uff0c\u8be6\u7ec6\u8ba8\u8bba\u4e86\u8fd9\u4e2a\u95ee\u9898\u3002 \u95ee\u9898\u7684\u63d0\u51fa \u4e8e\u662f\u6211\u60f3\uff0c1) SRFS\u770b\u5230\u7684\u5b9e\u8d28\u5230\u5e95\u662f\u4ec0\u4e48\uff1f\u5982\u679c\u5b83\u771f\u7684\u770b\u5230\u4e86\u4f53\u7cfb\u7684\u7ed3\u6784\u677e\u5f1b\uff0c\u5982\u4f55\u8bc1\u660e\u8fd9\u4e2a\u5bf9\u5e94\u5173\u7cfb\uff1f2) \u5982\u679c\u4e0d\u662f\uff0c\u90a3\u4e48\u6709\u4ec0\u4e48\u522b\u7684\u6d41\u53d8\u5b66\u65b9\u6cd5\uff0c\u80fd\u591f\u770b\u5230\u4f53\u7cfb\u5728\u975e\u7ebf\u6027\u6761\u4ef6\u4e0b\u7684\u7ed3\u6784\u677e\u5f1b\u5417\uff1f \u5bf9\u7b2c\u4e00\u4e2a\u95ee\u9898\uff0c\u53ef\u4ee5\u5148\u5148\u501f\u52a9\u6a21\u578b\u6765\u5bf9SRFS\u73b0\u8c61\u52a0\u6df1\u7406\u89e3\u3002\u6d41\u53d8\u5b9e\u9a8c\u89c2\u5bdf\u5230\u7684SRFS\u4e5f\u597d\uff0c\u8fc7\u51b7\u6db2\u4f53\u7684\u6a21\u62df\u4e2d\u89c2\u5bdf\u5230\u7684\u7ed3\u6784\u677e\u5f1b\u4e5f\u597d\uff0c\u4ece\u76ee\u524d\u62a5\u9053\u6765\u770b\u8fd9\u4e9b\u73b0\u8c61\u4f3c\u4e4e\u90fd\u662f\u73bb\u7483\u4f53\u7cfb\u7684\u7279\u5f81\u3002\uff08\u9ad8\u5206\u5b50\uff09\u7f20\u7ed3\u4f53\u7cfb\u6709\u6ca1\u6709\u8fd9\u6837\u7684\u7279\u5f81\u5462\uff1f\u4e3a\u4ec0\u4e48\u5728\u5386\u53f2\u4e0d\u77ed\u7684\u805a\u5408\u7269\u6d41\u53d8\u5b66\u7814\u7a76\u4e2d\u6ca1\u4eba\u62a5\u9053\u8fc7\u7c7b\u4f3c\u7684\u73b0\u8c61\u5462\uff1f\u6211\u5b9e\u9a8c\u5ba4\u7684\u6d41\u53d8\u4eea\u6ca1\u6709\u914doven\uff0c\u4e0d\u80fd\u505a\u9ad8\u5206\u5b50\u7194\u4f53\u3002\u6211\u5c31\u914d\u5236\u4e86\u4e00\u70b9worm-like micelle\u6765\u5f53\u4f5c\u7f20\u7ed3\u7684\u6a21\u578b\u4f53\u7cfb\u8bd5\u9a8c\uff0c\u53d1\u73b0\u662f\u5b8c\u5168\u4e0d\u7b26\u5408SRFS\u7684\u3002\u6211\u53c8\u7528Giesekus\u6a21\u578b\u505a\u4e86\u4e00\u4e0b\uff0c\u4e5f\u4e0d\u7b26\u5408\u3002\u8fd9\u4e5f\u8bb8\u53ef\u4ee5\u521d\u6b65\u8bf4\u660e\uff0c\u7f20\u7ed3\u4f53\u7cfb\u6ca1\u6709\u8fd9\u6837\u7684\u6027\u8d28\u3002SRFS\u65e2\u7136\u4f1a\u4f9d\u8d56\u8fd9\u79cddynamics\u7684\u5177\u4f53\u673a\u7406\uff0c\u53ef\u80fd\u771f\u7684\u662f\u53cd\u6620\u7740\u4ec0\u4e48\u7ed3\u6784\u677e\u5f1b\u7684\uff0c\u4f46\u662f\u8fd8\u4e0d\u597d\u4e0b\u4ec0\u4e48\u7ed3\u8bba\u3002 \u90a3\u4e48\uff0c\u9002\u7528\u4e8e\u80f6\u4f53\u4f53\u7cfb\u7684\u6d41\u53d8\u5b66\u6a21\u578b\uff0c\u662f\u5426\u5c31\u90fd\u4e00\u5b9a\u80fd\u7b26\u5408SRFS\u5462\uff1f\u6211\u770b\u4e0d\u4e00\u5b9a\u3002\u4e5f\u8bb8\u4ece\u8fd9\u4e2a\u89d2\u5ea6\u51fa\u53d1\uff0c\u53ef\u4ee5\u53bb\u8003\u5bdf\u8981\u6ee1\u8db3SRFS\u6d41\u53d8\u5b66\u6a21\u578b\u9700\u8981\u7b26\u5408\u4ec0\u4e48\u6837\u7684\u7279\u5f81\uff0c\u4ece\u800c\u53ef\u4ee5\u731c\u5230\u4e00\u4e9bSRFS\u7684\u672c\u8d28\uff0c\u540c\u65f6\u4e5f\u53ef\u4ee5\u770b\u770bSRFS\u53cd\u6620\u7684\u662f\u4ec0\u4e48\u201c\u7ed3\u6784\u677e\u5f1b\u201d\u3002\u8fd9\u9879\u5de5\u4f5c\u6211\u8fd8\u6ca1\u6709\u505a\uff0c\u56e0\u4e3a\u76ee\u524d\u63d0\u51fa\u7684\u80fd\u591f\u6bd4\u8f83\u5168\u9762\u5730\u63cf\u8ff0\u5c48\u670d\u5e94\u529b\u6d41\u4f53\u7684\u77ac\u6001\u6a21\u578b\u5e76\u4e0d\u591a\u3002\u8fd9\u6837\u7684\u672c\u6784\u65b9\u7a0b\u5f80\u5f80\u5c5e\u4e8estructural kinetic model\u7684\u7c7b\u578b\uff0c\u8bbe\u8ba1\u4e86\u5f88\u591a\u6ca1\u6709\u76f4\u63a5\u7269\u7406\u610f\u4e49\u7684\u8868\u8fbe\u5f0f\u51d1\u6765\u51d1\u53bb\u3002\u5982\u679c\u7528\u8fd9\u4e9b\u6a21\u578b\u53bb\u5c1d\u8bd5SRFS\uff0c\u65e0\u8bba\u662f\u6210\u8fd8\u662f\u4e0d\u6210\uff0c\u4f60\u90fd\u5f88\u96be\u83b7\u5f97\u4ec0\u4e48\u7269\u7406\u4e0a\u7684insight\u3002\u6240\u4ee5\uff0c\u6211\u5c31\u60f3\u6539\u7528\u4e00\u4e9b\u80f6\u4f53\u4f53\u7cfb\u7684first principle\u7684\u6d41\u53d8\u7406\u8bba\u3002\u9996\u5148\u60f3\u5230\u7684\u5c31\u662fMCT\u5411\u6d41\u53d8\u5b66\u7684\u63a8\u5e7f\uff0c\u5373Fuchs\u7b49\u4eba\u7684\u5de5\u4f5c\u3002\u5177\u4f53\u5730\uff0c\u662f\u5e0c\u671b\u91c7\u7528MCT-ITT\u7684\u4e00\u4e9b\u7b80\u5316\u7248schematic -model\u3002\u4f7f\u7528\u8fd9\u4e2a\u6a21\u578b\u6765\u9884\u6d4bLAOS\u7ed3\u679c\u7684\u62a5\u9053\u5df2\u7ecf\u6709\u4e86\u3002MCT-ITT\u7684\u6570\u5b66\u8fdc\u8fdc\u8d85\u8fc7\u4e86\u6211\u7684\u80fd\u529b\uff0c\u6211\u662f\u6700\u8fd1\u627e\u5230\u4e86\u4e00\u4e2a\u61c2\u6570\u5b66\u7684\u670b\u53cb\u5e2e\u5fd9\u8ba1\u7b97MCT\uff0c\u624d\u8003\u8651\u8fd9\u4e2a\u95ee\u9898\u7684\u3002\u8fd9\u9879\u5de5\u4f5c\u6b63\u5728\u8fdb\u884c\u4e2d\uff0c\u5b58\u5728\u4e00\u4e9b\u95ee\u9898\uff0c\u7a0d\u540e\u518d\u8bf4\u3002 \u8981\u56de\u7b54\u7b2c\u4e8c\u4e2a\u95ee\u9898\uff0c\u5373\u6709\u4ec0\u4e48\u6d41\u53d8\u5b66\u65b9\u6cd5\u80fd\u591f\u770b\u5230\u4f53\u7cfb\u5728\u975e\u7ebf\u6027\u6761\u4ef6\u4e0b\u7684\u7ed3\u6784\u677e\u5f1b\uff0c\u6211\u4eec\u5e94\u8be5\u9996\u5148\u628a\u60c5\u51b5\u7b80\u5316\u56de\u7a33\u6001\u526a\u5207\u3002\u8fb9\u8fdb\u884c\u7a33\u6001\u526a\u5207\uff0c\u8fb9\u8fdb\u884c\u677e\u5f1b\u6d4b\u8bd5\u7684\u6d41\u53d8\u5b66\u65b9\u6cd5\u662f\u6709\u7684\uff0c\u53eb\u505a\u201c\u53e0\u52a0\u6d41\u53d8\u5b66\u201d\uff0csuperposition rheology\u3002\u8fd9\u91cc\u7684superposition\u662f\u6307\u5728\u4e00\u4e2a\u7a33\u6001\u526a\u5207\u7684\u6d41\u573a\u4e0a\u53e0\u52a0\u4e00\u4e2a\u5c0f\u5e45\u632f\u8361\u7684\u6d41\u573a\u3002\u6837\u54c1\u7684\u54cd\u5e94\u53ef\u4ee5\u5206\u79bb\u6210\u7a33\u6001\u526a\u5207\u7684\u90e8\u5206\u548c\u5c0f\u5e45\u632f\u8361\u7684\u90e8\u5206\uff0c\u540e\u8005\u53ef\u4ee5\u6309\u7167\u7ebf\u6027\u54cd\u5e94\u7684\u505a\u6cd5\u5f97\u5230\u677e\u5f1b\u8c31\u3002\u4e00\u5171\u6709\u5e73\u884c\u548c\u6b63\u4ea4\u4e24\u79cd\u53e0\u52a0\u65b9\u6cd5\u3002\u6709\u62a5\u9053\u79f0\uff0c\u5e73\u884c\u53e0\u52a0\u7531\u4e8e\u8026\u5408\u7684\u56e0\u7d20\u5e76\u4e0d\u80fd\u83b7\u5f97\u771f\u6b63\u7684\u677e\u5f1b\u8c31\uff0c\u5fc5\u9762\u8981\u6b63\u4ea4\u53e0\u52a0\u7684\u624d\u53ef\u4ee5\u3002\u65e0\u8bba\u662f\u54ea\u79cd\u53e0\u52a0\uff0c\u90fd\u4e0d\u5bb9\u6613\u5728\u5546\u7528\u6d41\u53d8\u4eea\u4e0a\u5b9e\u73b0\u7684\uff0c\u9700\u8981\u8fdb\u884c\u6539\u9020\uff0c\u6240\u4ee5\u6211\u6682\u65f6\u4e0d\u80fd\u4eb2\u81ea\u505a\u8fd9\u6837\u7684\u5b9e\u9a8c\u3002\u6587\u732e\u62a5\u9053\u4e2d\u503c\u5f97\u7559\u610f\u7684\u6709\u5982\u4e0b\u8fd9\u4e9b\u3002\u5bf9\u9ad8\u5206\u5b50\u6eb6\u6db2\u505a\u4e86\u53e0\u52a0\u6d41\u53d8\u6d4b\u8bd5\uff0c\u53d1\u73b0\u6240\u5f97\u5230\u7684\u7ed3\u679c\u65e0\u6cd5\u8fdb\u884ctime-shear superposition\u3002\u5bf9\u805a\u4e59\u70ef\u7194\u4f53\u7684\u5b9e\u9a8c\u4e5f\u770b\u5230\u7c7b\u4f3c\u7684\u7ed3\u679c\u3002\u8fd9\u4e5f\u547c\u5e94\u4e86\u524d\u6587\u6240\u8bf4\u7f20\u7ed3\u4f53\u7cfb\u4e0d\u7b26\u5408SRFS\u7684\u73b0\u8c61\u3002\u80f6\u4f53\u4f53\u7cfb\u65b9\u9762\uff0c\u62a5\u9053\u4e86\u4e00\u4e9b\u672a\u53e0\u52a0\u7684\u5b9e\u9a8c\u7ed3\u679c\uff0c\u6211\u8fd8\u9700\u8981\u628a\u6587\u4e2d\u7684\u6570\u636e\u63d0\u53d6\u51fa\u6765\u5c1d\u8bd5\u53e0\u52a0\u6765\u9a8c\u8bc1\u4e00\u4e0b\u3002\u4f46\u662f\u5219\u51e0\u4e4e\u76f4\u63a5\u8bc1\u5b9e\u4e86time-shear superposition\u4e86\uff0c\u4f5c\u8005\u7ed9\u51fa\u4e86\u4e0d\u540c\u7a33\u6001\u5e94\u529b\u53e0\u52a0\u7684\u5c0f\u5e45\u626b\u9891\u66f2\u7ebf\uff0c\u5e76\u53e0\u52a0\u6210\u4e86\u4e3b\u66f2\u7ebf\uff0c\u4f46\u662f\u6ca1\u6709\u7ed9\u51fa\u76f8\u5e94\u7684\u526a\u5207\u901f\u7387\uff0c\u4e5f\u6ca1\u6709\u5bf9\u5e73\u79fb\u56e0\u5b50\u8fdb\u884c\u8ba8\u8bba\u3002\u4f46\u8fd9\u4e00\u62a5\u9053\u8bf4\u660e\uff0c\u80f6\u4f53\u4f53\u7cfb\u5728\u6d41\u53d8\u5b66\u884c\u4e3a\u4e0a\u4e5f\u662f\u7b26\u5408time-shear superposition\u7684\uff0c\u8ddf\u524d\u6587\u4ecb\u7ecd\u7684\u8fc7\u51b7\u6db2\u4f53\u7684\u6a21\u62df\u7ed3\u679c\u76f8\u547c\u5e94\u3002\u5728\u7ebf\u6027\u54cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u6d41\u53d8\u5b66\u4e0a\u7684\u529b\u5b66\u677e\u5f1b\u8ddf\u7ed3\u6784\u677e\u5f1b\u4e4b\u95f4\u5c31\u5dee\u4e2aGreen-Kubo\u5173\u7cfb\u3002\u4f46\u662f\u5728\u975e\u7ebf\u6027\u6761\u4ef6\u4e0b\uff0c\u662f\u5426\u4ecd\u6709\u67d0\u79cd\u5e7f\u4e49\u7684Green-Kubo\u5173\u7cfb\uff1f\u8fd9\u81f3\u5c11\u662f\u7406\u8bba\u5bb6\u4eec\u5e38\u5e38\u91c7\u7528\u7684\u4e00\u79cd\u5047\u8bbe\u3002 Schematic -model MCT\u5411\u6d41\u53d8\u5b66\u7684\u63a8\u5e7f\uff0c\u6709Fuchs\u7b49\u548cMiyazaki\u7b49\u7684\u4e24\u79cd\u505a\u6cd5\u3002Fuchs\u7b49\u4eba\u7684MCT-ITT\u53c8\u6709\u4e24\u79cd\u7b80\u5316\uff0c\u4e00\u79cd\u662fisotropically sheared hard sphere model\uff08ISHSM\uff09\uff0c\u53e6\u4e00\u79cd\u5c31\u662fschematic -model\u3002 Time-shear superposition\u5173\u7cfb\u5230\u03b2\u677e\u5f1b\u8fc7\u7a0b\u7684\u6807\u5ea6\u7279\u6027\u3002\u5bf9\u6b64\u8fdb\u884c\u4e86\u63a8\u5bfc\u3002\u5728\u73bb\u7483\u5316\u8f6c\u53d8\u9644\u8fd1\uff08\uff09\u5bc6\u5ea6\u76f8\u5173\u51fd\u6570\uff0c\u5176\u4e2dfq\u662fDebye-Waller factor\u3002\u5728MCT\u7684\u505a\u6cd5\u4e2d\uff0c\u4f3c\u4e4e\u89c4\u5b9a\u4e86b=1\u3002\u5176\u6b21\uff0c\u03c4\u4e0e\u7684\u5173\u7cfb\uff0c\u4e5f\u4f3c\u4e4e\u662f\u4eba\u4e3a\u89c4\u5b9a\u4e86\u7684\uff0c\u4f53\u73b0\u5728schematic -model\u7684memory function\u5f62\u5f0f\u7684\u9009\u62e9\u4e0a\uff1a \u8fd9\u662f\u5426\u8bf4\u660e\u54ea\u6015\u662fMCT\u7406\u8bba\u4e5f\u5e76\u6ca1\u6709\u9053\u51fatime-shear superposition\u7684\u7269\u7406\u5b9e\u8d28\uff1f\u2026","rel":"","context":"In "\u6211\u7684\u7814\u7a76\u7b14\u8bb0"","block_context":{"text":"\u6211\u7684\u7814\u7a76\u7b14\u8bb0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/rheo"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":6979,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/6979","url_meta":{"origin":6765,"position":4},"title":"\u62db\u6536\u7814\u7a76\u751f\u5bf9\u6211\u6709\u4ec0\u4e48\u597d\u5904\uff1f","author":"Andrew","date":"2016\u5e743\u670830\u65e5","format":"aside","excerpt":"\u8fd9\u51e0\u5e74\u6211\u505a\u79d1\u7814\u91cd\u590d\u9047\u5230\u7684\u4e00\u4e2a\u6700\u5927\u7684\u95ee\u9898\u5c31\u662f\uff0c\u5b66\u751f\u505a\u4e86\u4e0d\u5728\u8ba1\u5212\u5185\u6216\u8005\u4e0d\u5408\u8981\u6c42\u7684\u5b9e\u9a8c\uff0c\u7136\u540e\u6211\u8981\u8d1f\u8d23\u6574\u7406\u6570\u636e\u53d1\u8868\u3002\u6700\u8fd1\u9047\u5230\u7684\u4e24\u4ef6\u4e8b\uff0c\u7ec8\u4e8e\u89e6\u4f7f\u6211\u8ba4\u771f\u601d\u8003\uff0c\u5982\u4f55\u8df3\u51fa\u8fd9\u6837\u7684\u6076\u6027\u5faa\u73af\u3002\u9996\u5148\u6211\u56de\u60f3\u4e00\u4e0b\u9020\u6210\u6211\u51e0\u6b21\u8fd9\u79cd\u7ecf\u5386\u7684\u539f\u56e0\u3002\u6700\u4e3a\u5178\u578b\u7684\u7ecf\u8fc7\u662f\u8fd9\u6837\u7684\uff1a\u6211\u60f3\u4e86\u4e00\u4e2a\u9898\u76ee\uff0c\u9700\u8981\u5236\u5907\u4e00\u4e2a\u7279\u6b8a\u7684\u5b9e\u9a8c\u4f53\u7cfb\u3002\u7ed3\u679c\u5b9e\u9645\u5c1d\u8bd5\u53d1\u73b0\u6ee1\u8db3\u8981\u6c42\u7684\u5b9e\u9a8c\u4f53\u7cfb\u5f88\u96be\u5236\u5907\u51fa\u6765\u3002\u5f53\u65f6\u6211\u5c31\u8ddf\u5b66\u751f\u8bf4\uff0c\u90a3\u8fd9\u4e2a\u9898\u76ee\u4e0d\u505a\u4e86\uff0c\u7b49\u6211\u60f3\u60f3\u6362\u4e2a\u9898\u76ee\u6765\u505a\u3002\u4f46\u662f\u5b66\u751f\u8fd8\u662f\u62ff\u5df2\u7ecf\u5236\u5907\u51fa\u6765\u4e86\u7684\u4e00\u4e9b\u4e0d\u6ee1\u8db3\u8981\u6c42\u7684\u5b9e\u9a8c\u4f53\u7cfb\u505a\u4e86\u4e00\u4e9b\u6d4b\u8bd5\uff0c\u60f3\u53d1\u8868\u3002\u8fd9\u4e9b\u6570\u636e\u65e2\u4e0d\u80fd\u4f5c\u4e3a\u6211\u539f\u5148\u7684\u60f3\u7684\u9898\u76ee\u7684\u5b9e\u9a8c\u8bc1\u636e\uff08\u56e0\u4e3a\u662f\u6765\u81ea\u4e0d\u5408\u6761\u4ef6\u7684\u4f53\u7cfb\u7684\uff09\uff0c\u53c8\u4e0d\u662f\u9488\u5bf9\u65b0\u7684\u4ec0\u4e48\u9898\u76ee\u6765\u8bbe\u8ba1\u5b8c\u6210\u7684\uff0c\u5230\u5e95\u600e\u4e48\u53d1\u8868\uff1f\u5b66\u751f\u8bf4\uff1a\u6211\u770b\u5230\u54ea\u4e9b\u54ea\u4e9b\u8bba\u6587\uff0c\u4e5f\u662f\u53ea\u505a\u4e86\u8fd9\u4e9b\u5b9e\u9a8c\u554a\u3002\u4f46\u4ed6\u8bf4\u7684\u90a3\u4e9b\u8bba\u6587\uff0c\u90fd\u662f\u4e00\u4e9b\u51d1\u6570\u7684\u5de5\u4f5c\u3002\u6211\u4e0d\u5e0c\u671b\u53d1\u8868\u8fd9\u6837\u7684\u5de5\u4f5c\uff0c\u4f46\u7531\u4e8e\u53c8\u4e34\u65f6\u60f3\u4e0d\u51fa\u4ec0\u4e48\u57fa\u4e8e\u5f53\u524d\u8fd9\u4e2a\u5df2\u7ecf\u5236\u5907\u51fa\u6765\u7684\u4f53\u7cfb\u7279\u70b9\u7684\u9898\u76ee\uff08\u4e8b\u5b9e\u5f80\u5f80\u8fd8\u662f\uff0c\u5f53\u524d\u5236\u5907\u51fa\u6765\u7684\u5b9e\u9a8c\u4f53\u7cfb\u5c31\u662f\u4e00\u4e2a\u65e0\u8bba\u4ece\u54ea\u4e2a\u89d2\u5ea6\u770b\u90fd\u4e0dwell-define\u7684\u4f53\u7cfb\uff0c\u4f60\u60f3\u4efb\u4f55\u7269\u7406\u95ee\u9898\u53bb\u5957\u5b83\u90fd\u662f\u6ca1\u7528\u7684\uff09\uff0c\u65e0\u4ece\u53eb\u5b66\u751f\u600e\u4e48\u6539\u8fdb\u3002\u538b\u6839\u513f\u8bf4\u4e0d\u7ed9\u5b66\u751f\u53d1\u8868\u53c8\u4e0d\u884c\uff0c\u4f1a\u5f97\u7f6a\u5b66\u751f\uff0c\u4e8e\u662f\u82e6\u601d\u51a5\u60f3\uff0c\u53bb\u4e3a\u6570\u636e\u7f16\u6545\u4e8b\uff0c\u628a\u4e0d\u4e09\u4e0d\u56db\u7684\u5b9e\u9a8c\u6570\u636e\u201c\u6551\u6d3b\u201d\u3001\u53d1\u8868\u3002\u5f80\u5f80\u8fd9\u4e2a\u8fc7\u7a0b\u8fd8\u8981\u7ecf\u5386\u5f88\u591a\u5931\u8d25\u7684\u5c1d\u8bd5\uff0c\u4f8b\u5982\u8bd5\u56fe\u5957\u4e00\u4e9b\u6a21\u578b\u9884\u6d4b\u6bd4\u8f83\uff0c\u5957\u4e00\u4e9b\u6807\u5ea6\u7387\u7b49\u7b49\uff0c\u9700\u8981\u67e5\u8bba\u6587\u3001\u7f16\u7a0b\u5e8f\uff0c\u505a\u5b8c\u7ed3\u679c\u5982\u679c\u4e0d\u7406\u60f3\uff0c\u8fd8\u8981\u653e\u5f03\u3002\u7a3f\u5b50\u5728\u6211\u624b\u91cc\u62d6\u5f88\u4e45\uff0c\u53c8\u4f1a\u5f97\u7f6a\u5b66\u751f\u3002\u56e0\u4e3a\u8bba\u6587\u8ddf\u5b66\u751f\u7684\u5f88\u591a\u5b9e\u9645\u5229\u76ca\u662f\u6302\u52fe\u7684\u3002\u5b66\u751f\u4e5f\u4e0d\u77e5\u9053\u4f60\u4e3a\u8fd9\u4e2a\u6570\u636e\u60f3\u4e86\u8fd9\u4e48\u591a\u4e1c\u897f\uff0c\u6216\u8005\u89c9\u5f97\u5b8c\u5168\u6ca1\u5fc5\u8981\uff0c\u56e0\u4e3a\u4ed6\u539f\u672c\u5c31\u89c9\u5f97\u81ea\u5df1\u7684\u7a3f\u5b50\u662f\u7acb\u523b\u80fd\u6295\u7a3f\u7684\uff0c\u53ea\u4f1a\u89c9\u5f97\u90fd\u602a\u4f60\u5728\u62d6\u4ed6\u65f6\u95f4\u3002\u51e0\u6b21\u7ecf\u5386\u90fd\u5927\u540c\u5c0f\u5f02\uff0c\u6709\u65f6\u5b9e\u9a8c\u4f53\u7cfb\u7684\u56f0\u96be\u662f\u80fd\u514b\u670d\u7684\uff0c\u4f46\u5b66\u751f\u89c9\u5f97\u514b\u670d\u8fd9\u79cd\u6280\u672f\u6027\u56f0\u96be\u7684\u65f6\u95f4\u5f88\u957f\u3002\u4ed6\u60c5\u613f\u505a\u76f4\u63a5\u5f97\u5230\u6570\u636e\u7684\u5b9e\u9a8c\uff0c\u4ed6\u89c9\u5f97\u6570\u636e\u51fa\u6765\uff0c\u5c31\u610f\u5473\u7740\u53ef\u4ee5\u53d1\u8868\u4e86\uff0c\u54ea\u6015\u8fd9\u4e2a\u5b9e\u9a8c\u8ddf\u539f\u6765\u8bf4\u597d\u7684\u8bfe\u9898\u65e0\u5173\u3002\u7ed3\u679c\u4ecd\u7136\u662f\uff0c\u505a\u4e86\u4e00\u4e9b\u5b9e\u9a8c\u6570\u636e\uff0c\u6211\u8981\u4e34\u65f6\u4e3a\u8fd9\u4e9b\u6570\u636e\u7f16\u6545\u4e8b\u53d1\u8868\u3002\u8fd8\u6709\u4e24\u4ef6\u6211\u73b0\u5728\u5f88\u540e\u6094\u7684\u4e8b\uff0c\u5219\u662f\u7531\u4e8e\u6211\u8001\u677f\u5f53\u65f6\u62c5\u5fc3\u6211\u505a\u7684\u592a\u7406\u8bba\u4e0d\u6613\u53d1\u8868\uff0c\u5e0c\u671b\u80fd\u52a0\u5165\u4e00\u4e9b\u201c\u6613\u53d1\u8868\u7684\u5143\u7d20\u201d\u3002\u56e0\u6b64\uff0c\u539f\u672c\u6211\u8ba9X\u535a\u58eb\u505a\u6211\u4e00\u76f4\u60f3\u8981\u7814\u7a76\u7684\u80f6\u4f53\u60ac\u6d6e\u6db2\uff0c\u4f46\u4ed6\u653b\u514b\u4e86\u5bc6\u5ea6\u5339\u914d\u4e4b\u540e\uff0c\u5c31\u6539\u8ba9\u4ed6\u505acoffee ring effect\uff08\u4ee5\u4e3a\u65b0\u5947\u6613\u53d1\u8868\uff09\u4e86\uff0c\u6b8a\u4e0d\u77e5\u4e5f\u4e0d\u6613\u505a\uff0c\u73b0\u5728\u6587\u7ae0\u8fd8\u9700\u8981\u7406\u8bba\u5206\u6790\uff0c\u6211\u8fd8\u65e0\u6687\u6574\u7406\u53d1\u8868\uff0c\u4ed6\u7684\u535a\u58eb\u8bfe\u9898\u5c06\u6765\u5982\u4f55\u5f52\u7eb3\u6210\u4e00\u4e2a\u9898\u76ee\uff0c\u4e5f\u6210\u95ee\u9898\u3002\u53e6\u4e00\u4f4dL\u535a\u58eb\u66f4\u662f\u8ba9\u5176\u505a\u6c27\u5316\u77f3\u58a8\u70ef\uff08\u77f3\u58a8\u70ef\u5c31\u662f\u6613\u53d1\u8868\u5143\u7d20\uff09\uff0c\u4f46\u7531\u4e8e\u6ca1\u6709\u5177\u4f53\u8bfe\u9898\uff0c\u5b9e\u9645\u6d88\u8017\u4e86\u5f88\u591a\u65f6\u95f4\uff0c\u5230\u4ed6\u5feb\u6bd5\u4e1a\u4e86\uff0c\u624d\u6293\u4f4f\u4e86\u4e00\u4e2a\u6d41\u53d8\u5b66\u5f02\u5e38\u73b0\u8c61\uff0c\u4e0d\u5de7\u6d41\u53d8\u4eea\u8fd8\u635f\u574f\u4e86\u3002\u6211\u7acb\u523b\u51b3\u5b9a\u5e26\u4ed6\u4e00\u8d77\u53bb\u4e0a\u6d77\u505a\u4e86\u4e00\u5468\u5b9e\u9a8c\uff0c\u628a\u8fd9\u4e2a\u5f02\u5e38\u73b0\u8c61\u5b8c\u6574\u8868\u5f81\u4e86\u4e00\u904d\uff0c\u5f62\u6210\u73b0\u5728\u4ed6\u535a\u58eb\u8bba\u6587\u7684\u4e00\u5927\u534a\u7684\u5185\u5bb9\u3002\u4f46\u662f\u5982\u679c\u6709\u5f97\u518d\u6b21\u9009\u62e9\uff0c\u6211\u4e0d\u4f1a\u8ba9X\u535a\u58eb\u505acoffee ring effect\uff0c\u4e5f\u4e0d\u4f1a\u8ba9L\u535a\u58eb\u53bb\u505a\u6c27\u5316\u77f3\u58a8\u70ef\uff0c\u800c\u662f\u90fd\u8ba9\u4ed6\u4eec\u53bb\u505a\u80f6\u4f53\u60ac\u6d6e\u6db2\u3002\u5927\u90e8\u5206\u5b66\u751f\u90fd\u6015\u56f0\u96be\uff0c\u4e0d\u60f3\u5b8c\u6210\u6211\u5e0c\u671b\u5b8c\u6210\u7684\u8bfe\u9898\u3002\u56e0\u4e3a\u6211\u505a\u7684\u9898\u76ee\u504f\u7269\u7406\uff0c\u5b66\u751f\u591a\u534a\u514d\u4e0d\u4e86\u8981\u9996\u5148\u8865\u4e60\u5f88\u591a\u7406\u8bba\u77e5\u8bc6\u548c\u6570\u503c\u8ba1\u7b97\u6280\u80fd\uff0c\u81f3\u5c11\u7f16\u7a0b\u5c31\u662f\u4e00\u4e2a\u9003\u4e0d\u6389\u7684\u5de5\u4f5c\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u8fd8\u6709\u9605\u8bfb\u8fd9\u4e2a\u9886\u57df\u7684\u6bcf\u4e00\u7bc7\u8bba\u6587\uff0c\u77e5\u9053\u6240\u6709\u5df2\u77e5\u4e8b\u5b9e\u3002\u5c3d\u7ba1\u8fd9\u672c\u6765\u5c31\u662fPhD\u4efd\u5185\u7684\u4e8b\u60c5\uff0c\u4f46\u5230\u4eca\u5929\u6211\u57fa\u672c\u63a5\u53d7\u7684\u4e8b\u5b9e\u662f\uff0c\u6211\u6240\u5728\u7684\u73af\u5883\u91cc\u7684\u5b66\u751f\uff0c\u4ee5\u4e0a\u8fd9\u4e9b\u4e0d\u4f1a\u6709\u5b66\u751f\u80fd\u505a\u3002\u4ed6\u4eec\u4e60\u60ef\u7684\u60c5\u51b5\u662f\uff0c\u672c\u79d1\u6bd5\u4e1a\u8fdb\u5b9e\u9a8c\u5ba4\uff0c\u4e0d\u7528\u770b\u4ec0\u4e48\u4e66\uff0c\u8ddf\u7740\u505a\u4e00\u505a\u5b9e\u9a8c\uff0c\u6709\u6570\u636e\u5c31\u80fd\u53d1\u8868\u3002\u8ba9\u4ed6\u4eec\u505a\u8d85\u51fa\u8fd9\u4e2a\u7684\u4e8b\u60c5\u4ed6\u4eec\u90fd\u89c9\u5f97\u4e0d\u516c\u5e73\u3002\u5b66\u751f\u6309\u81ea\u5df1\u60f3\u6cd5\u505a\u4e86\u5b9e\u9a8c\u5f97\u5230\u4e00\u4e9b\u6570\u636e\uff0c\u7167\u6837\u53c8\u4f1a\u8981\u6211\u5199\u8bba\u6587\u53d1\u8868\u3002\u90a3\u6211\u4e0d\u5149\u81ea\u5df1\u7684\u8bfe\u9898\u6ca1\u4eba\u505a\uff0c\u8fd8\u82b1\u65f6\u95f4\u5728\u5b66\u751f\u7684\u8bba\u6587\u4e0a\u3002\u6240\u4ee5\uff0c\u73b0\u5728\u6211\u60f3\u7684\u5e94\u5bf9\u529e\u6cd5\u662f\uff0c\u8fd9\u79cd\u60c5\u51b5\u6211\u5c31\u4e0d\u5e2e\u5b66\u751f\u6539\u8bba\u6587\u4e86\u3002\u4ed6\u81ea\u5df1\u5199\uff0c\u81ea\u5df1\u6309\u671f\u520a\u683c\u5f0f\u6539\u6539\uff0c\u5c31\u81ea\u5df1\u6295\u5427\uff0c\u4e0d\u8981\u7f72\u6211\u540d\u5b57\u5c31\u884c\u4e86\u3002\u8fd9\u6837\u54ea\u6015\u5b66\u751f\u53bb\u505a\u4ed6\u81ea\u5df1\u7684\u8bfe\u9898\uff0c\u6211\u4e5f\u6709\u65f6\u95f4\u82b1\u5728\u6211\u81ea\u5df1\u8bfe\u9898\u4e0a\uff0c\u54ea\u6015\u662f\u770b\u6587\u732e\u4e5f\u597d\uff0c\u505a\u5b9e\u9a8c\u4e5f\u597d\uff0c\u53ea\u8981\u4e0d\u7528\u5e2e\u5b66\u751f\u6539\u8bba\u6587\uff0c\u6211\u80fd\u7701\u51fa\u4e00\u5927\u534a\u7684\u65f6\u95f4\uff0c\u6211\u81ea\u5df1\u505a\u5b9e\u9a8c\u5199\u8bba\u6587\u8fd8\u6bd4\u5b66\u751f\u5feb\u3002\u5176\u5b9e\u8bf4\u5230\u5e95\uff0c\u6211\u4e0d\u77e5\u9053\u4e3a\u4ec0\u4e48\u8981\u62db\u6536\u7814\u7a76\u751f\u3002\u62db\u6536\u7814\u7a76\u751f\u5bf9\u6211\u6709\u4ec0\u4e48\u597d\u5904\uff1f","rel":"","context":"In "\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0"","block_context":{"text":"\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/tagged"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":9238,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/9238","url_meta":{"origin":6765,"position":5},"title":"P. Flory\u81ea\u8ff0\u5bf9M. Huggins\u5de5\u4f5c\u7684\u9996\u6b21\u5173\u6ce8","author":"Andrew","date":"2025\u5e747\u670830\u65e5","format":"aside","excerpt":"\u805a\u5408\u7269\u6eb6\u6db2\u7684Flory--Huggins\u7406\u8bba\u662f\u9ad8\u5206\u5b50\u7269\u7406\u7ecf\u5178\u7406\u8bba\u4f53\u7cfb\u4e2d\u7684\u57fa\u77f3\u3002\u5b83\u54ea\u6015\u5341\u5206\u4e0d\u51c6\u786e\uff0c\u4e5f\u88ab\u5f53\u4f5c\u201c\u6807\u51c6\u6a21\u578b\u201d\uff0c\u4f5c\u4e3a\u66f4\u771f\u5b9e\u7406\u8bba\u7684\u53c2\u7167\u3002\u4e4b\u6240\u4ee5\u4f7f\u7528\u8fd9\u4e24\u4e2a\u540d\u5b57\uff0c\u662f\u56e0\u4e3a\u8fd9\u4e24\u4e2a\u4eba\u51e0\u4e4e\u540c\u65f6\u505a\u4e86\u540c\u6837\u7684\u5de5\u4f5c\u3002\u66f4\u51c6\u786e\u5730\u8bf4\uff0c\u662fMaurice L. Huggins\u5148\u505a\u7684\u3002\u4ece\u53d1\u8868\u7684\u65f6\u95f4\u6765\u770b\uff0cHuggins\u53d1\u8868\u4e8e1941\u5e745\u6708\uff0cFlory\u53d1\u8868\u4e8e\u540c\u5e748\u6708\uff0c\u5e76\u4e14\u5df2\u7ecf\u5f15\u7528\u4e86Huggins\u7684\u5de5\u4f5c\u4e86\u3002\u5b9e\u9645\u4e0a\u8fd9\u4e24\u7bc7\u8bba\u6587\u90fd\u63d0\u5230\u4e86\uff0c\u5728\u540c\u5e74\u76846\u6708\u4efd\u7684\u4e00\u4e2a\u4f1a\u8bae\u2014\u2014Wilder D. Bancroft Colloid Symposium\u4e0a\uff0cHuggins\u62a5\u544a\u4e86\u4ed6\u7684\u5de5\u4f5c\u3002\u591a\u5e74\u4e4b\u540e\u76841985\u5e74\uff0cFlory\u7684\u540e\u4e00\u7bc71942\u5e74\u7684\u8bba\u6587\u88ab\u7f8e\u56fd\u79d1\u5b66\u4fe1\u606f\u7814\u7a76\u6240\uff08Institutide of Scientific Information\uff0cISI\uff09\u7684\u671f\u520aCurrent Contents\u9009\u4e3a\u201c\u672c\u5468\u7ecf\u5178\u5f15\u7528\u201d\uff081985\u5e745\u67086\u65e5\uff0c\u7b2c18\u671f\uff09\uff0c\u8fd9\u4e2a\u680f\u76ee\u4f1a\u9080\u8bf7\u8bba\u6587\u4f5c\u8005\u5199\u70b9\u6545\u4e8b\u3002Flory\u5728\u8fd9\u91cc\u4eb2\u81ea\u56de\u5fc6\u4e86\u4ed6\u5728Wilder D. Bancroft Colloid Symposium\u9996\u6b21\u5f97\u77e5Huggins\u505a\u4e86\u8ddf\u4ed6\u91cd\u590d\u7684\u5de5\u4f5c\u7684\u5f88\u591a\u7ec6\u8282\u3002Huggins\u662fLewis\u7684\u5b66\u751f\uff0c\u662fFlory\u7684\u524d\u8f88\u3002\u4ee5\u4e0b\u662fFlory\u56de\u5fc6\u7684\u4e00\u6bb5\u539f\u6587\u7684\u4e2d\u6587\u8bd1\u6587\u3002 \u6211\u4eec\u7684\u7814\u7a76\u662f\u72ec\u7acb\u8fdb\u884c\u7684\u3002\u6211\u7b2c\u4e00\u6b21\u4e86\u89e3\u5230Huggins\u7684\u5de5\u4f5c\uff0c\u662f\u57281941\u5e746\u6708\u4e8e\u5eb7\u5948\u5c14\u5927\u5b66\u4e3e\u884c\u7684\u80f6\u4f53\u7814\u8ba8\u4f1a\u4e0a\uff0c\u5f53\u65f6\u4ed6\u5c55\u793a\u4e86\u4ed6\u7684\u7814\u7a76\u6210\u679c\u3002\u5728\u90a3\u6b21\u7814\u8ba8\u4f1a\u4e0a\uff0c\u6211\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u975e\u7ebf\u5f62\u805a\u5408\u7269\u51dd\u80f6\u5316\u548c\u7f51\u7edc\u5f62\u6210\u7406\u8bba\u7684\u8bba\u6587\uff0c\u8fd9\u4e2a\u4e3b\u9898\u4e0e\u4e0a\u8ff0\u5185\u5bb9\u65e0\u5173\uff0c\u4f46\u50cf\u5b83\u4e00\u6837\uff0c\u4e5f\u83b7\u5f97\u4e86\u5e7f\u6cdb\u7684\u8ba4\u53ef\u3002\u4eceHuggins\u7684\u6f14\u8bb2\u4e2d\uff0c\u6211\u60ca\u8bb6\u5730\u5f97\u77e5\u4ed6\u6240\u8fdb\u884c\u7684\u5de5\u4f5c\u4e0e\u6211\u5f53\u65f6\u6b63\u51c6\u5907\u53d1\u8868\u7684\u5173\u4e8e\u805a\u5408\u7269\u6eb6\u6db2\u70ed\u529b\u5b66\u7684\u7814\u7a76\u975e\u5e38\u76f8\u4f3c\u3002\u6f14\u8bb2\u7ed3\u675f\u540e\uff0c\u6211\u8d70\u8fd1\u4ed6\uff0c\u6307\u51fa\u6211\u4e5f\u5728\u8fdb\u884c\u7c7b\u4f3c\u7684\u7814\u7a76\u3002\u4ed6\u975e\u5e38\u548c\u853c\uff0c\u9f13\u52b1\u6211\u8fd9\u4e2a\u5f53\u65f6\u8fd8\u53ea\u662f\u4e2a\u65e0\u540d\u5c0f\u5352\u7684\u4eba\u53d1\u8868\u6211\u7684\u5de5\u4f5c\uff0c\u5e76\u4e0e\u4ed6\u4ea4\u6d41\u3002\u8fd9\u662f\u6211\u4eec\u7684\u7b2c\u4e00\u6b21\u4f1a\u9762\uff0c\u4e5f\u5f00\u542f\u4e86\u6211\u4eec\u4e00\u751f\u7684\u53cb\u8c0a\u3002\u540e\u6765\uff0c\u6211\u4eec\u5c31\u5404\u79cd\u4e3b\u9898\u548c\u53d1\u5c55\u8fdb\u884c\u4e86\u8bb8\u591a\u79d1\u5b66\u8ba8\u8bba,\u867d\u7136\u5e76\u4e0d\u603b\u662f\u5b8c\u5168\u4e00\u81f4\uff0c\u4f46\u603b\u662f\u76f8\u4e92\u5c0a\u91cd\uff0c\u5173\u7cfb\u878d\u6d3d\u3002\u6b63\u5982\u6211\u5e38\u8bf4\u7684\uff0c\u4ee5\u6211\u4eec\u540d\u5b57\u547d\u540d\u7684\u8fd9\u4e2a\u7406\u8bba\uff0c\u6211\u4eec\u7684\u540d\u5b57\u987a\u5e8f\u5e94\u8be5\u98a0\u5012\u8fc7\u6765\uff0c\u56e0\u4e3a\u4ed6\u7684\u7b2c\u4e00\u7bc7\u8bba\u6587\u6bd4\u6211\u7684\u65e9\u4e86\u4e00\u4e24\u4e2a\u6708\u3002\u4ed6\u6700\u521d\u7684\u8d21\u732e\u66f4\u8be6\u7ec6\u5730\u9610\u8ff0\u4e86\u6676\u683c\u7406\u8bba\uff0c\u800c\u6211\u7684\u53ef\u80fd\u5728\u67d0\u4e9b\u65b9\u9762\u66f4\u5168\u9762\u3002","rel":"","context":"In "\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0"","block_context":{"text":"\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/tagged"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]}],"jetpack_likes_enabled":true,"_links":{"self":[{"href":"https:\/\/www.andrewsun.net\/panta_rhei\/wp-json\/wp\/v2\/posts\/6765","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.andrewsun.net\/panta_rhei\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.andrewsun.net\/panta_rhei\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.andrewsun.net\/panta_rhei\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.andrewsun.net\/panta_rhei\/wp-json\/wp\/v2\/comments?post=6765"}],"version-history":[{"count":6,"href":"https:\/\/www.andrewsun.net\/panta_rhei\/wp-json\/wp\/v2\/posts\/6765\/revisions"}],"predecessor-version":[{"id":7836,"href":"https:\/\/www.andrewsun.net\/panta_rhei\/wp-json\/wp\/v2\/posts\/6765\/revisions\/7836"}],"wp:attachment":[{"href":"https:\/\/www.andrewsun.net\/panta_rhei\/wp-json\/wp\/v2\/media?parent=6765"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.andrewsun.net\/panta_rhei\/wp-json\/wp\/v2\/categories?post=6765"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.andrewsun.net\/panta_rhei\/wp-json\/wp\/v2\/tags?post=6765"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}