{"id":5225,"date":"2013-03-31T21:35:18","date_gmt":"2013-03-31T13:35:18","guid":{"rendered":"http:\/\/www.andrewsun.net\/panta_rhei\/?p=5225"},"modified":"2013-03-31T21:38:57","modified_gmt":"2013-03-31T13:38:57","slug":"kcite%e6%8f%92%e4%bb%b6%e6%b5%8b%e8%af%95","status":"publish","type":"post","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/5225","title":{"rendered":"kcite\u63d2\u4ef6\u6d4b\u8bd5"},"content":{"rendered":"
\n

\u88c5\u4e86kcite\u63d2\u4ef6\uff0c\u53ef\u4ee5\u5c06\u6587\u4e2d\u7684DOI\u53f7\u76f4\u63a5\u6e32\u67d3\u6210\u6070\u5f53\u7684\u5f15\u7528\uff08\u6587\u4e2d\u53d8\u5e8f\u53f7\uff0c\u6587\u672b\u52a0bibliography\uff09\u3002\u672c\u9875\u4e3a\u6d4b\u8bd5\u3002<\/p>\n

Recently, many simulation and experiment studies have been published [1]<\/a><\/span> to reveal the precise features of the jamming phase diagram for different amorphous systems within this framework. Of many model systems for the jamming transition, the poly(N<\/i>-isopropylacrylamide) (PNIPAM) microgel suspension is a unique one. The particles are soft and deformable, so they can be efficiently packed beyond the close packing condition for the hard spheres. Moreover, due to the thermo-responsibility, a small change in temperature will cause a large change of the particle diameter. This endows PNIPAM microgel suspensions with interesting physical and rheological properties [2]<\/a><\/span>[3]<\/a><\/span>. Different from the inert hard sphere counterparts, the PNIPAM microgel suspension undergoes a transition from solid-like to liquid-like state with increasing temperature not due to the increase in thermal energy k<\/i>B<\/sub>T<\/i>, but due to the decrease in the particle diameter, which lowered the effective volume fraction \u03c6<\/i>eff<\/sub> of the particles in the suspension [4]<\/a><\/span>[5]<\/a><\/span>[6]<\/a><\/span>[7]<\/a><\/span>. In the view of jamming phase diagram, T<\/i> was coupled with \u03c6<\/i>eff<\/sub>, so that the PNIPAM microgel suspension state cannot be independently controlled by T<\/i> and \u03c6<\/i>eff<\/sub>. Moreover, the softness of the microgel particles was also changed by the swelling extent. There was a report where \u03c6<\/i>eff<\/sub> was varied by the particle number density at constant temperature [8]<\/a><\/span>, but direct comparison between the effect of the two control variables, T<\/i> and concentration, on increasing \u03c6eff<\/sub> is lacking. In the jamming state, the microgel suspension responded essentially elastically to the applied small strain and turned to the shear-unjamming state and flowed beyond yielding by tuning control variables [9]<\/a><\/span>. The flow of the microgel suspensions after yielding was nonlinear viscoelastic [10]<\/a><\/span>[11]<\/a><\/span>.<\/p>\n

References<\/h2>\n
    \n
  1. <\/a>\nM.P. Ciamarra, M. Nicodemi, and A. Coniglio, \"Recent results on the jamming phase diagram\", Soft Matter<\/i>, vol. 6, pp. 2871, 2010. http:\/\/dx.doi.org\/10.1039\/b926810c<\/a>\n\n\n<\/li>\n
  2. <\/a>\nB. Sierra\u2010Martin, J.J. Lietor\u2010Santos, A. Fernandez\u2010Barbero, T.T. Nguyen, and A. Fernandez\u2010Nieves, \"Swelling Thermodynamics of Microgel Particles\", Microgel Suspensions<\/i>, pp. 71-116, 2011. http:\/\/dx.doi.org\/10.1002\/9783527632992.ch4<\/a>\n\n\n<\/li>\n
  3. <\/a>\nM. Cloitre, \"Yielding, Flow, and Slip in Microgel Suspensions: From Microstructure to Macroscopic Rheology\", Microgel Suspensions<\/i>, pp. 283-309, 2011. http:\/\/dx.doi.org\/10.1002\/9783527632992.ch11<\/a>\n\n\n<\/li>\n
  4. <\/a>\nG. Romeo, A. Fernandez\u2010Nieves, H.M. Wyss, D. Acierno, and D.A. Weitz, \"Temperature\u2010Controlled Transitions Between Glass, Liquid, and Gel States in Dense p\u2010NIPA Suspensions\", Advanced Materials<\/i>, vol. 22, pp. 3441-3445, 2010. http:\/\/dx.doi.org\/10.1002\/adma.200904189<\/a>\n\n\n<\/li>\n
  5. <\/a>\nZ. Zhang, N. Xu, D.T.N. Chen, P. Yunker, A.M. Alsayed, K.B. Aptowicz, P. Habdas, A.J. Liu, S.R. Nagel, and A.G. Yodh, \"Thermal vestige of the zero-temperature jamming transition\", Nature<\/i>, vol. 459, pp. 230-233, 2009. http:\/\/dx.doi.org\/10.1038\/nature07998<\/a>\n\n\n<\/li>\n
  6. <\/a>\nJ. Mattsson, H.M. Wyss, A. Fernandez-Nieves, K. Miyazaki, Z. Hu, D.R. Reichman, and D.A. Weitz, \"Soft colloids make strong glasses\", Nature<\/i>, vol. 462, pp. 83-86, 2009. http:\/\/dx.doi.org\/10.1038\/nature08457<\/a>\n\n\n<\/li>\n
  7. <\/a>\nF. Scheffold, P. D\u00edaz-Leyva, M. Reufer, N. Ben Braham, I. Lynch, and J.L. Harden, \"Brushlike Interactions between Thermoresponsive Microgel Particles\", Physical Review Letters<\/i>, vol. 104, 2010. http:\/\/dx.doi.org\/10.1103\/PhysRevLett.104.128304<\/a>\n\n\n<\/li>\n
  8. <\/a>\nD. Paloli, P.S. Mohanty, J.J. Crassous, E. Zaccarelli, and P. Schurtenberger, \"Fluid\u2013solid transitions in soft-repulsive colloids\", Soft Matter<\/i>, vol. 9, pp. 3000, 2013. http:\/\/dx.doi.org\/10.1039\/c2sm27654b<\/a>\n\n\n<\/li>\n
  9. <\/a>\nH. Senff, and W. Richtering, \"Temperature sensitive microgel suspensions: Colloidal phase behavior and rheology of soft spheres\", The Journal of Chemical Physics<\/i>, vol. 111, pp. 1705-1711, 1999. http:\/\/dx.doi.org\/10.1063\/1.479430<\/a>\n\n\n<\/li>\n
  10. <\/a>\nV. Carrier, and G. Petekidis, \"Nonlinear rheology of colloidal glasses of soft thermosensitive microgel particles\", Journal of Rheology<\/i>, vol. 53, pp. 245-273, 2009. http:\/\/dx.doi.org\/10.1122\/1.3045803<\/a>\n\n\n<\/li>\n
  11. <\/a>\nA. Le Grand, and G. Petekidis, \"Effects of particle softness on the rheology and yielding of colloidal glasses\", Rheologica Acta<\/i>, vol. 47, pp. 579-590, 2008. http:\/\/dx.doi.org\/10.1007\/s00397-007-0254-z<\/a>\n\n\n<\/li>\n<\/ol>\n\n<\/div> ","protected":false},"excerpt":{"rendered":"

    \u88c5\u4e86kcite\u63d2\u4ef6\uff0c\u53ef\u4ee5\u5c06\u6587\u4e2d\u7684DOI\u53f7\u76f4\u63a5\u6e32\u67d3\u6210\u6070\u5f53\u7684\u5f15\u7528\uff08\u6587\u4e2d\u53d8\u5e8f\u53f7\uff0c\u6587\u672b\u52a0bibliography\uff09\u3002\u672c\u9875\u4e3a\u6d4b\u8bd5\u3002 Recently, many simulation and experiment studies have been published to reveal the precise features of the jamming phase diagram for different amorphous systems within this framework. Of many model systems for the jamming transition, the poly(N-isopropylacrylamide) (PNIPAM) microgel suspension is a unique one. The particles are soft and deformable, so they can be efficiently 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systems\u6216\u8005counterions only system\uff0c\u6240\u4ee5\u53cd\u79bb\u5b50\u6d53\u5ea6\u662f\u4e0d\u53ef\u5ffd\u7565\u7684\uff0c\u9ad8\u7535\u8377\u5bc6\u5ea6\u65f6\u4f1a\u53d1\u751f\u53cd\u79bb\u5b50\u51dd\u805a\u3002\u8fd9\u5e94\u8be5\u662f\u4e2a\u5e38\u8bc6\u4e86\uff0c\u65e0\u5948\u6211\u77e5\u8bc6\u8fd8\u662f\u6b20\u7f3a\uff0c\u5168\u8d56\u4ed6\u7684\u6307\u70b9\u3002\u4e8e\u662f\u6211\u624d\u91cd\u65b0\u6309\u7167\u53cd\u79bb\u5b50\u51dd\u805a\u7684\u89d2\u5ea6\u6765\u601d\u8003\u6211\u7684\u4f53\u7cfb\u3002 \u5728\u53cd\u79bb\u5b50\u51dd\u805a\u7684\u7814\u7a76\u4e2d\uff0c\u5927\u90e8\u5206\u662f\u8003\u8651\u67f1\u72b6\u7684\u5e26\u7535\u8868\u9762\u7684\uff0c\u4e3b\u8981\u9762\u5411\u7684\u5b9e\u9645\u4f53\u7cfb\u662f\u805a\u7535\u89e3\u8d28\uff08\u5305\u62ecDNA\uff09\u6eb6\u6db2\uff0c\u53c8\u53ebManning condensation\u3002\u7403\u72b6\u7684\u7814\u7a76\u6bd4\u8f83\u5c11\uff0c\u7ecf\u5e38\u53eb\u6210charge renormalization\u3002Manning\u81ea\u5df1\u4e5f\u8003\u8651\u8fc7\u7403\u72b6\u7684\u4f53\u7cfb\uff0c\u4ed6\u7684two-state model\u662f\u4ece\u8003\u8651\u81ea\u7531\u80fd\u51fa\u53d1\uff0c\u8ba4\u4e3a\u7cbe\u786e\u7684\u7ed3\u679c\u8ddfDH\u8fd1\u4f3c\u4e4b\u95f4\u5c31\u662f\u5dee\u4e00\u4e2a\u7cfb\u6570\uff0c\u8fd9\u4e2a\u7cfb\u6570\u7b80\u5355\u5730\u8ba4\u4e3a\u662f\u4e2a\u975e\u51dd\u805a\u79bb\u5b50\u7684\u6bd4\u4f8b\u7cfb\u6570$(1-z\\theta)$\uff0c\u5176\u4e2d$\\theta$\u662f\u51dd\u805a\u79bb\u5b50\u6240\u5360\u6bd4\u4f8b\u3002\u4ed6\u7684\u903b\u8f91\u5176\u5b9e\u662f\u975e\u5e38\u7b03\u5b9a\u201c\u53cd\u79bb\u5b50\u51dd\u805a\u201d\u7684\u56fe\u50cf\uff0c\u8ba4\u4e3a\u6709\u975e\u5e38\u786e\u5b9a\u6570\u91cf\u7684\u53cd\u79bb\u5b50\u53d1\u751f\u4e86\u201c\u51dd\u805a\u201d\u3002\u7136\u540e\uff0c\u901a\u8fc7\u81ea\u7531\u80fd\u6700\u5c0f\u5316\u6765\u6c42\u5f97$\\theta$\u7684\u8868\u8fbe\u5f0f\u3002\u800c\u5219\u662f\u7528cell model\u6765\u6c42\u89e3Poisson-Boltzmann\u65b9\u7a0b\uff0c\u8bc1\u5b9e\u4e86\u7684\u786e\u53ef\u4ee5\u8fdb\u884c\u8868\u9762\u7535\u8377\uff08\u52bf\uff09\u7684\u7b49\u6548\u3002\u7684\u5de5\u4f5c\u867d\u7136\u88ab\u591a\u6b21\u5f15\u7528\uff0c\u4f46\u5c40\u9650\u4e8e\u7406\u8bba\u7814\u7a76\u7684\u5708\u5b50\u4e4b\u5185\u3002\u5f88\u5c11\u6709\u7528\u4ed6\u7684\u7ed3\u679c\u89e3\u91ca\u5b9e\u9a8c\u7684\u5de5\u4f5c\u3002\u505a\u4e86\u4e00\u4e2asalt-free\u4f53\u7cfb\u7684\u7535\u6cf3\u5b9e\u9a8c\u5e76\u4e14\u8fdb\u884c\u4e86\u7406\u8bba\u63cf\u8ff0\uff0c\u4f7f\u7528\u4e86\u4e00\u4e2a\u4e0e\u7c7b\u4f3c\u7684approach\u3002\u6211\u7684\u8bba\u6587\u76f4\u63a5\u7528\u4e86\u7684\u7ed3\u679c\u6765\u8ba1\u7b97\u76f8\u4e92\u4f5c\u7528\u52bf\u80fd$U\\left(h\\right)$\uff0c\u7136\u540e\u8fdb\u4e00\u6b65\u8ba1\u7b97RLCA\u7684stability ratio\uff0c\u5f97\u51fa\u4e0e\u5b9e\u9a8c\u6bd4\u8f83\u543b\u5408\u7684\u7ed3\u679c\uff0c\u5e94\u8be5\u662f\u7b2c\u4e00\u4e2a\u3002 \u6211\u7684\u6587\u7ae0\u53d1\u8868\u65f6\uff0c\u5ba1\u7a3f\u4eba\u4e5f\u663e\u793a\u51fa\u6bd4\u8f83\u9ad8\u7684\u5174\u8da3\uff0c\u8bf4\u6211\u8fd9\u662f\u4e00\u7bc7excellent paper\uff0c\u6709\u4e00\u6761\u4fee\u6539\u610f\u89c1\u8fd8\u662f\u201cThis is an interesting point that should be explored and highlighted further.\u201d \u867d\u7136\u6211\u6587\u7ae0\u7684\u81f4\u8c22\u91cc\u5df2\u7ecf\u611f\u8c22\u4e86Ohshima\uff0c\u4f46\u603b\u89c9\u5f97\u8fd8\u662f\u8981\u4eb2\u81ea\u611f\u8c22\u4ed6\u3002\u6587\u7ae0\u53d1\u8868\u540e\uff0c\u6211\u7ed9Ohshima\u56de\u4fe1\u611f\u8c22\u4ed6\uff0c\u628a\u6587\u7ae0\u7684PDF\u7ed9\u4ed6\u770b\u4e86\u3002\u4ed6\u4e5f\u56de\u4fe1\u5bf9\u6211\u8fdb\u884c\u4e86\u9f13\u52b1\uff1a Dear Dr. Weixiang Sun Thank you very much for sending me your excellent work. Congratulations! I have read your\u2026","rel":"","context":"In "\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0"","block_context":{"text":"\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/tagged"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":9022,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/9022","url_meta":{"origin":5225,"position":2},"title":"\u5173\u4e8e\u9ad8\u5206\u5b50\u7684\u7ed3\u6784\u6d41\u53d8\u5b66\u6a21\u578b","author":"Andrew","date":"2024\u5e743\u67081\u65e5","format":false,"excerpt":"\u8fd9\u662f\u4e3a\u8bb8\u5143\u6cfd\u5148\u751f\u7684\u8457\u4f5c\u300a\u9ad8\u5206\u5b50\u7ed3\u6784\u6d41\u53d8\u5b66\u300b\u7684\u7b2c\u4e8c\u7ae0\u6dfb\u52a0\u7684\u8bc4\u8bba\u3002 \u8bb8\u8001\u5e08\u5728\u7b2c\u4e8c\u7ae0\u5f00\u5934\u7684\u8fd9\u6bb5\u8bdd\u2014\u2014 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\u2014\u2014\u81f3\u4eca\u770b\u6765\u4ecd\u628a\u8be5\u4e66\u51fa\u7248\u65f6\uff081988\u5e74\uff09\u5df2\u7ecf\u5b9a\u578b\u7684\u7406\u8bba\u8ba4\u8bc6\u603b\u7ed3\u5f97\u5f88\u597d\u3002\u8fd9\u4e9b\u6a21\u578b\u53ef\u79f0\u4e3a\u9ad8\u5206\u5b50\u6eb6\u6db2\u7684\u6d41\u53d8\u5b66\u6027\u8d28\u7684\u201c\u7ecf\u5178\u6a21\u578b\u201d\u3002\u5b83\u4eec\u90fd\u662f\u6d41\u4f53\u52a8\u529b\u5b66\uff08hydrodynamic\uff09\u6a21\u578b\uff0c\u5373\u660e\u660e\u6eb6\u8d28\u5206\u5b50\uff08\u5bf9\u4e8e\u9ad8\u5206\u5b50\u6eb6\u8d28\u5219\u6307\u4e00\u4e2a\u94fe\u6bb5\u5355\u5143\uff09\u4e0e\u6eb6\u5242\u5206\u5b50\u7684\u5c3a\u5bf8\u548c\u8d28\u91cf\u5dee\u522b\u4e0d\u5927\uff0c\u5374\u89c6\u540e\u8005\u4e3a\u8fde\u7eed\u4ecb\u8d28\uff0c\u89c6\u524d\u8005\u4e3a\u60ac\u6d6e\u5728\u540e\u8005\u5f53\u4e2d\u53d1\u751f\u5e03\u6717\u8fd0\u52a8\u7684\u80f6\u4f53\u7c92\u5b50\u3002\u4e25\u683c\u610f\u4e49\u4e0a\uff0c\u8fd9\u6837\u7684\u6a21\u578b\u6240\u5f97\u51fa\u7684\u7ed3\u8bba\u5e94\u8be5\u53ea\u5728\u89c2\u6d4b\u65f6\u95f4\u5c3a\u5ea6\u5f88\u5927\u7684\u65f6\u5019\u6210\u7acb\uff0c\u5373\u6db2\u4f53\u975e\u5e73\u8861\u7edf\u8ba1\u4e2d\u7684\u6240\u8c13\u6d41\u4f53\u52a8\u529b\u5b66\u6781\u9650\uff08hydrodynamic limit\uff09\uff0c\u8be6\u89c1The Theory of Simple Liquids\u4e00\u4e66\u3002\u4f8b\u5982\uff0c\u5f39\u6027\u54d1\u94c3\u3001Rouse--Zimm\u548cDoi--Edwards\u6a21\u578b\u90fd\u5c5e\u4e8e\u6b64\u7c7b\u3002\u8fd9\u7c7b\u6a21\u578b\u7684\u5176\u4e2d\u4e00\u4e2a\u5171\u540c\u70b9\u662f\u90fd\u501f\u52a9\u4e86\u80f6\u4f53\u60ac\u6d6e\u6db2\u7684\u504f\u5e94\u529b\u5f20\u91cf\u7406\u8bba\u65b9\u6cd5\u3002\u8be5\u65b9\u6cd5\u7531Kramers\u63d0\u51fa\uff0cKirkwood\u96c6\u5927\u6210\u3002\u6b64\u5373\u4e3a\u8bb8\u8001\u5e08\u539f\u6587\u6240\u8bf4\u7684\u201c\u8ffd\u6eaf\u523040\u5e74\u4ee3\u201d\u3002\u8fd9\u4e00\u7406\u8bba\u65b9\u6cd5\u7528\u5230\u4e86Smoluschowski\u65b9\u7a0b\uff0c\u5176\u4e2d\u542b\u6709\u6d41\u4f53\u52a8\u529b\u5b66\u7684Oseen\u5f20\u91cf\u3002 \u76f8\u6bd4\u800c\u8a00\uff0c\u805a\u5408\u7269\u52a8\u529b\u5b66\u7684\u7b2c\u4e00\u539f\u7406\u6027\u6a21\u578b\u53d1\u5c55\u8f83\u665a\u3002\u6240\u8c13\u7b2c\u4e00\u539f\u7406\u6027\uff0c\u5373\u4ece\u5fae\u89c2\u5355\u5143\uff08\u805a\u5408\u7269\u94fe\u6bb5\u5355\u5143\u6216\u6eb6\u5242\u5206\u5b50\uff09\u7684Hamiltonian\u51fa\u53d1\u5efa\u7acb\u76f8\u7a7a\u95f4\u7684Liouville\u65b9\u7a0b\uff1b\u8fd0\u7528Zwanzig--Mori\u6295\u5f71\u7b97\u7b26\u6cd5\u83b7\u5f97\u4e00\u822c\u76f8\u7a7a\u95f4\u53d8\u91cf\u7684\u5e7f\u4e49Langevin\u65b9\u7a0b\uff1b\u518d\u8fd0\u7528\u67d0\u79cd\u6a21\u5f0f\u8026\u5408\u7406\u8bba\uff08mode-coupling theory\uff09\u6765\u5f97\u5230\u8bb0\u5fc6\u51fd\u6570\u548c\u5305\u62ec\u7c98\u5ea6\u5728\u5185\u7684\u5b8f\u89c2\u8f93\u9001\u6027\u8d28\u3002Zwanzig--Mori\u6295\u5f71\u7b97\u7b26\u6cd5\u53ef\u89c1Theory of Simple Liquids\u4e00\u4e66\u3002\u6a21\u5f0f\u8026\u5408\u7406\u8bba\u7531Kawasaki\u4e8e70\u5e74\u4ee3\u63d0\u51fa\u3002\u6700\u521d\u662f\u7528\u4e8e\u52a8\u529b\u5b66\u4e34\u754c\u884c\u4e3a\u7684\uff0c\u540e\u6765\u5e94\u7528\u4e8e\u975e\u4e34\u754c\u72b6\u6001\u7684\u4f53\u7cfb\u7684\u52a8\u529b\u5b66\uff0c\u53ef\u89c1Keyes\u7684\u7efc\u8ff01\u3002\u7b2c\u4e00\u4e2a\u5c06\u8fd9\u4e2a\u7406\u8bba\u6846\u67b6\u5e94\u7528\u4e8e\u805a\u5408\u7269\u4f53\u7cfb\u7684\u662fK. 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Rahman\u7684\u5de5\u4f5c\u3002\u4f5c\u8005\u63a8\u5bfc\u4e86\u6db2\u4f53\u7684\u65f6\u95f4\u4f9d\u8d56\u76f8\u5173\u51fd\u6570\u7684\u5c55\u5f00\u5f0f\u3002\u7b2c\u4e00\u9879\u5f53\u7136\u662f\u7eaf\u5e03\u6717\u8fd0\u52a8\u7684\u9ad8\u65af\u9879\uff0c\u7b2c\u4e8c\u9879\u5f00\u59cb\u7684\u9ad8\u9636\u9879\u90fd\u662f\u975e\u9ad8\u65af\u9879\uff0c\u5176\u4e2d\u5404\u7684\u7cfb\u6570\u53ef\u4ee5\u7528$\\alpha_n$\u6765\u8868\u793a\uff0c\u5176\u901a\u5f0f\u662f \\begin{equation}\\label{eq:2} \\alpha_n=\\frac{\\langle r^{2n}\\rangle}{C_n\\langle r^2\\rangle^n}-1 \\end{equation} \u5176\u4e2d$C_n=1\\cdot3\\cdot5\\cdots\\left(2n+1\\right)\/3^n$\u3002\u56e0\u6b64$\\alpha_2$\u6070\u597d\u5c31\u662f\u5f0f(\\ref{eq:1})\u3002\u6216\u8005\u8bf4\uff0c\u901a\u8fc7\u5c55\u5f00\u5f97\u5230\u7684\u7b2c\u4e8c\u9879\u7cfb\u6570\uff0c\u6070\u597d\u5c31\u662f\u4e00\u4e2a\u8ddf\u5cf0\u5ea6\u6709\u5173\u7684\u91cf\u3002\u4e5f\u5c31\u662f\u8bf4\uff0c$\\alpha_2$\u5176\u5b9e\u662f\u65f6\u95f4\u76f8\u5173\u51fd\u6570\u5c55\u5f00\u5f0f\u7684\u7b2c2\u9879\uff0c\u6240\u4ee5\u4e0b\u6807\u6709\u4e2a2\u3002\u81ea\u6587\u732e\u540e\uff0c$\\alpha_2$\u5f88\u5feb\u88ab\u91c7\u7528\u4e3a\u201c\u975e\u9ad8\u65af\u7cfb\u6570\u201d\u7528\u6765\u63cf\u8ff0\u6db2\u4f53\u6027\u8d28\uff0c\u6210\u4e3a\u6db2\u4f53\u7406\u8bba\u4e2d\u7684\u4e00\u4e2a\u91cd\u8981\u53c2\u6570\u3002\u540e\u6765\u80f6\u4f53\u7269\u7406\u7684\u5174\u8d77\uff0c\u7531\u4e8e\u5176\u7406\u8bba\u57fa\u7840\u57fa\u672c\u4e0a\u662f\u6db2\u4f53\u7269\u7406\uff0c\u6240\u4ee5\u5f88\u81ea\u7136\u5c31\u7528\u4e86\u76f8\u4f3c\u7684\u8ba8\u8bba\u8303\u5f0f\uff0c\u4f7f\u7528$\\alpha_2$\u8fd9\u4e2a\u7b26\u53f7\u3002\u518d\u4e00\u6b21\u8bf4\u660e\uff0c\u8981\u60f3\u505a\u597d\u80f6\u4f53\u7269\u7406\u7684\u7814\u7a76\uff0c\u5f88\u5e94\u8be5\u5e94\u8be5\u4ece\u6db2\u4f53\u7269\u7406\u5f00\u59cb\u8865\u4e60\u3002\u4e8b\u5b9e\u4e0a\uff0c\u6587\u732e\u662f\u6700\u65e9\u7528\u8ba1\u7b97\u673a\u6765\u8ba1\u7b97\u6db2\u4f53\u7684\u76f8\u5173\u51fd\u6570\u7684\u5de5\u4f5c\u3002\u4f5c\u8005Aneesur Rahman\u662f\u201c\u5206\u5b50\u52a8\u529b\u5b66\u4e4b\u7236\u201d\u3002\u5728\u6709\u8ba1\u7b97\u673a\u4e4b\u524d\uff0c\u76f8\u5173\u51fd\u6570\u53ea\u6709\u7406\u60f3\u6c14\u4f53\u548c\u683c\u5b50\u6676\u4f53\u624d\u80fd\u8ba1\u7b97\uff0c\u6db2\u4f53\u7684\u76f8\u5173\u51fd\u6570\u7531\u4e8e\u591a\u4f53\u6548\u5e94\u800c\u96be\u4ee5\u8ba1\u7b97\u3002Aneesur Rahman\u5728\u5f53\u65f6\u7684CDC 3600\u8d85\u7ea7\u8ba1\u7b97\u673a\u4e0a\u8ba1\u7b97\u4e86864\u4e2aLennard-Jones\u4f5c\u7528\u52bf\u7684\u539f\u5b50\uff0c\u6a21\u62df\u6db2\u6c29\u3002","rel":"","context":"In "\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0"","block_context":{"text":"\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/tagged"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":6221,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/6221","url_meta":{"origin":5225,"position":4},"title":"J. Chem. Educ.\u4e0a\u7684\u6d41\u53d8\u5b66","author":"Andrew","date":"2015\u5e741\u670828\u65e5","format":"aside","excerpt":"\u6211\u4e00\u76f4\u90fd\u8ba2\u9605ACS\u7684J. Chem. Educ.\u671f\u520a\uff0c\u53d1\u73b0\u6700\u8fd1\u5bc6\u96c6\u51fa\u73b0\u4e86\u51e0\u7bc7\u5173\u4e8e\u6d41\u53d8\u5b66\u7684\u6587\u7ae0\uff0c\u8fd9\u5c31\u8ba9\u6211\u60f3\u8d77\u53bb\u627e\u627eJ. Chem. Educ.\u4ece\u521b\u520a\u4ee5\u6765\u5173\u4e8e\u6d41\u53d8\u5b66\u7684\u6587\u7ae0\u90fd\u6709\u54ea\u4e9b\u3002 \u7528rheology\u4e3a\u5173\u952e\u8bcd\uff0c\u641c\u51fa\u6765\u7684\u7ed3\u679c\u5176\u5b9e\u5e76\u4e0d\u591a\uff0c\u4f46\u662f\u91cc\u9762\u4e5f\u6709\u5f88\u591a\u6709\u610f\u601d\u7684\u4e1c\u897f\u3002\u6211\u6311\u9009\u4e86\u4e00\u4e9b\u51fa\u6765\u3002 1929\u5e74\u6b63\u662f\u7f8e\u56fd\u6d41\u53d8\u5b66\u4f1a\u6210\u7acb\u7684\u90a3\u5e74\uff0cBingham\u5728J. Chem. Educ.\u53d1\u8868\u4e86\u4e24\u7bc7\u6587\u7ae0\u6765\u4ecb\u7ecd\u8fd9\u4e2a\u65b0\u7684\u5b66\u79d1\u3002\u4ed6\u4e3b\u8981\u5f3a\u8c03\u4e86\u9664\u4e86\u5c42\u6d41\u548c\u6e4d\u6d41\u4e4b\u5916\u8fd8\u6709\u201c\u7b2c\u4e09\u79cd\u6d41\u201d\u5c31\u662f\u5c48\u670d\u548c\u5851\u6027\u6d41\u52a8\u3002\u4ed6\u5176\u5b9e\u4e5f\u5f3a\u8c03\u4e86\u8fd9\u79cd\u6d41\u52a8\u6027\u8d28\u662f\u80f6\u4f53\u7269\u8d28\u7684\u7279\u5f81\u3002\u6bd5\u7adf\uff0c\u5bbe\u6c49\u6d41\u4f53\u662f\u4ee5\u4ed6\u540d\u5b57\u547d\u540d\u7684\u30021930\u5e74\uff0cJ. Chem. Educ.\u62a5\u9053\u4e86\u6d41\u53d8\u5b66\u4f1a\u5728\u7f8e\u56fd\u56fd\u5bb6\u6807\u51c6\u5c40\u53ec\u5f00\u7684\u6d88\u606f\uff0c\u5217\u51fa\u4e86\u90e8\u5206\u4f1a\u8bae\u8bba\u6587\u53ca\u4f5c\u8005\uff0c\u5176\u4e2d\u6709Bingham\u3001Reiner\u548cScott-Blair\u8fd9\u51e0\u4e2a\u8457\u540d\u7684\u7b2c\u4e00\u4ee3\u6d41\u53d8\u5b66\u5bb6\u3002\u5176\u4e2dReiner\u6f14\u8bb2\u9898\u76ee\u7adf\u7136\u53eb\u505aThe General Equation of Flow!\uff08\u539f\u6807\u9898\u5c31\u542b\u611f\u53f9\u53f7\uff09\uff0c\u8ba9\u6211\u5f88\u597d\u5947\u6f14\u8bb2\u7684\u5185\u5bb9\u662f\u600e\u4e48\u6837\u7684\u3002 \u65f6\u95f4\u4e00\u4e0b\u5b50\u8df3\u5230\u4e8660\u5e74\u4ee3\uff0cFerry\u5728J. Chem. Educ.\u4e0a\u4ecb\u7ecd\u6d41\u53d8\u5b66\uff0c\u4e3b\u8981\u5173\u6ce8\u70b9\u5c31\u662f\u9ad8\u5206\u5b50\u6d41\u53d8\u5b66\u4e86\u3002\u4ed6\u5b9e\u8d28\u4e0a\u4ecb\u7ecd\u4e86\u7c98\u5f39\u6027\u7684\u6982\u5ff5\uff0c\u4f46\u8bed\u8a00\u4e0a\u662f\u8bf4\u201c\u6d41\u4f53\u4e5f\u80fd\u50a8\u5b58\u80fd\u91cf\u201d\uff0c\u539f\u56e0\u5c31\u662f\u201c\u5206\u5b50\u94fe\u88ab\u63a5\u4f38\u201d\u3002\u6587\u7ae0\u4e0d\u53ef\u907f\u514d\u5730\u4e5f\u89e3\u91ca\u4e86\u4e00\u4e9b\u201c\u71b5\u5f39\u6027\u201d\u6982\u5ff5\u3002\u6700\u540e\u4ecb\u7ecd\u4e86\u7ebf\u6027\u7c98\u5f39\u6027\u7684\u677e\u5f1b\u8c31\u3002 Weissenberg\u6548\u5e94\u662f1940\u5e74\u4ee3\u53d1\u73b0\u7684\u3002\u4f46\u662f\u5176\u539f\u56e0\u4e00\u76f4\u523060\u5e74\u4ee3\u8fd8\u4e0d\u662f\u5f88\u6e05\u695a\uff0c\u8fd8\u5904\u4e8e\u53d1\u73b0\u54ea\u4e9b\u7269\u8d28\u4f1a\u6709\u8fd9\u4e2a\u6548\u5e94\u7684\u9636\u6bb5\u30021961\u5e74Nature\u4e0a\u7684\u4e00\u7bc7\u6587\u7ae0\uff0c\u5176\u5185\u5bb9\u5c31\u662f\u53d1\u73b0\u86cb\u767d\u6709Weissenberg\u6548\u5e94\u3002\u5728J. 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Educ.\u4e0a\u4e5f\u6709\u4e00\u7bc7\u6587\u7ae0\uff0c\u8bf4\u660e\u80f6\u53ef\u4ee5\u4f5c\u4e3a\u6f14\u793aWeissenberg\u6548\u5e94\u7684\u65b9\u4fbf\u7684\u6750\u6599\u3002 \u6d41\u53d8\u5b66\u6b63\u5f0f\u63d0\u51fa\u662f1920\u5e74\u3002\u8fd9\u521a\u597d\u4e5f\u662fStaudinger\u53d1\u8868\u300a\u8bba\u805a\u5408\u300b\u7684\u90a3\u5e74\uff0c\u9ad8\u5206\u5b50\u6982\u5ff5\u8fd8\u6ca1\u6709\u88ab\u5e7f\u6cdb\u63a5\u53d7\u3002\u6240\u4ee5\uff0c\u5f15\u8d77\u5b66\u8005\u5173\u6ce8\u590d\u6742\u6d41\u4f53\u7684\u6d41\u53d8\u73b0\u8c61\u7684\uff0c\u90fd\u662f\u80f6\u4f53\u4f53\u7cfb\u6837\u54c1\uff08\u6216\u8005\u8bf4\u5728\u5f53\u65f6\u90fd\u53eb\u80f6\u4f53\uff09\u3002\u4e8b\u5b9e\u4e0a\uff0c\u5173\u4e8e\u7c98\u5f39\u6027\uff08\u5f53\u53ebelastic aftereffect\uff09\u3001\u7c98\u5ea6\u7684\u526a\u5207\u901f\u7387\u4f9d\u8d56\u6027\uff0c\u4eba\u4eec\u57281920\u5e74\u4ee5\u524d\u5df2\u7ecf\u8ba4\u8bc6\u5f97\u6bd4\u597d\u4e86\uff08\u4ee5Maxwell\u7528\u5fae\u5206\u65b9\u7a0b\u7684\u5f62\u5f0f\u63cf\u8ff0\u7ebf\u6027\u7c98\u5f39\u6027\u7684\u666e\u904d\u5f62\u5f0f\u4e3a\u6807\u5fd7\uff09\u3002\u8fd9\u4e9b\u7814\u7a76\u4ee5\u864e\u514b\u548c\u725b\u987f\u4e3a\u6e90\u5934\uff0c\u7ecf\u8fc7\u6cca\u8083\u53f6\u3001\u67ef\u897f\u3001Maxwell\u548cBoltzmann\u7b49\u4eba\u8fdb\u5165\u5230\u4e8c\u5341\u4e16\u7eaa\uff0c\u672c\u6765\u5c31\u5df2\u7ecf\u5c5e\u4e8e\u6d41\u4f53\u529b\u5b66\u6216\u8005\u8fde\u7eed\u4f53\u529b\u5b66\u7684\u7814\u7a76\u8303\u56f4\u3002Reiner\u5728\u542c\u8bf4Bingham\u8981\u63d0\u51fa\u6d41\u53d8\u5b66\u4f5c\u4e3a\u4e00\u4e2a\u65b0\u7684\u5b66\u79d1\u65f6\u4e5f\u662f\u8fd9\u4e48\u56de\u590d\u7684\u3002\u4e8b\u5b9e\u4e0a\uff0c\u8fd9\u4e00\u7ebf\u7684\u7814\u7a76\u540e\u7eed\u8fd8\u6709Rivlin\u3001Oldroyd\u3001Noll\u3001Truesdell\u7b49\u4eba\u6cbf\u7740\u4f53\u529b\u5b66\u548c\u7406\u6027\u529b\u5b66\u7684\u8def\u5b50\u8d70\u4e0b\u53bb\uff0c\u53ea\u662f\u540e\u6765\u6d41\u53d8\u5b66\u771f\u7684\u5f62\u6210\u4e00\u4e2a\u5b66\u79d1\u4e4b\u540e\u628a\u4ed6\u4eec\u7684\u4e00\u4e9b\u5de5\u4f5c\u7eb3\u5165\u5230\u4e86\u81ea\u5df1\u5b66\u79d1\u7684\u7406\u8bba\u57fa\u7840\u800c\u5df2\u3002\u53ef\u4ee5\u8bf4\uff0c\u8fd9\u4e00\u7ebf\u7814\u7a76\u786e\u5b9e\u4e0d\u9700\u8981\u53e6\u5916\u518d\u8bbe\u7acb\u4e00\u4e2a\u5b66\u79d1\u3002\u6240\u4ee5Bingham\u5728J. Chem. Educ.\u4e0a\u7684\u6587\u7ae0\uff0c\u4e3a\u4e86\u786e\u7acb\u6d41\u53d8\u5b66\u8fd9\u4e00\u5b66\u79d1\uff0c\u660e\u786e\u5730\u6307\u51fa\u5927\u5bb6\u6240\u5ffd\u89c6\u7684\u6d41\u52a8\u662f\u5851\u6027\u6d41\u52a8\uff0c\u5373\u8ddf\u5f53\u65f6\u5173\u4e8e\u7c98\u5f39\u6027\u7684\u8fde\u7eed\u4ecb\u8d28\u672c\u6784\u65b9\u7a0b\u7814\u7a76\u65e0\u5173\u7684\u3001\u90a3\u79cd\u5177\u6709\u5c48\u670d\u5e94\u529b\u7684\u7ed3\u6784\u6d41\u4f53\u7684\u6d41\u52a8\uff08\u5728Bingham\u7684\u6587\u7ae0\u4e2d\u7684\u4f8b\u5b50\u662f\u4e00\u4e2a\u4e73\u6db2\u6837\u54c1\uff09\u3002\u4ed6\u8bf4\uff1a The hydraulicians were not aware that there is more than the one type of flow, and the type with which they were occupied did not\u2026","rel":"","context":"In "\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0"","block_context":{"text":"\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/tagged"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":6765,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/6765","url_meta":{"origin":5225,"position":5},"title":"\u8270\u96be\u7684\u8bba\u6587\u53d1\u8868\u4e4b\u8def","author":"Andrew","date":"2015\u5e7412\u67084\u65e5","format":"aside","excerpt":"\u53c8\u4e00\u4efd\u5de5\u4f5c\u53d1\u8868\u4e86\u3002\u8fd9\u7bc7\u8bba\u6587\u5176\u5b9e\u662f\u63a5\u7740\u4e0a\u4e00\u7bc7\u5de5\u4f5c\u7684\u7ee7\u7eed\u3002\u6709\u4eba\u8bf4\uff0c\u81ea\u5df1\u7684\u8bba\u6587\uff0c\u53d1\u8868\u4e4b\u540e\u5c31\u4e0d\u60f3\u91cd\u770b\u4e86\u3002\u80fd\u591f\u53d1\u8868\u503c\u5f97\u81ea\u5df1\u80af\u5b9a\u7684\u8bba\u6587\uff0c\u90fd\u4e0d\u662f\u5bb9\u6613\u7684\u4e8b\u60c5\uff0c\u66f4\u4e0d\u7528\u8bf4\u8ba9\u522b\u4eba\u80af\u5b9a\u4e86\u3002\u54ea\u6015\u662f\u5982\u6b64\u65e0\u8da3\u7684\u5de5\u4f5c\uff0c\u6211\u7684publication rate\u4e5f\u7279\u522b\u4f4e\uff0c\u56e0\u4e3a\u6bcf\u4e00\u7bc7\u8bba\u6587\uff0c\u6211\u90fd\u5e0c\u671b\u63a8\u8fdb\u4e00\u6b65\uff0c\u800c\u6211\u57fa\u7840\u6bd4\u8f83\u8584\u5f31\uff0c\u8fd9\u63a8\u8fdb\u7684\u4e00\u6b65\u5f80\u5f80\u662f\u4ece\u8865\u4e60\u57fa\u672c\u77e5\u8bc6\u5f00\u59cb\uff1a\u5148\u5b66\u4e60\u57fa\u672c\u7406\u8bba\u7684\u76f8\u5173\u6559\u79d1\u4e66\u4e86\u89e3\u4e00\u822c\u7684\u60c5\u51b5\uff0c\u7136\u540e\u770b\u76f8\u5173\u7684\u6587\u732e\u4e86\u89e3\u8ddf\u6211\u7684\u95ee\u9898\u63a5\u8fd1\u7684\u60c5\u51b5\uff0c\u7136\u540e\u518d\u8003\u8651\u6211\u7684\u9700\u8981\u53d1\u8868\u7684\u95ee\u9898\u3002\u5982\u679c\u6211\u6bcf\u7bc7\u8bba\u6587\u90fd\u53ea\u6709\u5f53\u524d\u7684\u77e5\u8bc6\u7684\u7406\u89e3\uff0c\u90a3\u6211\u5c31\u4f1a\u66f4\u52a0\u5728\u6bd4\u8f83\u6e23\u7684\u6c34\u5e73\u4e0a\u505c\u6b65\u4e0d\u524d\u3002\u5728\u8fd9\u91cc\uff0c\u6211\u4e0d\u6015\u522b\u4eba\u7b11\u8bdd\u6211\u57fa\u7840\u6c34\u5e73\u66fe\u7ecf\u6709\u591a\u5dee\uff0c\u7b80\u5355\u8bb0\u5f55\u4e00\u4e0b\u6211\u600e\u4e48\u4ece\u83dc\u9e1f\u8d70\u8fc7\u6765\u7684\u3002\u5c06\u6765\u4e5f\u4f1a\u4e00\u76f4\u8d70\u4e0b\u53bb\u3002\u535a\u58eb\u751f\u671f\u95f4\u4ece\u96f6\u5f00\u59cb\u5b66\u4e60\u6d41\u53d8\u5b66\u4e4b\u540e\u8fdb\u884cLAOS\u7814\u7a76\u7684\u7ecf\u5386\uff0c\u5c31\u4e0d\u63d0\u4e86\u3002\u62112012\u5e74\u7684\u90a3\u7bc7J. 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at 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Matter\u662f\u63a5\u7740\u4e0a\u8ff0\u7684\u5de5\u4f5c\u7684\u3002\u4f46\u4e5f\u662f\u5b66\u4e60\u53e6\u4e00\u4e2a\u7ec4\u505a\u51fa\u7684\u52a8\u6001\u7c98\u5f39\u8c31\u7684\u53e0\u52a0\u6027\u7ed3\u679c\uff0c\u6362\u6210\u4e86\u8ddf2012\u5e74\u4e00\u6837\u7684\u4f53\u7cfb\uff0c\u628a\u4eba\u5bb6\u770b\u5230\u8fc7\u7684\u89c4\u5f8b\u91cd\u590d\u4e86\u4e00\u904d\u3002\u4f46\u662f\uff0c\u8fd9\u7bc7\u8bba\u6587\u7a81\u7834\u4e86time-aging time superposition\u7684\u5df2\u77e5\u884c\u4e3a\uff0c\u5c55\u793a\u4e86time-X superposition\u884c\u4e3a\uff0cX\u4ee3\u8868\u80fd\u4fee\u9970\u7c92\u5b50\u76f8\u4e92\u4f5c\u7528\u52bf\u7684\u5404\u7c7b\u6761\u4ef6\u3002\u4e00\u5f00\u59cb\u4e0d\u77e5\u5929\u9ad8\u5730\u539a\uff0c\u8bd5\u6295PRL\uff0c\u7ed3\u679c\u7531\u4e8e\u9009\u53d6\u7684Laponite\u6d53\u5ea6\u4f53\u7cfb\u5728\u5df2\u62a5\u9053\u7684\u76f8\u56fe\u4e2d\u4f4d\u7f6e\u5c34\u5c2c\uff0c\u96be\u4ee5\u8bf4\u660e\u662fgel\u8fd8\u662fglass\u3002\u8fd9\u4e2a\u95ee\u9898\u73b0\u5728\u6211\u5176\u5b9e\u6709\u6bd4\u8f83\u81ea\u4fe1\u7684\u770b\u6cd5\uff0c\u540e\u9762\u6709\u65f6\u95f4\u4f1a\u63d0\u5230\u3002\u4f46\u5f53\u65f6\u6211\u81ea\u5df1\u5bf9\u5df2\u62a5\u9053\u7684Laponite\u76f8\u56fe\u4e5f\u7406\u89e3\u4e0d\u6df1\uff0c\u65e2\u65e0\u6cd5\u6279\u5224\u5b83\u4eec\uff0c\u53c8\u65e0\u6cd5\u89e3\u91ca\u81ea\u5df1\u7684\u4f53\u7cfb\uff0c\u7ed3\u679c\u5c31\u5728\u8fd9\u4e2a\u95ee\u9898\u4e0a\u5361\u4f4f\uff0cPRL\u6295\u4e0d\u8fdb\u53bb\uff0c\u5c31\u6539\u6295\u4e86Soft Matter\u63a5\u6536\u4e86\u3002\u5c3d\u7ba1\u63a5\u6536\u4e86\uff0c\u81f3\u4eca\u672a\u6709\u4ed6\u4eba\u5f15\u7528\u3002\u5f53\u65f6PRL \u5ba1\u7a3f\u610f\u89c1\u8fd8\u63d0\u51fa\u6211\u4eec\u5e94\u8be5\u63d0\u51fa\u4e00\u4e2a\u6a21\u578b\u53bb\u63cf\u8ff0\u8fd9\u4e2a\u73b0\u8c61\uff0c\u4e0d\u80fd\u53ea\u662f\u5b9e\u9a8c\u3002\u4e8e\u662f\u6211\u53c8\u5728\u56de\u590d\u5ba1\u7a3f\u610f\u89c1\u7684\u9650\u671f\u5185\u67e5\u9605\u4e86\u5927\u91cf\u8bba\u6587\u3002\u73b0\u5728\u77e5\u9053\uff0c\u8981\u4ece\u80f6\u4f53\u76f8\u4e92\u4f5c\u7528\u52bf\u51fa\u53d1\uff0c\u9884\u6d4b\u5176\u51dd\u80f6\u6216\u73bb\u7483\u6001\u7684\u7ebf\u6027\u7c98\u5f39\u6027\u7684\u7406\u8bba\uff0c\u4e5f\u5c31\u53ea\u6709\u57fa\u4e8eschematic MCT\u7684F12\u6a21\u578b\u3002\u8def\u5b50\u4e0d\u662f\u6ca1\u6709\u7684\uff0c\u4ece\u76f8\u4e92\u4f5c\u7528\u52bf\u80fd\u51fa\u53d1\uff0c\u91c7\u7528\u4e00\u4e2a\u5e38\u7528\u7684\u6bd4\u5982\u8bf4Percus\u2013Yevick\uff0c\u5f97\u5230\u76f8\u5e94\u7684\u9759\u6001\u7ed3\u6784\u56e0\u5b50\uff0c\u7136\u540e\u4ee3\u5165MCT\u7684kernal\u5f0f\u4e2d\u8ba1\u7b97memory function\uff1b\u7136\u540e\u4ee3\u5165\u5c0f\u5e45\u6b63\u5f26\u632f\u8361\u5e94\u53d8\uff0c\u8ba1\u7b97\u77ac\u6001\u5e94\u529b\u54cd\u5e94\uff0c\u5e76\u5f97\u5230\u76f8\u5e94\u7684\u590d\u6570\u6a21\u91cf\u3002\u8fd9\u4e00\u5927\u901a\u8ba1\u7b97\uff0c\u6211\u5f53\u65f6\u770b\u50bb\u773c\u4e86\uff0c\u6240\u4ee5\u653e\u5f03\u4e86\u3002\u73b0\u5728\uff0c\u867d\u7136\u5927\u81f4\u89c9\u5f97\u90fd\u61c2\u5f04\uff0c\u4f46\u6ca1\u6709\u7cbe\u529b\u5199\u8fd9\u4e2a\u7a0b\u5e8f\u3002\u7ecf\u8fc7\u5bf9Laponite\u4f53\u7cfb\u7684\u4e00\u6bb5\u65f6\u95f4\u63a5\u89e6\uff0c\u6211\u8d8a\u6765\u8d8a\u5f3a\u70c8\u5730\u89c9\u5f97\uff0c\u90a3\u4e9b\u5728\u5df2\u62a5\u9053\u76f8\u56fe\u4e2d\u6807\u660e\u4e3a\u201c\u73bb\u7483\u201d\u7684\u914d\u6bd4\u4f53\u7cfb\u5176\u5b9e\u5e94\u8be5\u662f\u51dd\u80f6\u3002\u4e3a\u6b64\uff0c\u6211\u5f00\u59cb\u9010\u7bc7\u67e5\u9605\u5173\u4e8eLaponite\u76f8\u56fe\u7684\u8bba\u6587\u3002\u4f46\u8fd9\u6d89\u53ca\u5230\u201c\u4f55\u4e3a\u80f6\u4f53\u73bb\u7483\/\u51dd\u80f6\u201d\u7684\u95ee\u9898\uff0c\u6211\u53c8\u6269\u5927\u5230\u4e86\u6240\u6709\u786c\u7403\u4f53\u7cfb\u7684\u5e73\u8861\u6001\u76f8\u8f6c\u53d8\u7814\u7a76\u3002\u8fd9\u4e00\u4e0b\u5b50\u6d89\u53ca\u9762\u5c31\u5927\u4e86\uff0c\u800c\u4e14\u6211\u4e00\u4e0b\u5b50\u610f\u8bc6\u4e0d\u5230\uff0c\u6211\u9996\u5148\u5e94\u8be5\u6709\u5e73\u8861\u6001\u7edf\u8ba1\u7269\u7406\u7684\u57fa\u7840\u4ee5\u53ca\u8ba1\u7b97\u673a\u6a21\u62df\u65b9\u6cd5\u7684\u57fa\u7840\uff0c\u4e00\u76f4\u901a\u8fc7\u6587\u732e\u603b\u7ed3\u77e5\u8bc6\uff0c\u8fd9\u6bb5\u65f6\u95f4\u5927\u6982\u662f\u4ece2013\u5e74\u52302014\u5e74\u8fd9\u4e00\u5e74\u7684\u65f6\u95f4\u3002\u6211\u5927\u6982\u4ece\u6982\u5ff5\u4e0a\u641e\u6e05\uff0c\u4e5f\u8c03\u67e5\u6e05\u695a\u628aLaponite\u4f53\u7cfb\u770b\u4f5c\u73bb\u7483\u7684\u89c2\u70b9\u53f2\u53ca\u8bc1\u636e\uff0c\u8ba4\u4e3a\u54ea\u6015\u7efc\u8ff0\u90fd\u53d1\u8868\u4e86\uff0c\u4f46\u8fd9\u4e2a\u89c2\u70b9\u662f\u7f3a\u4e4f\u652f\u6301\u7684\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u8ddf\u6211\u505a\u5b9e\u9a8c\u7684\u5e08\u5f1f\u53c8\u91cd\u590d\u6211\u5df2\u53d1\u8868\u5de5\u4f5c\u7684\u5957\u8def\uff0c\u8fd9\u6b21\u4ed6\u53d8\u5316\u4e86\u4e0d\u540c\u7684\u6e29\u5ea6\u505a\u52a8\u529b\u5b66\u66f2\u7ebf\uff0c\u7136\u540e\u53d1\u73b0\u53ef\u53e0\u52a0\u6027\u3002\u672c\u6765\u6211\u63d0\u4e0d\u8d77\u7cbe\u795e\u53bb\u6574\u7406\u8fd9\u79cd\u91cd\u590d\u7684\u5de5\u4f5c\uff0c\u4f46\u662f\u6bd5\u7adf\u5de5\u4f5c\u4e86\uff0c\u6ca1\u8d28\u91cf\u6709\u6570\u91cf\u4e5f\u597d\u554a\u3002\u8fd9\u4e2a\u5e08\u5f1f\u7684\u5b9e\u9a8c\u7ed3\u679c\u6709\u4e00\u4e2a\u5c0f\u5f02\u5e38\uff0c\u5c31\u662fLaponite\u51dd\u80f6\u5316\u5feb\u6162\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u4e0d\u662f\u5355\u8c03\u7684\u3002\u4e00\u5f00\u59cb\u6211\u89c9\u5f97\u8fd9\u4e5f\u5f88\u96be\u8bf4\u51fa\u4e2a\u4ec0\u4e48\uff0c\u800c\u4e14\u5047\u5982\u91c7\u7528\u4ee5\u524d\u7528\u8fc7\u7684\u4e0d\u53ef\u9006\u805a\u96c6\u6a21\u578b\u518d\u6765\u8ba1\u7b97\u4e00\u756a\uff0c\u4e5f\u65e0\u8bba\u5982\u4f55\u4e0d\u4f1a\u7b97\u51fa\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u3002\u4e8e\u662f\u60f3\u4e5f\u8bb8\u4e0d\u540c\u6e29\u5ea6\u4e0b\u4e5f\u8bb8\u7c92\u5b50\u8868\u9762\u7279\u6027\u4f1a\u4e0d\u540c\uff0c\u662f\u4ece\u76f8\u4e92\u4f5c\u7528\u52bf\u5c42\u9762\u5f71\u54cd\u5bfc\u81f4\u7684\u7ed3\u679c\uff0c\u4e8e\u662f\u5c31\u8ba9\u5e08\u5f1f\u8865\u6d4b\u4e86\u4e00\u4e0b\u4e0d\u540c\u7535\u5bfc\u7387\u548cpH\u503c\uff0c\u76f4\u63a5\u8ba1\u7b97\u8868\u9762\u7535\u8377\u5bc6\u5ea6\uff08\u800c\u4e0d\u662f\u7b80\u5355\u7528\u4e00\u4e2a\u6587\u732e\u62a5\u9053\u7684zeta\u7535\u52bf\u6765\u4ee3\u5165\u8ba1\u7b97\uff09\u3002\u867d\u7136\u4ecd\u7136\u6ca1\u53d1\u73b0\u4ec0\u4e48\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\uff0c\u4f46\u8fd8\u662f\u60f3\u786c\u7740\u5934\u76ae\u5f80\u4e0b\u7b97\uff0c\u9047\u5230\u4e86\u4e00\u4e2a\u65b0\u95ee\u9898\uff0c\u5c31\u662f\u8fd9\u6b21\u5e08\u5f1f\u7528\u7684\u662f\u65e0\u76d0\u7c92\u5b50\u60ac\u6d6e\u6db2\uff0c\u6db2\u4f53\u4e2d\u7684\u79bb\u5b50\u5168\u662f\u7c92\u5b50\u7535\u79bb\u7684\u53cd\u79bb\u5b50\u3002\u6211\u60f3\u4e86\u534a\u5929\u4e0d\u77e5\u9053\u600e\u4e48\u8003\u8651\uff0c\u7ffb\u9605H. Ohshima\u7684Theory of Colloid and Interfacial Electric Phenomena\u4e0d\u6b62\u4e00\u6b21\uff0c\u4e5f\u627e\u4e0d\u5230\u4e66\u4e2d\u54ea\u79cd\u60c5\u51b5\u80fd\u591f\u4e0e\u6211\u7684\u5bf9\u5e94\u3002\u4e8e\u662f\u76f4\u63a5\u5199\u4fe1\u7ed9H. Ohshima\u8bf7\u6559\uff0c\u624d\u4e86\u89e3\u5230\u6211\u7684\u60c5\u51b5\u5c5e\u4e8esalt-free system\u6216\u8005counterions-only system\u3002\u4ed6\u8fd8\u4ecb\u7ecd\u6211\u770b\u4e86\u76f8\u5173\u7684\u8bba\u6587\u3002\u5176\u5b9e\uff0c\u8fd9\u7bc7\u6587\u7ae0\u5230\u6211\u77e5\u9053\u6b63\u786e\u5bf9\u5e94\u7684\u7269\u7406\u4f53\u7cfb\u65f6\uff0c\u5df2\u7ecf\u62d6\u4e86\u5f88\u4e45\uff0c\u6211\u8001\u677f\u603b\u662f\u89c9\u5f97\u4e00\u7bc7\u6587\u7ae0\u4e0d\u503c\u5f97\u5f04\u8fd9\u4e48\u4e45\u3002\u4f46\u4ed6\u4e0d\u77e5\u9053\uff0c\u4e4b\u6240\u4ee5\u4e45\uff0c\u662f\u56e0\u4e3a\u6211\u6c34\u5e73\u5dee\u3001\u5916\u884c\u3001\u8d70\u5f2f\u8def\u3002\u4ed6\u662f\u7ecf\u8fc7\u826f\u597d\u7684\u7814\u7a76\u751f\u8bad\u7ec3\u7684\u7814\u7a76\u8005\uff0c\u6709\u4ed6\u64c5\u957f\u7684\u4e13\u4e1a\uff0c\u5728\u4ed6\u64c5\u957f\u7684\u9886\u57df\u5185\uff0c\u80fd\u591f\u4e0d\u8d70\u4f4e\u7ea7\u7684\u5f2f\u8def\u3002\u800c\u6211\u6ca1\u6709\u4ec0\u4e48\u505a\u7269\u7406\u5e94\u6709\u7684\u7406\u8bba\u57fa\u7840\uff0c\u5c31\u4f1a\u8d70\u5f2f\u8def\u3002\u6240\u4ee5\uff0c\u5b66\u5230\u4e86\u6b63\u786e\u7684\u77e5\u8bc6\u4e4b\u540e\uff0c\u7518\u613f\u518d\u82b1\u4e00\u500d\u7684\u65f6\u95f4\u91cd\u65b0\u6309\u7167\u6b63\u786e\u7684\u6a21\u578b\u53bb\u8ba1\u7b97\u3002\u7ed3\u679c\u53d1\u73b0\uff0c\u901a\u8fc7\u5b9e\u9a8c\u6d4b\u5f97\u7684\u7c92\u5b50\u8868\u9762\u7279\u6027\uff0c\u518d\u6b63\u786e\u8003\u8651\u53cd\u79bb\u5b50\u51dd\u805a\uff0c\u5c31\u6070\u597d\u80fd\u9884\u6d4b\u51fa\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u3002\u8fd9\u662f\u8ba9\u6211\u5f88\u5174\u594b\u7684\u7ed3\u679c\u3002\u53ef\u662f\u4e00\u5f00\u59cb\u6295\u8fc7Langmuir\u548cSoft Matter\u90fd\u88ab\u79d2\u62d2\u4e86\uff0c\u5f88\u53d7\u632b\u3002\u540e\u6765\u8fd8\u662f\u6295J. Colloid Interf. Sci.\u53cd\u800c\u83b7\u5f97\u4e86\u597d\u8bc4\u3002\u8fd9\u6bb5\u8fc7\u7a0b\u8ba9\u6211\u76f8\u4fe1\uff0c\u8bba\u6587\u5c31\u5e94\u8be5\u6295\u5230\u9886\u57df\u76f8\u7b26\u7684\u671f\u520a\uff0c\u4e00\u70b9\u4e5f\u4e0d\u8981\u8ffd\u6c42\u5f71\u54cd\u56e0\u5b50\u548cJCR\u5206\u533a\u3002\u56e0\u4e3a\u53ea\u6709\u5c3d\u53ef\u80fd\u5bf9\u53e3\u7684\u540c\u884c\u624d\u6709\u5f97\u61c2\u4f60\u7684\u5de5\u4f5c\uff0c\u7406\u89e3\u4f60\u5de5\u4f5c\u7684\u91cd\u8981\u6027\uff0c\u7ed9\u4e88\u6709\u5efa\u8bbe\u6027\u7684\u610f\u89c1\u5e76\u5efa\u8bae\u53d1\u8868\u3002\u521a\u521a\u53d1\u8868\u7684\u5de5\u4f5c\uff0c\u5219\u662f\u53c8\u5b66\u77402013\u5e74\u7684\u90a3\u7bc7Soft Matter\u90a3\u6837\uff0c\u628a\u521a\u505a\u8fc7\u52a8\u529b\u5b66\u66f2\u7ebf\u53e0\u52a0\u7684\u4f53\u7cfb\uff0c\u518d\u505a\u4e00\u6b21\u7c98\u5f39\u8c31\u53e0\u52a0\u3002\u8fd9\u5728\u5b9e\u9a8c\u4e0a\u5b9e\u5728\u662f\u7eaf\u7cb9\u7684\u91cd\u590d\uff0c\u800c\u4e14\u8ddf2013\u5e74\u7684\u60c5\u51b5\u4e00\u6837\uff0c\u6211\u4ecd\u7136\u65e0\u6cd5\u5229\u7528schematic MCT\u6a21\u578b\u5bf9\u7c98\u5f39\u8c31\u8fdb\u884c\u7406\u8bba\u8ba1\u7b97\u6bd4\u8f83\uff0c\u6ca1\u529e\u6cd5\u7a81\u7834\u3002\u4f46\u662f\uff0c\u8fd9\u65f6\u6211\u6070\u597d\u770b\u5230\u4e86H. Winter\u7684\u4e00\u7bc7\u8bba\u6587\uff0c\u63d0\u9192\u6211\u867d\u7136\u4e0d\u80fd\u4ece\u7b2c\u4e00\u6027\u539f\u7406\u6a21\u578b\u53bb\u8ba1\u7b97\u7c98\u5f39\u8c31\uff0c\u81f3\u5c11\u53ef\u4ee5\u7528\u552f\u8c61\u6a21\u578b\u62df\u5408\u51fa\u4e00\u4e2a\u8c31\u6765\u7814\u7a76\u3002\u4e8e\u662f\u5c31\u5bf9\u7ed3\u679c\u8fdb\u884c\u4e86\u8bd5\u9a8c\uff0c\u53d1\u73b0\u5728\u6211\u7684\u7ed3\u679c\u4e2d\u5c31\u6709\u6240\u8c13\u7684\u51dd\u80f6\u5230\u73bb\u7483\u7684rheological inversion\u3002\u8fd9\u4e5f\u662f\u4ee4\u6211\u89c9\u5f97\u6709\u8da3\u7684\u7ed3\u679c\uff0c\u800c\u4e14\u7ec8\u4e8e\u4f7f\u8fd9\u90e8\u5206\u5de5\u4f5c\u4e0d\u518d\u6d41\u4e8e\u7b80\u5355\u91cd\u590d\u5df2\u6709\u5de5\u4f5c\u4e86\u3002\u7531\u4e8e\u662f\u7d27\u63a5\u7740\u505a\u7684\uff0c\u4e8e\u662f\u4e5f\u60f3\u518d\u6295\u540c\u4e00\u4e2a\u671f\u520a\uff0c\u4ee5\u4e3a\u5c31\u4f1a\u987a\u5229\u53d7\u5ba1\uff0c\u7ed3\u679c\u88ab\u79d2\u62d2\uff0c\u5341\u5206\u53d7\u632b\uff0c\u6295Colloids Surf. A\u3002\u56e0\u4e3a\u6211\u4e4b\u524d\u6709\u53e6\u5916\u4e00\u4e9b\u5b9e\u9a8c\u5de5\u4f5c\u51e0\u6b21\u6295\u4e0d\u51fa\u53bb\u6700\u540e\u90fd\u6295\u5230Colloids Surf. A\u89e3\u51b3\u7684\u3002\u8fd9\u6b21\u53ea\u597d\u53c8\u5982\u6cd5\u6ce1\u5236\u3002\u8fd8\u5728\u9001\u5ba1\u7684\u8fc7\u7a0b\u4e2d\uff0c\u6211\u53c2\u52a0\u4e86\u7f8e\u56fd\u6d41\u53d8\u5b66\u4f1a\uff0c\u5728Baltimore\u89c1\u5230\u4e86H. Winter\u672c\u4eba\u3002\u6211\u5411\u4ed6\u63cf\u8ff0\u4e86\u6211\u5bf9\u4ed6\u5de5\u4f5c\u7684\u5f15\u7528\uff0c\u4ed6\u5f88\u611f\u5174\u8da3\u3002\u4e8e\u662f\uff0c\u6211\u8868\u8fbe\u4e86\u76ee\u524d\u8fd9\u4e2a\u5de5\u4f5c\u7684\u6295\u7a3f\u72b6\u6001\uff0c\u610f\u601d\u5c31\u662f\u6c42\u4ed6\u5e2e\u5fd9\u3002\u4ed6\u7ed9\u6211\u975e\u5e38nice\u7684\u56de\u590d\u3002\u73b0\u5728\u8fd8\u662f\u987a\u5229\u53d1\u8868\u4e86\uff0c\u6211\u53ef\u4ee5\u544a\u8bc9\u4ed6\u8fd9\u4e00\u6d88\u606f\u3002\u5728\u4ee5\u4e0a\u4e24\u4e09\u5e74\u5bf9Laponite\u7684\u7814\u7a76\u8fc7\u7a0b\uff0c\u6211\u975e\u5e38\u5c0f\u5fc3\u5730\u8003\u8651\u4e86\u5b83\u7684\u76f8\u4e92\u4f5c\u7528\u52bf\uff0c\u4e5f\u4ece\u5bf9\u5176\u52a8\u529b\u5b66\u7684\u9884\u6d4b\u7ed3\u679c\u8bc1\u660e\u4e86\u8fd9\u79cd\u8003\u8651\u7684\u5408\u7406\u6027\uff0c\u6211\u7684\u7ed3\u679c\u8bf4\u660e\u522b\u4eba\u8bf4\u662f\u73bb\u7483\u7684Laponite\u4f53\u7cfb\u5176\u5b9e\u662f\u4e0d\u53ef\u9006\u805a\u96c6\u51dd\u80f6\u3002\u4e8e\u662f\uff0c\u4ee5\u524d\u8ba4\u4e3a\u56e0\u4e3a\u662f\u73bb\u7483\u6240\u4ee5\u4e0d\u5947\u602a\u7684time-aging time superposition\u73b0\u8c61\uff0c\u73b0\u5728\u5e94\u7406\u89e3\u4e3a\u4e0d\u53ef\u9006\u805a\u96c6\u51dd\u80f6\uff08\u5373\u5206\u5f62\u56e2\u7c07\u7f51\u7edc\uff09\u4e5f\u6709\u7684glassy behavior\u3002\u800c\u4e14\u6211\u8fd8\u8bc1\u5b9e\u4e86\u81f3\u5c11\u5728Laponite\u4f53\u7cfb\u7406\uff0c\u8fd8\u6709time-X superposition\uff0c\u5176\u4e2dX\u53ef\u7406\u89e3\u4e3a\u5e7f\u4e49\u6e29\u5ea6\u3002\u6211\u5e0c\u671b\u8fd9\u4e9b\u53d1\u73b0\u4e0d\u662fLaponite\u4f53\u7cfb\u7279\u6709\u7684\uff0c\u800c\u662f\u80f6\u4f53\u4f53\u7cfb\u975e\u5e73\u8861\u6001\u7684\u5171\u6027\uff0c\u4e8e\u662f\u6211\u5f00\u59cb\u5accLaponite\u4e0d\u591f\u5178\u578b\uff0c\u8003\u8651\u4f20\u7edf\u7684\u786c\u7403\u5438\u5f15\u4f53\u7cfb\u3002\u5f88\u81ea\u7136\uff0c\u6211\u53c8\u514d\u4e0d\u4e86\u4e00\u756a\u6587\u732e\u5b66\u4e60\u3002\u5438\u5f15\u529b\u7684\u6a21\u578b\u5b9e\u9a8c\u4f53\u7cfb\u65e0\u975e\u5c31\u662f\u63a5\u6709octadecyl\u7684\u4e8c\u6c27\u5316\u7845\u7c92\u5b50\u60ac\u6d6e\u6db2\u548c\u63a5\u6709PHSA\u7684PMMA\u7c92\u5b50\u60ac\u6d6e\u6db2\uff0c\u524d\u8005\u662f\u9760\u53d8\u6e29\u6539\u53d8\u6eb6\u5242\u6027\u8d28\u5f15\u5165\u5438\u5f15\u529b\u7684\uff0c\u8fd1\u4f3c\u4e8eBaxter's sticky ball\u52bf\uff0c\u540e\u8005\u5219\u662f\u901a\u8fc7\u6dfb\u52a0\u7ebf\u5f62PS\u5f15\u5165\u6392\u7a7a\u529b\uff0c\u5bf9\u5e94\u7684\u662fAsakawa-Oosawa\u52bf\u3002\u6211\u770b\u4e86\u5927\u91cf\u8ba1\u7b97\u673a\u6a21\u62df\u548c\u5b9e\u9a8c\u7ed3\u679c\uff0c\u4e8e\u662f\u5411\u82f1\u56fd\u7684\u5b9e\u9a8c\u5ba4\u8d2d\u4e70\u4e86\u4e0d\u5c11PMMA\u7c92\u5b50\uff0c\u7ed3\u679c\u53d1\u73b0\uff0c\u8fd9\u79cd\u4f53\u7cfb\u5f62\u6210\u7684\u51dd\u80f6\u7f51\u7edc\u975e\u5e38\u5f31\u3002\u660e\u660e\u5728\u663e\u5fae\u955c\u4e0b\u770b\u5230\u4e86\u5f88\u597d\u7684\u51dd\u80f6\u7f51\u7edc\uff0c\u5b8f\u89c2\u6837\u54c1\u5374\u50cf\u6c34\u4e00\u6837\u5bb9\u6613\u6d41\u52a8\uff0c\u4e1d\u6beb\u65e0\u6cd5\u652f\u6301\u81ea\u8eab\u91cd\u91cf\u3002\u4e8e\u662f\u6ca1\u6709\u7ee7\u7eed\u8fdb\u884c\u6d41\u5b66\u6d4b\u8bd5\uff0c\u8fd9\u4ef6\u4e8b\u60c5\u5c31\u6401\u7f6e\u4e86\u3002\u4e5f\u662f\u5230\u4e86\u7f8e\u56fd\u6d41\u53d8\u5b66\u4f1a\uff0c\u5728\u8ddf\u505a\u6a21\u62df\u7684R. 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