{"id":3451,"date":"2011-07-22T00:46:21","date_gmt":"2011-07-21T16:46:21","guid":{"rendered":"http:\/\/www.andrewsun.net\/panta_rhei\/?p=3451"},"modified":"2011-07-22T00:49:07","modified_gmt":"2011-07-21T16:49:07","slug":"dls-and-zeta-potential-measurement","status":"publish","type":"post","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/3451","title":{"rendered":"DLS and zeta-potential measurement"},"content":{"rendered":"<div class=\"kcite-section\" kcite-section-id=\"3451\">\n<p>Aim: To aid the theoretical modeling of the rheological data.<\/p>\n<h3>Viscosity of PEO solutions<\/h3>\n<p>Used to calculate zeta-potentials.<\/p>\n<p><em>Samples: PEG 35k aqueous solutions at <\/em><em>c<\/em><sub>p<\/sub> = 0, 0.063, 0.1, 0.25, 0.4, 0.63, 0.8, 1.0 wt%<\/p>\n<p>Instrument: AR-G2<\/p>\n<h3>DLS and zeta-potential measurement<\/h3>\n<p>Procedure: yet to determine.<\/p>\n<ul>\n<li>Principles of zeta-potential measurement?<\/li>\n<\/ul>\n<ul>\n<li>http:\/\/goo.gl\/aQVDU<\/li>\n<li>http:\/\/goo.gl\/CQtD1<\/li>\n<li>http:\/\/goo.gl\/HXNwJ<\/li>\n<li>How dilute must the samples be?<\/li>\n<li>Make sure everything is ready: filters, syringes, cuvettes, etc.<\/li>\n<\/ul>\n<p><em>Samples: Neat Laponite suspension, Laponite\/PEG suspension with PEG 35k of <\/em><em>c<\/em><sub>p<\/sub> = 0.063, 0.1, 0.25, 0.4, 0.63, 0.8, 1.0 wt%<\/p>\n<p>Instrument: Malvern Zetasizer nano zs90<\/p>\n<!-- kcite active, but no citations found -->\n<\/div> <!-- kcite-section 3451 -->","protected":false},"excerpt":{"rendered":"<p>Aim: To aid the theoretical modeling of the rheological data. Viscosity of PEO solutions Used to calculate zeta-potentials. Samples: PEG 35k aqueous solutions at cp = 0, 0.063, 0.1, 0.25, 0.4, 0.63, 0.8, 1.0 wt% Instrument: AR-G2 DLS and zeta-potential measurement Procedure: yet to determine. Principles of zeta-potential measurement? http:\/\/goo.gl\/aQVDU http:\/\/goo.gl\/CQtD1 http:\/\/goo.gl\/HXNwJ How dilute must [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"inline_featured_image":false,"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":false,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[264],"tags":[],"class_list":["post-3451","post","type-post","status-publish","format-standard","hentry","category-264"],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"","jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/p1aPvF-TF","jetpack-related-posts":[{"id":3418,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/3418","url_meta":{"origin":3451,"position":0},"title":"Rheometry of Laponite\/PEO suspensions","author":"Andrew","date":"2011\u5e747\u670821\u65e5","format":false,"excerpt":"A full lest of rheometric investigation of Laponite\/PEG suspension. Parts of the tasks have been submitted or published. Observation during preshear Comparison of different shear rates Steady shear flow [math]\\eta[\/math] vs [math]\\dot{\\gamma}[\/math]. Procedure: steady preshear at [math]\\dot{\\gamma}[\/math] = 200 s-1 for 200s, delay for 800s, steady state flow test. Samples:\u2026","rel":"","context":"In &quot;\u5de5\u4f5c\u7b14\u8bb0&quot;","block_context":{"text":"\u5de5\u4f5c\u7b14\u8bb0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/personal\/%e5%b7%a5%e4%bd%9c%e7%ac%94%e8%ae%b0"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":4296,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/4296","url_meta":{"origin":3451,"position":1},"title":"\u91cd\u65b0\u8003\u8651Laponite\u7c92\u5b50\u95f4\u4f5c\u7528\u52bf\u80fd","author":"Andrew","date":"2011\u5e7411\u67086\u65e5","format":false,"excerpt":"\u9000\u56de\u7684\u5ba1\u7a3f\u610f\u89c1\u53cd\u6620\u7a3f\u5b50\u7684\u6700\u5927\u95ee\u9898\u5728\u4e8e\u5bf9Laponite\u7c92\u5b50\u76f8\u4e92\u4f5c\u7528\u7684\u8003\u8651\u4e0d\u5468\u3002\u9700\u8981\u5bf9\u539f\u672c\u7684model\u8fdb\u884c\u6bd4\u8f83\u5927\u7684\u4fee\u6539\u3002 Laponite\u7c92\u5b50\u5f62\u72b6\u4e0e\u5e26\u7535\u7684\u5404\u5411\u5f02\u6027 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\u7531\u4e8e\u771f\u5b9e\u4e16\u754c\uff08\u975e\u8ba1\u7b97\u673a\u6a21\u62df\uff09\u7684\u5b9e\u9a8c\u624b\u6bb5\u5927\u591a\u65e0\u6cd5\u5206\u8fa8Laponite\u7c92\u5b50\u53d6\u5411\u5206\u5e03\u3002\u5e38\u7528\u7684\u52a8\u6001\u5149\u6563\u5c04\u6cd5\u6d4b\u7c92\u5f84\u548c\u7535\u6cf3\u6cd5\u6d4b\u03b6-\u7535\u4f4d\u90fd\u662f\u5047\u8bbe\u7c92\u5b50\u4e3a\u7403\u5f62\u5f97\u5230\u5b9e\u9a8c\u7ed3\u679c\u7684\u3002\u6240\u4ee5\u5c31\u7b97\u4f60\u80fd\u4ece\u7406\u8bba\u4e0a\u7ed9\u51fa\u53d6\u5411\u5206\u5e03\u7684\u5b9a\u91cf\u5173\u7cfb\uff0c\u9664\u8ba1\u7b97\u673a\u6a21\u62df\u4ee5\u5916\u4e5f\u7f3a\u4e4f\u5b9e\u9a8c\u9a8c\u8bc1\u624b\u6bb5\uff0c\u8003\u8651\u4e86\u4e5f\u767d\u8003\u8651\u3002\u56e0\u6b64\u6211\u4e0d\u592a\u7406\u89e3\u5ba1\u7a3f\u4eba\u662f\u5426\u975e\u8981\u6211\u5b9e\u7259\u5b9e\u9f7f\u5730\u8003\u8651face-edge\u76f8\u4e92\u4f5c\u7528\u4e0d\u53ef\u3002\u6211\u770b\u5230University of Washington\u7684J. Berg\u7ec4\u6709\u4e00\u7bc7\u7814\u7a76Laponite\u6d41\u53d8\u5b66\u7684\u6587\u7ae0\u76f4\u63a5\u628a\u7c92\u5b50\u5f53\u7403\u5f62\u8003\u8651\u4e86\uff0c\u4f46\u6709\u4e00\u6bb5\u5173\u4e8eedge\u548cface\u7684\u89e3\u91ca\u6587\u5b57\u5982\u4e0b\uff08\u91cd\u70b9\u662f\u6211\u52a0\u7684\uff09\uff1a The electrical surface potential must now account for the face and edge potential separately. This gives the following estimate [math]\\mathit{\\Phi}_\\textup{e}\\approx 2\\pi\\epsilon\\epsilon_0 a\\psi _\\textup{face}\\psi_\\textup{edge}\\ln\\left[\\frac{1}{1-\\exp\\left(-\\kappa D \\right )} \\right ].[\/math] The Larson anlysis went from this point to replace the surface potential\u2026","rel":"","context":"In &quot;\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0&quot;","block_context":{"text":"\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/tagged"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2498,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/2498","url_meta":{"origin":3451,"position":2},"title":"\u6587\u7ae0\u7684Discussion\u90e8\u5206","author":"Andrew","date":"2011\u5e743\u670813\u65e5","format":false,"excerpt":"\u6458\u8981\uff1a\u6eb6\u89e3\u5728\u80f6\u4f53\u60ac\u6d6e\u6db2\u4e2d\u7684\u805a\u5408\u7269\uff0c\u5982\u679c\u5438\u9644\u5728\u80f6\u4f53\u7c92\u5b50\u7684\u8868\u9762\uff0c\u7531\u4e8e\u589e\u52a0\u4e86\u65a5\u529b\u7684\u4f5c\u7528\u8ddd\u79bb\uff0c\u63d0\u9ad8\u4e86\u7c92\u5b50\u95f4\u4f5c\u7528\u52bf\u5792Umax\uff0c\u7c92\u5b50\u805a\u96c6\u901f\u7387\u4f1a\u964d\u4f4e\u3002\u8fd9\u662f\u5b9a\u6027\u7684\u89e3\u91ca\u3002\u672c\u5b9e\u9a8c\u65e2\u7136\u80fd\u5f97\u5230\u5e73\u79fb\u56e0\u5b50\u968f\u805a\u5408\u7269\u6d53\u5ea6\u7684\u53d8\u5316\u5173\u7cfb\uff0c\u5c31\u60f3\u534a\u5b9a\u91cf\u5730\u89e3\u91ca\u4e00\u4e0b\u3002\u805a\u5408\u7269\u5438\u9644\u5728\u7c92\u5b50\u4e0a\u7684\u4f4d\u963b\u52bf\u51fd\u6570\u5df2\u7ecf\u6709\u6210\u719f\u7684\u7406\u8bba\u6a21\u578b\u3002\u7c92\u5b50\u805a\u96c6\u901f\u7387\u4e0e\u4f5c\u7528\u52bf\u5792\u4e4b\u95f4\u7684\u5173\u7cfb\u4e5f\u53ef\u4ee5\u901a\u8fc7Smoluchowski\u65b9\u7a0b\u548cstability ratio\u6765\u63cf\u8ff0\u3002\u96be\u70b9\u5728\u4e8e\u8bf4\u660e\u4e24\u4e2a\u5173\u7cfb\uff1a\u4e00\u662f\u5e73\u79fb\u56e0\u5b50\u4e0eUmax\u7684\u5173\u7cfb\uff0c\u4e8c\u662f\u8981\u4ece\u7c92\u5b50\u7684\u603b\u52bf\u80fd\u51fd\u6570U=U\u8303+U\u7535+U\u805a\u5408\u7269\u7684\u8868\u8fbe\u5f0f\u6c42\u6781\u5927\u503c\uff0c\u83b7\u5f97Umax\u4e0e\u805a\u5408\u7269\u5438\u9644\u91cf\u0393\u6216\u6dfb\u52a0\u91cfcp\u7684\u5173\u7cfb\u3002\u4ee5\u4e0b\u662f\u6211\u67e5\u9605\u8d44\u6599\u540e\u7684\u603b\u7ed3\uff0c\u611f\u89c9\u6ca1\u6709\u80fd\u529b\u518d\u5b8c\u5584\u4e86\u3002 1 Laponite\u7684\u805a\u96c6\u901f\u7387 \u80f6\u4f53\u7c92\u5b50\u7684\u805a\u96c6\uff08coagulation\uff09\u8fc7\u7a0b\u53ef\u5206\u4e3a\u6269\u6563\u63a7\u5236\u578b\u548c\u53cd\u5e94\u63a7\u5236\u578b\u3002\u6269\u6563\u63a7\u5236\u578b\u662f\u7531\u4e8e\u7c92\u5b50\u4e4b\u95f4\u805a\u96c6\u53cd\u5e94\u5341\u5206\u5feb\uff08\u6d3b\u5316\u80fd\u4e3a\u96f6\uff09\uff0c\u56e0\u6b64\u53cd\u5e94\u901f\u7387\u57fa\u672c\u53ea\u53d7\u5236\u4e8e\u78b0\u649e\u673a\u7387\u3002\u6839\u636e\u5e03\u6717\u8fd0\u52a8\u7684\u516c\u5f0f\uff0c\u53ef\u4ee5\u5199\u51fa\u5176\u901f\u7387\u5e38\u6570\u3002\u800c\u53cd\u5e94\u63a7\u5236\u578b\u5219\u662f\u7531\u4e8e\u7c92\u5b50\u95f4\u6210\u529f\u5730\u7ed3\u5408\u9700\u8981\u514b\u670d\u80fd\u5792Umax\u56e0\u800c\u5e76\u975e\u6240\u6709\u78b0\u649e\u4e8b\u4ef6\u90fd\u80fd\u6210\u529f\u53d1\u751f\u805a\u96c6\uff0c\u5176\u901f\u7387\u5e38\u6570\u5c31\u8981\u6bd4\u4ec5\u53d7\u6269\u6563\u63a7\u5236\u7684kD\u5c0f\u3002\u5b9a\u4e49stability ratio\uff0cW = kD \/ kR\uff0c\u4ee5\u8868\u5f81\u53cd\u5e94\u96be\u5ea6\uff08Umax\uff09\u5bf9\u805a\u96c6\u8fc7\u7a0b\u5feb\u6162\u7684\u963b\u788d\u7a0b\u5ea6\uff0c\u5219W\u5e94\u8be5\u8ddfUmax\u6709\u5173\uff08\u4ee5\u4e0a\u53ef\u53c2\u89c1T. Cosgrove\u7b49\u5408\u7f16\u7684\u4e66[1]\uff09\u3002N. Fuch[2]\u5b9a\u4e49\uff0c\u53ef\u7528\u4e8e\u4eceU(h)\u8ba1\u7b97W\uff0c\u4f46U(r)\u7684\u5f62\u5f0f\u53d6\u51b3\u4e8e\u5177\u4f53\u7684\u805a\u5408\u7269\u5438\u9644\u6a21\u578b\uff08\u5982Scheutjens\u2013Fleer\u7684\u5e73\u5747\u573a\u7406\u8bba\u8fd8\u662fde Gennes\u7684\u6807\u5ea6\u7406\u8bba\uff09\u4e14\u8868\u8fbe\u5f0f\u590d\u6742\uff08\u56e0\u4e3a\u8fd8\u8981\u52a0\u4e0a\u8303\u5fb7\u534e\u52bf\u548c\u9759\u7535\u52bf\uff09\uff0c\u56e0\u6b64\u5b9e\u9645\u4e0a\u5f80\u5f80\u76f4\u63a5\u91c7\u7528W\u7684\u8fd1\u4f3c\u5f0f\u3002\u4f8b\u5982S. Tawari\u7b49\u548cA. Nelson\u7b49[3, 4]\u91c7\u7528\u4ee5\u4e0b\u8868\u8fbe\u5f0f\u6765\u63cf\u8ff0Laponite\u60ac\u6d6e\u6db2\u7684\u8001\u5316\uff1a \u4e0a\u5f0f\u672c\u6765\u662fPrieve and Ruckenstein[5]\u4e3a\u7403\u5f62\u7c92\u5b50\u5bfc\u51fa\u7684\u8fd1\u4f3c\u8868\u8fbe\u5f0f\uff0cLaponite\u4f5c\u4e3a\u975e\u7403\u72b6\u7c92\u5b50\uff0c\u7cfb\u65700.25\u5e94\u8be5\u504f\u5927\uff0c\u4f46\u8fd9\u4e00\u7cfb\u6570\u503c\u7684\u53d8\u5316\u5bf9W\u7684\u5927\u5c0f\u5f71\u54cd\u5f88\u5c0f\uff08\u89c1S. Tawari\u7b49\u7684\u8ba8\u8bba[3]\uff09\uff0c\u5012\u4e5f\u53ef\u4ee5\u4e0d\u53bb\u4fee\u6539\u3002\u5982\u679c\u672c\u6587\u4e5f\u91c7\u7528\u6b64\u5f0f\uff0c\u5219\u6709kR ~ W-1 ~ exp(-Umax\/kBT)\u3002 \u6839\u636eSmoluchowski\u805a\u96c6\u7406\u8bba\u7684\u5047\u8bbe\uff0c\u805a\u96c6\u8fc7\u7a0b\u662f\u4e00\u4e2a\u4e8c\u7ea7\u53cd\u5e94\u63a7\u5236\u805a\u96c62A\u2192P\uff0c\u4ea7\u7269\u751f\u6210\u91cfP\u968f\u65f6\u95f4\u7684\u53d8\u5316\u5173\u7cfb\u662f\uff1a \u5176\u4e2d\uff0cA0\u662f\u53cd\u5e94\u7269\u7684\u91cf\uff08\u4f5c\u4e3a\u7c92\u5b50\u805a\u96c6\u4f53\u7cfb\u5c31\u662f\u521d\u59cb\u7c92\u5b50\u6570\uff09\uff0ck\u662f\u53cd\u5e94\u6570\u7387\u5e38\u6570\uff08\u5373\u524d\u6587\u7684kR\uff09\u3002\u5bf9\u4e8e\u672c\u6587\u7684\u4f53\u7cfb\uff0cPEG\u7684\u6dfb\u52a0\u4f7f\u5f97Laponite\u8001\u5316\u7684\u8fc7\u7a0b\u88ab\u63d0\u524d\uff0c\u5c31\u662f\u7531\u4e8e\u805a\u5408\u7269\u7684\u4f4d\u963b\u4f5c\u7528\uff0c\u589e\u5927\u4e86Umax\u3002\u800c\u4e14Umax\u4e0ePEG\u6d53\u5ea6cp\u6709\u5173\uff0c\u56e0\u800c\u6570\u7387\u5e38\u6570k\u4e5f\u4e0ecp\u6709\u5173\u3002\u5982\u679c\u4e0d\u540ccp\u4e0b\u7684\u66f2\u7ebfP(tw, cp)\u5728\u65f6\u95f4\u5c3a\u5ea6\u4e0a\u6709\u53e0\u52a0\u6027\u4e14\u5e73\u79fb\u56e0\u5b50\u4e3aap(cp)\u3001\u53e0\u52a0\u540e\u4e3b\u66f2\u7ebf\u7684\u6a2a\u5750\u6807\u4e3atw\/ap\uff0c\u90a3\u4e48\u5c31\u6709k(cp)\/ap = k0\uff08k0\u4e3a\u53c2\u8003\u66f2\u7ebf\u7684\u901f\u7387\u5e38\u6570\uff09\uff0c\u5373ap ~ k-1 ~ W ~ exp(Umax\/kBT)\u3002\u8fd9\u5c31\u662f\u5e73\u79fb\u56e0\u5b50\u4e0eUmax\u7684\u5173\u7cfb\u3002 Y. Joshi\u66fe\u628aLaponite\u8001\u5316\u53e0\u52a0\u66f2\u7ebf\u7684\u6c34\u5e73\u5e73\u79fb\u56e0\u5b50\u4e0eexp(Umax\/kBT)\u76f8\u8054\u7cfb\uff0c\u4f46\u6ca1\u6709\u4e25\u683c\u89e3\u91ca\uff0c\u53ea\u662f\u4e00\u53e5\u5e26\u8fc7[6]\u3002 \u5269\u4e0b\u7684\u95ee\u9898\uff0c\u5c31\u662fUmax\u4e0ecp\u7684\u5173\u7cfb\u3002 2 Laponite\u7684\u7c92\u5b50\u95f4\u4f5c\u7528\u52bf \u00a0 \u6309\u7167\u6211\u60f3\u8c61\uff0c\u6c42Umax\u7684\u65b9\u6cd5\u5c31\u662f\u53bb\u6c42U(h)\u51fd\u6570\u7684\u6781\u5927\u503c\uff0c\u5148\u6c42\u5bfc\u518d\u89e3\u65b9\u7a0b\u3002\uff08\u4e0d\u77e5\u9053\u6570\u5b66\u4e0a\u662f\u5426\u6709\u5176\u4ed6\u53d6\u5de7\u7684\u65b9\u6cd5\uff09\uff0c\u56e0\u6b64\u8981\u77e5\u9053U(h)\u7684\u5177\u4f53\u5f62\u5f0f\u3002 \u60ac\u6d6e\u5e26\u7535\u7c92\u5b50\u95f4\u7684\u4f5c\u7528\u52bf\u51fd\u6570U(h)\u662f\u6307\u628a\u4e24\u4e2a\u7c92\u5b50\u4ece\u8ddd\u79bb\u65e0\u9650\u8fdc\u79fb\u52a8\u81f3\u8ddd\u79bb\u4e3ah\u6240\u9700\u8981\u514b\u670d\u7684\u80fd\u91cf\u3002\u5b83\u53ef\u4ee5\u770b\u4f5c\u662f\u4e09\u4e2a\u90e8\u5206\u7684\u52a0\u548c\uff1a\u3002\u9759\u7535\u76f8\u4e92\u4f5c\u7528\uff08\u53cc\u7535\u5c42\uff09\u53ef\u91c7\u7528UDL(h) = CDLexp(-\u03bah)\uff0c\u5176\u4e2dCDL\u4e3a\u5e38\u6570\u3002\u8be5\u5f0f\u9002\u7528\u4e8e\u03ba > 3\u7684\u60c5\u51b5\u3002\u8303\u5fb7\u534e\u529b\u53ef\u91c7\u7528UA(h) = -Aa\/12h\uff0c\u5176\u4e2dA\u4e3aHamacker\u5e38\u6570\uff0ca\u4e3a\u6837\u54c1\u7684\u534a\u5f84\uff0c\u8be5\u5f0f\u9002\u7528\u4e8eh <<\u2026","rel":"","context":"In &quot;\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0&quot;","block_context":{"text":"\u4ee5tag\u5206\u7c7b\u7684\u6587\u7ae0","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/category\/tagged"},"img":{"alt_text":"clip_image002","src":"https:\/\/i0.wp.com\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2011\/03\/clip_image002_thumb.png?resize=350%2C200","width":350,"height":200},"classes":[]},{"id":6765,"url":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/6765","url_meta":{"origin":3451,"position":3},"title":"\u8270\u96be\u7684\u8bba\u6587\u53d1\u8868\u4e4b\u8def","author":"Andrew","date":"2015\u5e7412\u67084\u65e5","format":"aside","excerpt":"\u53c8\u4e00\u4efd\u5de5\u4f5c\u53d1\u8868\u4e86\u3002\u8fd9\u7bc7\u8bba\u6587\u5176\u5b9e\u662f\u63a5\u7740\u4e0a\u4e00\u7bc7\u5de5\u4f5c\u7684\u7ee7\u7eed\u3002\u6709\u4eba\u8bf4\uff0c\u81ea\u5df1\u7684\u8bba\u6587\uff0c\u53d1\u8868\u4e4b\u540e\u5c31\u4e0d\u60f3\u91cd\u770b\u4e86\u3002\u80fd\u591f\u53d1\u8868\u503c\u5f97\u81ea\u5df1\u80af\u5b9a\u7684\u8bba\u6587\uff0c\u90fd\u4e0d\u662f\u5bb9\u6613\u7684\u4e8b\u60c5\uff0c\u66f4\u4e0d\u7528\u8bf4\u8ba9\u522b\u4eba\u80af\u5b9a\u4e86\u3002\u54ea\u6015\u662f\u5982\u6b64\u65e0\u8da3\u7684\u5de5\u4f5c\uff0c\u6211\u7684publication rate\u4e5f\u7279\u522b\u4f4e\uff0c\u56e0\u4e3a\u6bcf\u4e00\u7bc7\u8bba\u6587\uff0c\u6211\u90fd\u5e0c\u671b\u63a8\u8fdb\u4e00\u6b65\uff0c\u800c\u6211\u57fa\u7840\u6bd4\u8f83\u8584\u5f31\uff0c\u8fd9\u63a8\u8fdb\u7684\u4e00\u6b65\u5f80\u5f80\u662f\u4ece\u8865\u4e60\u57fa\u672c\u77e5\u8bc6\u5f00\u59cb\uff1a\u5148\u5b66\u4e60\u57fa\u672c\u7406\u8bba\u7684\u76f8\u5173\u6559\u79d1\u4e66\u4e86\u89e3\u4e00\u822c\u7684\u60c5\u51b5\uff0c\u7136\u540e\u770b\u76f8\u5173\u7684\u6587\u732e\u4e86\u89e3\u8ddf\u6211\u7684\u95ee\u9898\u63a5\u8fd1\u7684\u60c5\u51b5\uff0c\u7136\u540e\u518d\u8003\u8651\u6211\u7684\u9700\u8981\u53d1\u8868\u7684\u95ee\u9898\u3002\u5982\u679c\u6211\u6bcf\u7bc7\u8bba\u6587\u90fd\u53ea\u6709\u5f53\u524d\u7684\u77e5\u8bc6\u7684\u7406\u89e3\uff0c\u90a3\u6211\u5c31\u4f1a\u66f4\u52a0\u5728\u6bd4\u8f83\u6e23\u7684\u6c34\u5e73\u4e0a\u505c\u6b65\u4e0d\u524d\u3002\u5728\u8fd9\u91cc\uff0c\u6211\u4e0d\u6015\u522b\u4eba\u7b11\u8bdd\u6211\u57fa\u7840\u6c34\u5e73\u66fe\u7ecf\u6709\u591a\u5dee\uff0c\u7b80\u5355\u8bb0\u5f55\u4e00\u4e0b\u6211\u600e\u4e48\u4ece\u83dc\u9e1f\u8d70\u8fc7\u6765\u7684\u3002\u5c06\u6765\u4e5f\u4f1a\u4e00\u76f4\u8d70\u4e0b\u53bb\u3002\u535a\u58eb\u751f\u671f\u95f4\u4ece\u96f6\u5f00\u59cb\u5b66\u4e60\u6d41\u53d8\u5b66\u4e4b\u540e\u8fdb\u884cLAOS\u7814\u7a76\u7684\u7ecf\u5386\uff0c\u5c31\u4e0d\u63d0\u4e86\u3002\u62112012\u5e74\u7684\u90a3\u7bc7J. Colloid Interf. Sci.\uff0c\u662f\u6211\u53c2\u52a0\u5de5\u4f5c\u540e\u53d1\u8868\u7684\u7b2c\u4e00\u7bc7\uff08\u5f53\u7136\u662f\u535a\u58eb\u671f\u95f4\u7684\u5de5\u4f5c\uff09\u3002\u5b9e\u9a8c\u4e0a\u53ea\u662f\u5b66\u4eba\u5bb6\u5df2\u7ecf\u505a\u51fa\u6765\u7684\u7ed3\u679c\uff0c\u591a\u52a0\u4e86\u4e00\u4e2a\u6761\u4ef6\uff0c\u91cd\u590d\u4e86\u4e00\u6b21\u73b0\u8c61\uff0c\u5373Laponite\u51dd\u80f6\u5316\u7684\u52a8\u529b\u5b66\u66f2\u7ebf\u6709\u53e0\u52a0\u6027\u3002\u4f46\u662f\u4e3a\u4e86\u7406\u89e3\u5b83\uff0c\u6211\u627e\u4e86\u4e00\u4e9b\u8bba\u6587\uff0c\u53d1\u73b0\u8fd9\u7684\u786e\u662f\u53ef\u4ee5\u7531\u6a21\u578b\u9884\u6d4b\u7684\uff0c\u5c31\u5728\u5b9e\u9a8c\u7ed3\u679c\u62a5\u9053\u4e4b\u540e\u7eed\u4e86\u4e00\u4e2a\u6a21\u578b\u8ba1\u7b97\u3002\u5176\u5b9e\u5982\u679c\u4ece\u66f4\u9ad8\u7684\u54c1\u4f4d\u6765\u770b\uff0c\u6240\u6709\u80fd\u7531\u7ecf\u5178\u6a21\u578b\u7b80\u5355\u9884\u6d4b\u51fa\u6765\u7684\u73b0\u8c61\uff0c\u4e0d\u7b97\u4ec0\u4e48\u65b0\u53d1\u73b0\u3002\u56e0\u4e3a\u6240\u8c13\u7ecf\u5178\u5c31\u662f\u6307\u65e9\u5df2\u88ab\u63a5\u53d7\u7684\u6a21\u578b\uff0c\u5b9e\u9a8c\u7b26\u5408\u7684\u4f8b\u5b50\u4e5f\u8bb8\u5df2\u7ecf\u6709\u6210\u5343\u4e0a\u4e07\u4e86\uff0c\u4f60\u518d\u4e3e\u4e00\u4e2a\u4e5f\u5c31\u53ea\u662f\u7b2c\u4e00\u4e07\u96f6\u4e00\u3002\u9664\u975e\u4f60\u662f\u63d0\u51fa\u5b83\u7684\u53cd\u4f8b\uff08\u4e5f\u5f88\u96be\uff09\u53ef\u80fd\u624d\u6bd4\u8f83\u5f15\u4eba\u5173\u6ce8\u3002\u4e0d\u53ef\u9006\u805a\u96c6\u7684\u6a21\u578b\u7684\u7814\u7a76\u65e9\u5c31\u63d0\u51fa\u4e86\u4e0d\u7ba1\u662f\u4e8c\u805a\u8fd8\u662fN\u805a\u90fd\u53ef\u7528\u4e00\u4e2a\u53cd\u5e94\u901f\u7387\u5e38\u6570\u63cf\u8ff0\u7684\u60c5\u51b5\uff0c\u76f8\u5f53\u4e8e\u9884\u6d4b\u4e86\u52a8\u529b\u5b66\u66f2\u7ebf\u6709\u53e0\u52a0\u6027\u3002\u6211\u7528\u4e0d\u53ef\u9006\u805a\u96c6\u7684\u6a21\u578b\u8ba1\u7b97\u7ed3\u679c\u4e0e\u5b9e\u9a8c\u7ed3\u679c\u6bd4\u8f83\u4e00\u4e0b\uff0c\u53ea\u80fd\u8bf4\u660eLaponite\u51dd\u80f6\u5316\u662f\u4e00\u4e2a\u4e0d\u53ef\u9006\u805a\u96c6\u6210cluster\u7f51\u7edc\u7684\u8fc7\u7a0b\u3002\u4f46\u5c31\u4e3a\u8fd9\u4ef6\u4e8b\uff0c\u6211\u91cd\u5934\u5b66\u4e60\u4e86\u5982\u4f55\u63cf\u8ff0\u7c92\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u52bf\u80fd\u51fd\u6570\uff0c\u5305\u62ecDLVO\u52bf\u7684van 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at 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Matter\u662f\u63a5\u7740\u4e0a\u8ff0\u7684\u5de5\u4f5c\u7684\u3002\u4f46\u4e5f\u662f\u5b66\u4e60\u53e6\u4e00\u4e2a\u7ec4\u505a\u51fa\u7684\u52a8\u6001\u7c98\u5f39\u8c31\u7684\u53e0\u52a0\u6027\u7ed3\u679c\uff0c\u6362\u6210\u4e86\u8ddf2012\u5e74\u4e00\u6837\u7684\u4f53\u7cfb\uff0c\u628a\u4eba\u5bb6\u770b\u5230\u8fc7\u7684\u89c4\u5f8b\u91cd\u590d\u4e86\u4e00\u904d\u3002\u4f46\u662f\uff0c\u8fd9\u7bc7\u8bba\u6587\u7a81\u7834\u4e86time-aging time superposition\u7684\u5df2\u77e5\u884c\u4e3a\uff0c\u5c55\u793a\u4e86time-X superposition\u884c\u4e3a\uff0cX\u4ee3\u8868\u80fd\u4fee\u9970\u7c92\u5b50\u76f8\u4e92\u4f5c\u7528\u52bf\u7684\u5404\u7c7b\u6761\u4ef6\u3002\u4e00\u5f00\u59cb\u4e0d\u77e5\u5929\u9ad8\u5730\u539a\uff0c\u8bd5\u6295PRL\uff0c\u7ed3\u679c\u7531\u4e8e\u9009\u53d6\u7684Laponite\u6d53\u5ea6\u4f53\u7cfb\u5728\u5df2\u62a5\u9053\u7684\u76f8\u56fe\u4e2d\u4f4d\u7f6e\u5c34\u5c2c\uff0c\u96be\u4ee5\u8bf4\u660e\u662fgel\u8fd8\u662fglass\u3002\u8fd9\u4e2a\u95ee\u9898\u73b0\u5728\u6211\u5176\u5b9e\u6709\u6bd4\u8f83\u81ea\u4fe1\u7684\u770b\u6cd5\uff0c\u540e\u9762\u6709\u65f6\u95f4\u4f1a\u63d0\u5230\u3002\u4f46\u5f53\u65f6\u6211\u81ea\u5df1\u5bf9\u5df2\u62a5\u9053\u7684Laponite\u76f8\u56fe\u4e5f\u7406\u89e3\u4e0d\u6df1\uff0c\u65e2\u65e0\u6cd5\u6279\u5224\u5b83\u4eec\uff0c\u53c8\u65e0\u6cd5\u89e3\u91ca\u81ea\u5df1\u7684\u4f53\u7cfb\uff0c\u7ed3\u679c\u5c31\u5728\u8fd9\u4e2a\u95ee\u9898\u4e0a\u5361\u4f4f\uff0cPRL\u6295\u4e0d\u8fdb\u53bb\uff0c\u5c31\u6539\u6295\u4e86Soft Matter\u63a5\u6536\u4e86\u3002\u5c3d\u7ba1\u63a5\u6536\u4e86\uff0c\u81f3\u4eca\u672a\u6709\u4ed6\u4eba\u5f15\u7528\u3002\u5f53\u65f6PRL \u5ba1\u7a3f\u610f\u89c1\u8fd8\u63d0\u51fa\u6211\u4eec\u5e94\u8be5\u63d0\u51fa\u4e00\u4e2a\u6a21\u578b\u53bb\u63cf\u8ff0\u8fd9\u4e2a\u73b0\u8c61\uff0c\u4e0d\u80fd\u53ea\u662f\u5b9e\u9a8c\u3002\u4e8e\u662f\u6211\u53c8\u5728\u56de\u590d\u5ba1\u7a3f\u610f\u89c1\u7684\u9650\u671f\u5185\u67e5\u9605\u4e86\u5927\u91cf\u8bba\u6587\u3002\u73b0\u5728\u77e5\u9053\uff0c\u8981\u4ece\u80f6\u4f53\u76f8\u4e92\u4f5c\u7528\u52bf\u51fa\u53d1\uff0c\u9884\u6d4b\u5176\u51dd\u80f6\u6216\u73bb\u7483\u6001\u7684\u7ebf\u6027\u7c98\u5f39\u6027\u7684\u7406\u8bba\uff0c\u4e5f\u5c31\u53ea\u6709\u57fa\u4e8eschematic MCT\u7684F12\u6a21\u578b\u3002\u8def\u5b50\u4e0d\u662f\u6ca1\u6709\u7684\uff0c\u4ece\u76f8\u4e92\u4f5c\u7528\u52bf\u80fd\u51fa\u53d1\uff0c\u91c7\u7528\u4e00\u4e2a\u5e38\u7528\u7684\u6bd4\u5982\u8bf4Percus\u2013Yevick\uff0c\u5f97\u5230\u76f8\u5e94\u7684\u9759\u6001\u7ed3\u6784\u56e0\u5b50\uff0c\u7136\u540e\u4ee3\u5165MCT\u7684kernal\u5f0f\u4e2d\u8ba1\u7b97memory function\uff1b\u7136\u540e\u4ee3\u5165\u5c0f\u5e45\u6b63\u5f26\u632f\u8361\u5e94\u53d8\uff0c\u8ba1\u7b97\u77ac\u6001\u5e94\u529b\u54cd\u5e94\uff0c\u5e76\u5f97\u5230\u76f8\u5e94\u7684\u590d\u6570\u6a21\u91cf\u3002\u8fd9\u4e00\u5927\u901a\u8ba1\u7b97\uff0c\u6211\u5f53\u65f6\u770b\u50bb\u773c\u4e86\uff0c\u6240\u4ee5\u653e\u5f03\u4e86\u3002\u73b0\u5728\uff0c\u867d\u7136\u5927\u81f4\u89c9\u5f97\u90fd\u61c2\u5f04\uff0c\u4f46\u6ca1\u6709\u7cbe\u529b\u5199\u8fd9\u4e2a\u7a0b\u5e8f\u3002\u7ecf\u8fc7\u5bf9Laponite\u4f53\u7cfb\u7684\u4e00\u6bb5\u65f6\u95f4\u63a5\u89e6\uff0c\u6211\u8d8a\u6765\u8d8a\u5f3a\u70c8\u5730\u89c9\u5f97\uff0c\u90a3\u4e9b\u5728\u5df2\u62a5\u9053\u76f8\u56fe\u4e2d\u6807\u660e\u4e3a\u201c\u73bb\u7483\u201d\u7684\u914d\u6bd4\u4f53\u7cfb\u5176\u5b9e\u5e94\u8be5\u662f\u51dd\u80f6\u3002\u4e3a\u6b64\uff0c\u6211\u5f00\u59cb\u9010\u7bc7\u67e5\u9605\u5173\u4e8eLaponite\u76f8\u56fe\u7684\u8bba\u6587\u3002\u4f46\u8fd9\u6d89\u53ca\u5230\u201c\u4f55\u4e3a\u80f6\u4f53\u73bb\u7483\/\u51dd\u80f6\u201d\u7684\u95ee\u9898\uff0c\u6211\u53c8\u6269\u5927\u5230\u4e86\u6240\u6709\u786c\u7403\u4f53\u7cfb\u7684\u5e73\u8861\u6001\u76f8\u8f6c\u53d8\u7814\u7a76\u3002\u8fd9\u4e00\u4e0b\u5b50\u6d89\u53ca\u9762\u5c31\u5927\u4e86\uff0c\u800c\u4e14\u6211\u4e00\u4e0b\u5b50\u610f\u8bc6\u4e0d\u5230\uff0c\u6211\u9996\u5148\u5e94\u8be5\u6709\u5e73\u8861\u6001\u7edf\u8ba1\u7269\u7406\u7684\u57fa\u7840\u4ee5\u53ca\u8ba1\u7b97\u673a\u6a21\u62df\u65b9\u6cd5\u7684\u57fa\u7840\uff0c\u4e00\u76f4\u901a\u8fc7\u6587\u732e\u603b\u7ed3\u77e5\u8bc6\uff0c\u8fd9\u6bb5\u65f6\u95f4\u5927\u6982\u662f\u4ece2013\u5e74\u52302014\u5e74\u8fd9\u4e00\u5e74\u7684\u65f6\u95f4\u3002\u6211\u5927\u6982\u4ece\u6982\u5ff5\u4e0a\u641e\u6e05\uff0c\u4e5f\u8c03\u67e5\u6e05\u695a\u628aLaponite\u4f53\u7cfb\u770b\u4f5c\u73bb\u7483\u7684\u89c2\u70b9\u53f2\u53ca\u8bc1\u636e\uff0c\u8ba4\u4e3a\u54ea\u6015\u7efc\u8ff0\u90fd\u53d1\u8868\u4e86\uff0c\u4f46\u8fd9\u4e2a\u89c2\u70b9\u662f\u7f3a\u4e4f\u652f\u6301\u7684\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u8ddf\u6211\u505a\u5b9e\u9a8c\u7684\u5e08\u5f1f\u53c8\u91cd\u590d\u6211\u5df2\u53d1\u8868\u5de5\u4f5c\u7684\u5957\u8def\uff0c\u8fd9\u6b21\u4ed6\u53d8\u5316\u4e86\u4e0d\u540c\u7684\u6e29\u5ea6\u505a\u52a8\u529b\u5b66\u66f2\u7ebf\uff0c\u7136\u540e\u53d1\u73b0\u53ef\u53e0\u52a0\u6027\u3002\u672c\u6765\u6211\u63d0\u4e0d\u8d77\u7cbe\u795e\u53bb\u6574\u7406\u8fd9\u79cd\u91cd\u590d\u7684\u5de5\u4f5c\uff0c\u4f46\u662f\u6bd5\u7adf\u5de5\u4f5c\u4e86\uff0c\u6ca1\u8d28\u91cf\u6709\u6570\u91cf\u4e5f\u597d\u554a\u3002\u8fd9\u4e2a\u5e08\u5f1f\u7684\u5b9e\u9a8c\u7ed3\u679c\u6709\u4e00\u4e2a\u5c0f\u5f02\u5e38\uff0c\u5c31\u662fLaponite\u51dd\u80f6\u5316\u5feb\u6162\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u4e0d\u662f\u5355\u8c03\u7684\u3002\u4e00\u5f00\u59cb\u6211\u89c9\u5f97\u8fd9\u4e5f\u5f88\u96be\u8bf4\u51fa\u4e2a\u4ec0\u4e48\uff0c\u800c\u4e14\u5047\u5982\u91c7\u7528\u4ee5\u524d\u7528\u8fc7\u7684\u4e0d\u53ef\u9006\u805a\u96c6\u6a21\u578b\u518d\u6765\u8ba1\u7b97\u4e00\u756a\uff0c\u4e5f\u65e0\u8bba\u5982\u4f55\u4e0d\u4f1a\u7b97\u51fa\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u3002\u4e8e\u662f\u60f3\u4e5f\u8bb8\u4e0d\u540c\u6e29\u5ea6\u4e0b\u4e5f\u8bb8\u7c92\u5b50\u8868\u9762\u7279\u6027\u4f1a\u4e0d\u540c\uff0c\u662f\u4ece\u76f8\u4e92\u4f5c\u7528\u52bf\u5c42\u9762\u5f71\u54cd\u5bfc\u81f4\u7684\u7ed3\u679c\uff0c\u4e8e\u662f\u5c31\u8ba9\u5e08\u5f1f\u8865\u6d4b\u4e86\u4e00\u4e0b\u4e0d\u540c\u7535\u5bfc\u7387\u548cpH\u503c\uff0c\u76f4\u63a5\u8ba1\u7b97\u8868\u9762\u7535\u8377\u5bc6\u5ea6\uff08\u800c\u4e0d\u662f\u7b80\u5355\u7528\u4e00\u4e2a\u6587\u732e\u62a5\u9053\u7684zeta\u7535\u52bf\u6765\u4ee3\u5165\u8ba1\u7b97\uff09\u3002\u867d\u7136\u4ecd\u7136\u6ca1\u53d1\u73b0\u4ec0\u4e48\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\uff0c\u4f46\u8fd8\u662f\u60f3\u786c\u7740\u5934\u76ae\u5f80\u4e0b\u7b97\uff0c\u9047\u5230\u4e86\u4e00\u4e2a\u65b0\u95ee\u9898\uff0c\u5c31\u662f\u8fd9\u6b21\u5e08\u5f1f\u7528\u7684\u662f\u65e0\u76d0\u7c92\u5b50\u60ac\u6d6e\u6db2\uff0c\u6db2\u4f53\u4e2d\u7684\u79bb\u5b50\u5168\u662f\u7c92\u5b50\u7535\u79bb\u7684\u53cd\u79bb\u5b50\u3002\u6211\u60f3\u4e86\u534a\u5929\u4e0d\u77e5\u9053\u600e\u4e48\u8003\u8651\uff0c\u7ffb\u9605H. Ohshima\u7684Theory of Colloid and Interfacial Electric Phenomena\u4e0d\u6b62\u4e00\u6b21\uff0c\u4e5f\u627e\u4e0d\u5230\u4e66\u4e2d\u54ea\u79cd\u60c5\u51b5\u80fd\u591f\u4e0e\u6211\u7684\u5bf9\u5e94\u3002\u4e8e\u662f\u76f4\u63a5\u5199\u4fe1\u7ed9H. Ohshima\u8bf7\u6559\uff0c\u624d\u4e86\u89e3\u5230\u6211\u7684\u60c5\u51b5\u5c5e\u4e8esalt-free system\u6216\u8005counterions-only system\u3002\u4ed6\u8fd8\u4ecb\u7ecd\u6211\u770b\u4e86\u76f8\u5173\u7684\u8bba\u6587\u3002\u5176\u5b9e\uff0c\u8fd9\u7bc7\u6587\u7ae0\u5230\u6211\u77e5\u9053\u6b63\u786e\u5bf9\u5e94\u7684\u7269\u7406\u4f53\u7cfb\u65f6\uff0c\u5df2\u7ecf\u62d6\u4e86\u5f88\u4e45\uff0c\u6211\u8001\u677f\u603b\u662f\u89c9\u5f97\u4e00\u7bc7\u6587\u7ae0\u4e0d\u503c\u5f97\u5f04\u8fd9\u4e48\u4e45\u3002\u4f46\u4ed6\u4e0d\u77e5\u9053\uff0c\u4e4b\u6240\u4ee5\u4e45\uff0c\u662f\u56e0\u4e3a\u6211\u6c34\u5e73\u5dee\u3001\u5916\u884c\u3001\u8d70\u5f2f\u8def\u3002\u4ed6\u662f\u7ecf\u8fc7\u826f\u597d\u7684\u7814\u7a76\u751f\u8bad\u7ec3\u7684\u7814\u7a76\u8005\uff0c\u6709\u4ed6\u64c5\u957f\u7684\u4e13\u4e1a\uff0c\u5728\u4ed6\u64c5\u957f\u7684\u9886\u57df\u5185\uff0c\u80fd\u591f\u4e0d\u8d70\u4f4e\u7ea7\u7684\u5f2f\u8def\u3002\u800c\u6211\u6ca1\u6709\u4ec0\u4e48\u505a\u7269\u7406\u5e94\u6709\u7684\u7406\u8bba\u57fa\u7840\uff0c\u5c31\u4f1a\u8d70\u5f2f\u8def\u3002\u6240\u4ee5\uff0c\u5b66\u5230\u4e86\u6b63\u786e\u7684\u77e5\u8bc6\u4e4b\u540e\uff0c\u7518\u613f\u518d\u82b1\u4e00\u500d\u7684\u65f6\u95f4\u91cd\u65b0\u6309\u7167\u6b63\u786e\u7684\u6a21\u578b\u53bb\u8ba1\u7b97\u3002\u7ed3\u679c\u53d1\u73b0\uff0c\u901a\u8fc7\u5b9e\u9a8c\u6d4b\u5f97\u7684\u7c92\u5b50\u8868\u9762\u7279\u6027\uff0c\u518d\u6b63\u786e\u8003\u8651\u53cd\u79bb\u5b50\u51dd\u805a\uff0c\u5c31\u6070\u597d\u80fd\u9884\u6d4b\u51fa\u975e\u5355\u8c03\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u3002\u8fd9\u662f\u8ba9\u6211\u5f88\u5174\u594b\u7684\u7ed3\u679c\u3002\u53ef\u662f\u4e00\u5f00\u59cb\u6295\u8fc7Langmuir\u548cSoft Matter\u90fd\u88ab\u79d2\u62d2\u4e86\uff0c\u5f88\u53d7\u632b\u3002\u540e\u6765\u8fd8\u662f\u6295J. Colloid Interf. Sci.\u53cd\u800c\u83b7\u5f97\u4e86\u597d\u8bc4\u3002\u8fd9\u6bb5\u8fc7\u7a0b\u8ba9\u6211\u76f8\u4fe1\uff0c\u8bba\u6587\u5c31\u5e94\u8be5\u6295\u5230\u9886\u57df\u76f8\u7b26\u7684\u671f\u520a\uff0c\u4e00\u70b9\u4e5f\u4e0d\u8981\u8ffd\u6c42\u5f71\u54cd\u56e0\u5b50\u548cJCR\u5206\u533a\u3002\u56e0\u4e3a\u53ea\u6709\u5c3d\u53ef\u80fd\u5bf9\u53e3\u7684\u540c\u884c\u624d\u6709\u5f97\u61c2\u4f60\u7684\u5de5\u4f5c\uff0c\u7406\u89e3\u4f60\u5de5\u4f5c\u7684\u91cd\u8981\u6027\uff0c\u7ed9\u4e88\u6709\u5efa\u8bbe\u6027\u7684\u610f\u89c1\u5e76\u5efa\u8bae\u53d1\u8868\u3002\u521a\u521a\u53d1\u8868\u7684\u5de5\u4f5c\uff0c\u5219\u662f\u53c8\u5b66\u77402013\u5e74\u7684\u90a3\u7bc7Soft Matter\u90a3\u6837\uff0c\u628a\u521a\u505a\u8fc7\u52a8\u529b\u5b66\u66f2\u7ebf\u53e0\u52a0\u7684\u4f53\u7cfb\uff0c\u518d\u505a\u4e00\u6b21\u7c98\u5f39\u8c31\u53e0\u52a0\u3002\u8fd9\u5728\u5b9e\u9a8c\u4e0a\u5b9e\u5728\u662f\u7eaf\u7cb9\u7684\u91cd\u590d\uff0c\u800c\u4e14\u8ddf2013\u5e74\u7684\u60c5\u51b5\u4e00\u6837\uff0c\u6211\u4ecd\u7136\u65e0\u6cd5\u5229\u7528schematic MCT\u6a21\u578b\u5bf9\u7c98\u5f39\u8c31\u8fdb\u884c\u7406\u8bba\u8ba1\u7b97\u6bd4\u8f83\uff0c\u6ca1\u529e\u6cd5\u7a81\u7834\u3002\u4f46\u662f\uff0c\u8fd9\u65f6\u6211\u6070\u597d\u770b\u5230\u4e86H. Winter\u7684\u4e00\u7bc7\u8bba\u6587\uff0c\u63d0\u9192\u6211\u867d\u7136\u4e0d\u80fd\u4ece\u7b2c\u4e00\u6027\u539f\u7406\u6a21\u578b\u53bb\u8ba1\u7b97\u7c98\u5f39\u8c31\uff0c\u81f3\u5c11\u53ef\u4ee5\u7528\u552f\u8c61\u6a21\u578b\u62df\u5408\u51fa\u4e00\u4e2a\u8c31\u6765\u7814\u7a76\u3002\u4e8e\u662f\u5c31\u5bf9\u7ed3\u679c\u8fdb\u884c\u4e86\u8bd5\u9a8c\uff0c\u53d1\u73b0\u5728\u6211\u7684\u7ed3\u679c\u4e2d\u5c31\u6709\u6240\u8c13\u7684\u51dd\u80f6\u5230\u73bb\u7483\u7684rheological inversion\u3002\u8fd9\u4e5f\u662f\u4ee4\u6211\u89c9\u5f97\u6709\u8da3\u7684\u7ed3\u679c\uff0c\u800c\u4e14\u7ec8\u4e8e\u4f7f\u8fd9\u90e8\u5206\u5de5\u4f5c\u4e0d\u518d\u6d41\u4e8e\u7b80\u5355\u91cd\u590d\u5df2\u6709\u5de5\u4f5c\u4e86\u3002\u7531\u4e8e\u662f\u7d27\u63a5\u7740\u505a\u7684\uff0c\u4e8e\u662f\u4e5f\u60f3\u518d\u6295\u540c\u4e00\u4e2a\u671f\u520a\uff0c\u4ee5\u4e3a\u5c31\u4f1a\u987a\u5229\u53d7\u5ba1\uff0c\u7ed3\u679c\u88ab\u79d2\u62d2\uff0c\u5341\u5206\u53d7\u632b\uff0c\u6295Colloids Surf. A\u3002\u56e0\u4e3a\u6211\u4e4b\u524d\u6709\u53e6\u5916\u4e00\u4e9b\u5b9e\u9a8c\u5de5\u4f5c\u51e0\u6b21\u6295\u4e0d\u51fa\u53bb\u6700\u540e\u90fd\u6295\u5230Colloids Surf. A\u89e3\u51b3\u7684\u3002\u8fd9\u6b21\u53ea\u597d\u53c8\u5982\u6cd5\u6ce1\u5236\u3002\u8fd8\u5728\u9001\u5ba1\u7684\u8fc7\u7a0b\u4e2d\uff0c\u6211\u53c2\u52a0\u4e86\u7f8e\u56fd\u6d41\u53d8\u5b66\u4f1a\uff0c\u5728Baltimore\u89c1\u5230\u4e86H. 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