{"id":1610,"date":"2010-10-10T18:27:25","date_gmt":"2010-10-10T10:27:25","guid":{"rendered":"http:\/\/www.andrewsun.net\/xiangge\/?p=1610"},"modified":"2011-03-20T16:17:24","modified_gmt":"2011-03-20T08:17:24","slug":"nob","status":"publish","type":"post","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/1610","title":{"rendered":"2010\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956"},"content":{"rendered":"<div class=\"kcite-section\" kcite-section-id=\"1610\">\n<blockquote>\n<p>\u300a\u65b0\u77e5\u5ba2\u300b\u7ea6\u7a3f\uff0c\u52ff\u8f6c\uff01<\/p>\n<\/blockquote>\n<p>\u4eca\u5e74\u7684\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u9881\u7ed9\u4e86\u4e09\u4f4d\u4e0e\u94af\u50ac\u5316\u53cd\u5e94\u76f8\u5173\u7684\u4e09\u4f4d\u5316\u5b66\u5bb6\uff1a\u94c3\u6728\u7ae0\uff08Akira Suzuki\uff09\u3001\u6839\u5cb8\u82f1\u4e00\uff08Ei-ichi Negishi\uff09\u548c\u7406\u67e5\u00b7\u8d6b\u514b\uff08Richard F. Heck\uff09\u3002<\/p>\n<h3>\u6709\u673a\u5408\u6210\u6709\u591a\u96be\uff1f<\/h3>\n<p><div style=\"width: 545px\" class=\"wp-caption alignnone\"><a href=\"http:\/\/www.sciencemuseum.org.uk\/images\/object_images\/535x535\/10268521.jpg\"><img loading=\"lazy\" decoding=\"async\" alt=\"1860\u5e74\u4ee3\u7684\u4e00\u526f\u7403\u68cd\u6a21\u578b\" src=\"http:\/\/www.sciencemuseum.org.uk\/images\/object_images\/535x535\/10268521.jpg\" title=\"1860\u5e74\u4ee3\u7684\u4e00\u526f\u7403\u68cd\u6a21\u578b\" width=\"535\" height=\"440\" \/><\/a><p class=\"wp-caption-text\">1860\u5e74\u4ee3\u7684\u4e00\u526f\u7403\u68cd\u6a21\u578b<\/p><\/div><br \/>\n<div style=\"width: 376px\" class=\"wp-caption alignnone\"><a href=\"http:\/\/sbillinghurst.files.wordpress.com\/2009\/09\/reflux.gif?w=366&#038;h=735\"><img loading=\"lazy\" decoding=\"async\" alt=\"\u53cd\u5e94\u88c5\u7f6e\" src=\"http:\/\/sbillinghurst.files.wordpress.com\/2009\/09\/reflux.gif?w=366&#038;h=735\" title=\"\u53cd\u5e94\u88c5\u7f6e\" width=\"366\" height=\"735\" \/><\/a><p class=\"wp-caption-text\">\u8001\u5f0f\u53cd\u5e94\u88c5\u7f6e\u4e00\u4f8b<\/p><\/div><\/p>\n<p>\u63d0\u8d77\u5316\u5b66\u4e5f\u8bb8\u6709\u4e9b\u4eba\u4f1a\u60f3\u5230\u65b0\u534e\u5b57\u5178\u540e\u9762\u7684\u5143\u7d20\u5468\u671f\u8868\uff0c\u6709\u4e9b\u4eba\u4f1a\u60f3\u5230\u4e2d\u5b66\u8bfe\u5802\u4e0a\u7684\u7403\u68cd\u6a21\u578b\u3002\u5316\u5b66\u7814\u7a76\u5c31\u597d\u50cf\u73a9\u79ef\u6728\uff0c\u4ece\u4e94\u989c\u516d\u8272\u7684\u5143\u7d20\u5468\u671f\u8868\u91cc\u6311\u51fa\u5408\u9002\u7684\u7403\uff0c\u7136\u540e\u68cd\u5b50\u642d\u51fa\u5404\u79cd\u5404\u6837\u7684\u5206\u5b50\u6765\u3002\u7403\u548c\u68cd\u6bd5\u7adf\u53ea\u662f\u6a21\u578b\uff0c\u771f\u6b63\u7684\u5316\u5b66\u53cd\u5e94\u5f80\u5f80\u662f\u6253\u788e\u4e00\u4e2a\u73b0\u6210\u7684\u5206\u5b50\uff0c\u7136\u540e\u53d8\u6362\u7ed3\u5408\u51fa\u65b0\u7684\u5206\u5b50\uff0c\u9700\u8981\u5728\u8bd5\u7ba1\u548c\u70e7\u676f\u4e2d\u5b9e\u73b0\u3002\u5206\u5b50\u662f\u8089\u773c\u770b\u4e0d\u89c1\u7684\u4e1c\u897f\uff0c\u4e00\u6ef4\u6c34\u4e2d\u7684\u6c34\u5206\u5b50\u6570\u91cf\uff0c\u8981\u57281\u540e\u9762\u52a023\u4e2a0\u3002\u6240\u4ee5\u5316\u5b66\u5b9e\u9a8c\u9488\u5bf9\u7684\u603b\u662f\u6781\u5176\u5927\u91cf\u7684\u5206\u5b50\u3002\u6307\u6325\u4e24\u4e09\u4e2a\u4eba\u540c\u65f6\u5411\u53f3\u8f6c\u4e5f\u8bb8\u90fd\u4e0d\u7528\u8bad\u7ec3\uff0c\u4f46\u662f\u6307\u6325\u4e00\u4e2a\u8425\u7684\u4eba\u540c\u65f6\u5411\u53f3\u8f6c\u5c31\u975e\u5e38\u56f0\u96be\u3002\u5c31\u7b97\u518d\u8bad\u7ec3\u6709\u7d20\u7684\u961f\u4f0d\uff0c\u4eba\u591a\u8d77\u6765\u603b\u6709\u4e2a\u8c01\u5148\u8c01\u540e\uff0c\u4e0d\u53ef\u80fd\u4e25\u683c\u540c\u65f6\u3002\u5316\u5b66\u53cd\u5e94\u4e5f\u662f\u8fd9\u6837\uff0c\u4e00\u4e07\u4e2a\u5206\u5b50\u4e2d\uff0c\u8c01\u80fd\u4fdd\u8bc1\u6ca1\u6709\u4e00\u4e24\u4e2a\u4f8b\u5916\u7684\uff1f\u4f55\u51b5\u662f1\u52a0\u4e0a23\u4e2a0\u8fd9\u4e48\u591a\u4e2a\u5206\u5b50\uff0c\u80af\u5b9a\u6709\u7684\u8f6c\u5f97\u5feb\uff0c\u6709\u7684\u8f6c\u5f97\u6162\uff0c\u6709\u7684\u8fd8\u8f6c\u9519\u65b9\u5411\u3002\u7cdf\u7cd5\u7684\u662f\uff0c\u4f60\u8981\u662f\u4e0d\u558a\u505c\uff0c\u8f6c\u7684\u5feb\u7684\u5c31\u7ee7\u7eed\u8f6c\uff0c\u8f6c\u8fc7\u5934\u4e86\uff1b\u4f60\u8981\u662f\u558a\u505c\uff0c\u53c8\u4f1a\u597d\u591a\u8f6c\u7684\u6162\u7684\u6ca1\u8f6c\u5230\u4f4d\u3002\u56e0\u6b64\uff0c\u51e1\u662f\u5316\u5b66\u53cd\u5e94\uff0c\u603b\u4f1a\u6216\u591a\u6216\u5c11\u4f34\u968f\u6709\u526f\u4ea7\u7269\u3002<\/p>\n<p>\u65e0\u673a\u7269\u5206\u5b50\u5c31\u597d\u50cf\u8bad\u7ec3\u6709\u7d20\u7684\u961f\u4f0d\uff0c\u7edd\u5927\u591a\u6570\u65e0\u673a\u5316\u5b66\u53cd\u5e94\u7684\u4ea7\u7387\u90fd\u662f\u8d85\u8fc790%\u7684\uff1b\u4f46\u662f\u6709\u673a\u7269\u2014\u2014\u5373\u4ee5\u78b3\u57fa\u5316\u5408\u7269\u2014\u2014\u5c31\u597d\u50cf\u4e00\u7fa4\u4e0d\u542c\u8bdd\u7684\u5b69\u5b50\u3002\u78b3-\u78b3\u952e\u7684\u5f62\u6210\u5c24\u5176\u56f0\u96be\uff0c\u800c\u4e00\u65e6\u5f62\u6210\u53c8\u6bd4\u8f83\u7a33\u5b9a\u3002\u505a\u4e00\u4e2a\u6709\u673a\u5316\u5b66\u53cd\u5e94\uff0c\u5c31\u597d\u50cf\u4f60\u660e\u660e\u53eb\u5411\u5de6\u8f6c\uff0c\u6700\u7ec8\u6b63\u786e\u8f6c\u4e86\u7684\u53ea\u6709\u4e09\u56db\u5341\uff08\u4ea7\u7387\u4f4e\uff09\u3002\u5bf9\u4e8e\u5927\u591a\u6570\u6709\u673a\u5408\u6210\u4efb\u52a1\uff0c\u9700\u8981\u8fdb\u884c\u7684\u5316\u5b66\u53cd\u5e94\u8fd8\u4e0d\u6b62\u4e00\u6b65\u3002\u7b49\u4f60\u558a\u4e0a\u5341\u51e0\u4e2a\u53e3\u4ee4\u4e4b\u540e\uff0c\u4e00\u767e\u4e2a\u5206\u5b50\u4e5f\u8bb8\u53ea\u6709\u4e00\u4e24\u4e2a\u987a\u5229\u5230\u4f4d\u4e86\uff0c\u800c\u4e14\u5b83\u4eec\u8fd8\u6df7\u5728\u4e00\u5927\u5806\u4e71\u4e03\u516b\u7cdf\u7684\u9519\u8bef\u5206\u5b50\u4e2d\uff0c\u5f97\u4f60\u53bb\u628a\u5b83\u4eec\u7ea0\u51fa\u6765\uff08\u5206\u79bb\u56f0\u96be\uff09\u3002\u56e0\u6b64\uff0c\u5c3d\u7ba1\u5728\u7eb8\u4e0a\u53ef\u4ee5\u968f\u4fbf\u753b\u51e0\u4e2a\u78b3\u539f\u5b50\uff0c\u7528\u77ed\u6a2a\u7ebf\u8fde\u4e00\u4e0b\uff0c\u5c31\u80fd\u8bbe\u8ba1\u51fa\u4e00\u4e2a\u6709\u673a\u7269\u6765\uff1b\u4f46\u662f\u5728\u70e7\u676f\u4e2d\u6307\u6325\u4e0a\u4ebf\u4e2a\u5206\u5b50\u5b9e\u73b0\u8fd9\u6837\u7684\u7269\u8d28\u6765\u5c31\u5f88\u5934\u75db\u3002<\/p>\n<p>\u73b0\u5728\uff0c\u5728\u4e00\u4e2a\u6700\u666e\u901a\u7684\u73b0\u4ee3\u4eba\u89e6\u624b\u53ef\u53ca\u7684\u751f\u6d3b\u5468\u56f4\uff0c\u5168\u90fd\u662f\u6709\u673a\u5408\u6210\u529f\u4e1a\u7684\u4ea7\u7269\u3002\u5bb6\u91cc\u6240\u6709\u7684\u5851\u6599\u548c\u6a61\u80f6\u5236\u54c1\uff0c\u8bb8\u591a\u6297\u751f\u7d20\u548c\u9547\u75db\u7c7b\u836f\u7269\u3001\u6d17\u6da4\u5316\u5986\u7528\u54c1\u751a\u81f3\u4e8e\u90e8\u5206\u98df\u54c1\uff0c\u90fd\u662f\u4eba\u5de5\u5408\u6210\u7684\u6709\u673a\u7269\u3002\u6240\u6709\u8fd9\u4e9b\u7ec4\u6210\u6211\u4eec\u73b0\u4ee3\u751f\u6d3b\u7684\u7269\u8d28\u7684\u53d1\u660e\u548c\u751f\u4ea7\u5747\u9700\u8981\u9ad8\u6548\u3001\u51c6\u786e\u5730\u78b3-\u78b3\u952e\u3002\u62dc\u94af\u50ac\u5316\u53cd\u5e94\u6240\u8d50\uff0c\u9664\u8349\u5242\u6c1f\u78fa\u9686\uff08Prosulfuron\uff09\u3001\u9547\u75db\u836f\u8418\u666e\u751f\uff08Naproxen)\u3001\u5e73\u5598\u836f\u987a\u800c\u5b81\uff08Singulair\uff09\u7b49\u836f\u7269\u5e74\u4ea7\u91cf\u5df2\u8d85\u8fc71\u5428\uff0c\u6781\u96be\u5206\u79bb\u7684\u6297\u80bf\u7624\u836f\u7269Discodermolide\u7684\u4eba\u5de5\u5408\u6210\u7814\u7a76\uff0c\u4e5f\u6709\u94af\u50ac\u5316\u5076\u5408\u7684\u529f\u52b3\uff08\u56fe\uff09\u3002<\/p>\n<div id=\"attachment_1626\" style=\"width: 310px\" class=\"wp-caption alignnone\"><a href=\"http:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/Discodermolide_Structure.png\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-1626\" data-attachment-id=\"1626\" data-permalink=\"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/1610\/discodermolide_structure\" data-orig-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/Discodermolide_Structure.png\" data-orig-size=\"1182,497\" data-comments-opened=\"1\" data-image-meta=\"{&quot;aperture&quot;:&quot;0&quot;,&quot;credit&quot;:&quot;&quot;,&quot;camera&quot;:&quot;&quot;,&quot;caption&quot;:&quot;&quot;,&quot;created_timestamp&quot;:&quot;0&quot;,&quot;copyright&quot;:&quot;&quot;,&quot;focal_length&quot;:&quot;0&quot;,&quot;iso&quot;:&quot;0&quot;,&quot;shutter_speed&quot;:&quot;0&quot;,&quot;title&quot;:&quot;&quot;}\" data-image-title=\"Discodermolide_Structure\" data-image-description=\"\" data-image-caption=\"&lt;p&gt;\u6297\u80bf\u5ec7\u836fDiscodermolide\u4e2d\u7684\u8bfa\u8d1d\u5c14\u5956&lt;\/p&gt;\n\" data-large-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/Discodermolide_Structure-1024x430.png\" src=\"http:\/\/www.andrewsun.net\/xiangge\/wp-content\/uploads\/2010\/10\/Discodermolide_Structure-300x126.png\" alt=\"\u6297\u80bf\u5ec7\u836fDiscodermolide\" title=\"Discodermolide_Structure\" width=\"300\" height=\"126\" class=\"size-medium wp-image-1626\" srcset=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/Discodermolide_Structure-300x126.png 300w, https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/Discodermolide_Structure-1024x430.png 1024w, https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/Discodermolide_Structure.png 1182w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><p id=\"caption-attachment-1626\" class=\"wp-caption-text\">\u6297\u80bf\u5ec7\u836fDiscodermolide\u4e2d\u7684\u8bfa\u8d1d\u5c14\u5956<\/p><\/div>\n<p>\u56e0\u6b64\uff0c\u5f80\u5f80\u7eb8\u4e0a\u90a3\u4e00\u6761\u8fde\u63a5\u4e24\u4e2a\u78b3\u7b26\u53f7\u7684\u5c0f\u6a2a\u7ebf\uff0c\u4e00\u65e6\u5b9e\u73b0\u4e86\u5c31\u4f1a\u5f15\u8d77\u4ea7\u4e1a\u7684\u9769\u547d\u3002\u5728\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u7684\u5386\u53f2\u4e0a\uff0c\u5df2\u7ecf\u6709\u591a\u6b21\u5956\u9879\u9881\u7ed9\u4e86\u5173\u4e8e\u5f62\u6210\u78b3-\u78b3\u952e\u7684\u7814\u7a76\u8005\u3002\u5176\u4e2d\uff0c\u6240\u6709\u6709\u673a\u5408\u6210\u5b9e\u9a8c\u5458\u7684\u6700\u7231\u2014\u2014\u683c\u6c0f\u8bd5\u5242\u2014\u2014\u7684\u53d1\u73b0\u8005\uff0c\u6cd5\u56fd\u5316\u5b66\u5bb6\u683c\u6797\u5c3c\u4e9a\uff08V. Grignard\uff09\uff0c\u5c31\u83b7\u5f97\u4e861912\u5e74\u7684\u8bfa\u8d1d\u5c14\u5956\uff1b\u800c1950\u5e74\u7684\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u5219\u9881\u7ed9\u4e86\u53d1\u660eDiels-Alder\u53cd\u5e94\u7684\u4e24\u4f4d\u5316\u5b66\u5bb6\uff08O. Diels\u548cK. Alder\uff09\uff0c\u8be5\u53cd\u5e94\u88ab\u8a89\u4e3a\u5316\u5b66\u53cd\u5e94\u4e2d\u7684\u8499\u5a1c\u4e3d\u838e\uff1b1963\u5e74\u7684\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956Ziegler-Natta\u50ac\u5316\u5242\u7684\u53d1\u660e\u8005K. Ziegler\u548cG. Natta\u7684\u5de5\u4f5c\uff0c\u4f7f\u5f97\u805a\u4e19\u70ef\u6750\u6599\u5f97\u4ee5\u5546\u54c1\u5316\uff08\u4f8b\u5982\u73b0\u5728\u5e02\u573a\u7d27\u4fcf\u7684\u4e50\u6263\u724c\u5851\u6599\u5236\u54c1\uff09\u3002\u4ed6\u4eec\u7684\u5de5\u4f5c\uff0c\u753b\u5728\u7eb8\u4e0a\uff0c\u90fd\u65e0\u975e\u662f\u78b3-\u78b3\u952e\u7684\u5f62\u6210\u3002\u4eca\u5e74\u7684\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u4e5f\u4e0d\u4f8b\u5916\u2014\u2014\u5b83\u5728\u73b0\u4ee3\u5de5\u4e1a\u4e2d\u7684\u91cd\u8981\u6027\u751a\u81f3\u8d85\u8fc7\u4e86\u4e0a\u8ff0\u5de5\u4f5c\u7684\u610f\u4e49\u3002\u4ee5\u83b7\u5956\u8005\u547d\u540d\u7684\u4e09\u4e2a\u53cd\u5e94\uff1aHeck\u53cd\u5e94\u3001Negishi\uff08\u6839\u5cb8\uff09\u53cd\u5e94\u548cSuzuki\uff08\u94c3\u6728\uff09\u53cd\u5e94\u51e0\u4e4e\u89e6\u53ca\u5230\u4e86\u5f53\u4eca\u5316\u5b66\u5305\u62ec\u65b0\u836f\u5408\u6210\u3001\u65b0\u6750\u6599\u3001\u6709\u673a\u5149\u7535\u663e\u793a\u7b49\u7684\u6240\u6709\u7814\u7a76\u9886\u57df\uff0c\u4e0e\u666e\u7f57\u5927\u4f17\u7684\u5065\u5eb7\u548c\u751f\u6d3b\u8d28\u91cf\u7684\u63d0\u9ad8\u606f\u606f\u76f8\u5173\u3002<\/p>\n<p>\u83b7\u5f97\u8bfa\u8d1d\u5c14\u5956\u7684\u78b3-\u78b3\u6210\u952e\u53cd\u5e94\uff0c\u77a7\u77a7\u6a2a\u7ebf\u753b\u5728\u54ea\u513f\uff1a<\/p>\n<p><div id=\"attachment_1617\" style=\"width: 310px\" class=\"wp-caption alignnone\"><a href=\"http:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/grignard.png\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-1617\" data-attachment-id=\"1617\" data-permalink=\"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/1610\/grignard\" data-orig-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/grignard.png\" data-orig-size=\"1934,261\" data-comments-opened=\"1\" data-image-meta=\"{&quot;aperture&quot;:&quot;0&quot;,&quot;credit&quot;:&quot;&quot;,&quot;camera&quot;:&quot;&quot;,&quot;caption&quot;:&quot;&quot;,&quot;created_timestamp&quot;:&quot;0&quot;,&quot;copyright&quot;:&quot;&quot;,&quot;focal_length&quot;:&quot;0&quot;,&quot;iso&quot;:&quot;0&quot;,&quot;shutter_speed&quot;:&quot;0&quot;,&quot;title&quot;:&quot;&quot;}\" data-image-title=\"\u683c\u6c0f\u8bd5\u5242\" data-image-description=\"\" data-image-caption=\"&lt;p&gt;\u683c\u6c0f\u53cd\u5e94&lt;\/p&gt;\n\" data-large-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/grignard-1024x138.png\" src=\"http:\/\/www.andrewsun.net\/xiangge\/wp-content\/uploads\/2010\/10\/grignard-300x40.png\" alt=\"\u683c\u6c0f\u8bd5\u5242\" title=\"\u683c\u6c0f\u8bd5\u5242\" width=\"300\" height=\"40\" class=\"size-medium wp-image-1617\" srcset=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/grignard-300x40.png 300w, https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/grignard-1024x138.png 1024w, https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/grignard.png 1934w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><p id=\"caption-attachment-1617\" class=\"wp-caption-text\">\u683c\u6c0f\u53cd\u5e94\uff0c1912\u5e74<\/p><\/div><br \/>\n<div style=\"width: 299px\" class=\"wp-caption alignnone\"><a href=\"http:\/\/upload.wikimedia.org\/wikipedia\/commons\/7\/7f\/Diels-alder_(1,3-butadiene_-_Ethylene).png\"><img loading=\"lazy\" decoding=\"async\" alt=\"Diels-Alder\u53cd\u5e94\" src=\"http:\/\/upload.wikimedia.org\/wikipedia\/commons\/7\/7f\/Diels-alder_(1,3-butadiene_-_Ethylene).png\" title=\"Diels-Alder\u53cd\u5e94\" width=\"289\" height=\"91\" \/><\/a><p class=\"wp-caption-text\">Diels-Alder\u53cd\u5e94\uff0c1950\u5e74<\/p><\/div><br \/>\n<div style=\"width: 351px\" class=\"wp-caption alignnone\"><a href=\"http:\/\/openlearn.open.ac.uk\/file.php\/2937\/!via\/oucontent\/course\/223\/t838_1_i017i.jpg\"><img loading=\"lazy\" decoding=\"async\" alt=\"Ziegler-Natta\u50ac\u5316\" src=\"http:\/\/openlearn.open.ac.uk\/file.php\/2937\/!via\/oucontent\/course\/223\/t838_1_i017i.jpg\" title=\"Ziegler-Natta\u50ac\u5316\" width=\"341\" height=\"329\" \/><\/a><p class=\"wp-caption-text\">Ziegler-Natta\u50ac\u5316\uff0c1963\u5e74<\/p><\/div><br \/>\n<div id=\"attachment_1618\" style=\"width: 310px\" class=\"wp-caption alignnone\"><a href=\"http:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/Mizoroki-Heck-Reaction.png\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-1618\" data-attachment-id=\"1618\" data-permalink=\"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/1610\/mizoroki-heck-reaction\" data-orig-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/Mizoroki-Heck-Reaction.png\" data-orig-size=\"2531,449\" data-comments-opened=\"1\" data-image-meta=\"{&quot;aperture&quot;:&quot;0&quot;,&quot;credit&quot;:&quot;&quot;,&quot;camera&quot;:&quot;&quot;,&quot;caption&quot;:&quot;&quot;,&quot;created_timestamp&quot;:&quot;0&quot;,&quot;copyright&quot;:&quot;&quot;,&quot;focal_length&quot;:&quot;0&quot;,&quot;iso&quot;:&quot;0&quot;,&quot;shutter_speed&quot;:&quot;0&quot;,&quot;title&quot;:&quot;&quot;}\" data-image-title=\"Heck\u53cd\u5e94\" data-image-description=\"\" data-image-caption=\"&lt;p&gt;Heck\u53cd\u5e94\uff0c2010\u5e74&lt;\/p&gt;\n\" data-large-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/Mizoroki-Heck-Reaction-1024x181.png\" src=\"http:\/\/www.andrewsun.net\/xiangge\/wp-content\/uploads\/2010\/10\/Mizoroki-Heck-Reaction-300x53.png\" alt=\"Heck\u53cd\u5e94\" title=\"Heck\u53cd\u5e94\" width=\"300\" height=\"53\" class=\"size-medium wp-image-1618\" srcset=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/Mizoroki-Heck-Reaction-300x53.png 300w, https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/Mizoroki-Heck-Reaction-1024x181.png 1024w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><p id=\"caption-attachment-1618\" class=\"wp-caption-text\">Heck\u53cd\u5e94\uff0c2010\u5e74<\/p><\/div><\/p>\n<h3>\u7eaa\u5ff5\u6c9f\u5415\u6728\u52c9\uff08Tsutomu Mizorok\uff09<\/h3>\n<div style=\"width: 593px\" class=\"wp-caption alignnone\"><a href=\"http:\/\/www.alchemywebsite.com\/images\/fettes.jpg\"><img loading=\"lazy\" decoding=\"async\" alt=\"\u70bc\u91d1\u5e08\" src=\"http:\/\/www.alchemywebsite.com\/images\/fettes.jpg\" title=\"\u70bc\u91d1\u5e08\" width=\"583\" height=\"753\" \/><\/a><p class=\"wp-caption-text\">19\u4e16\u7eaa\u6cb9\u753b\u300a\u70bc\u91d1\u5e08\u300b\u3002\u5316\u5b66\u5bb6\u7684\u5bc2\u5bde\u548c\u8d21\u732e\u90fd\u5f88\u5927\u3002<\/p><\/div>\n<p>\u683c\u6c0f\u8bd5\u5242\u3001Diels-Alder\u53cd\u5e94\u3001Ziegler-Natta\u50ac\u5316\u5242\u3001Heck\u53cd\u5e94\u3001Suzuki\u53cd\u5e94\u2026\u2026\u6240\u6709\u8fd9\u4e9b\u6709\u673a\u5408\u6210\u7684\u8bfa\u8d1d\u5c14\u5956\u5f97\u4e3b\u7684\u540d\u5b57\u4e5f\u540c\u65f6\u6210\u4e3a\u4e86\u4ed6\u4eec\u53d1\u73b0\u7684\u5316\u5b66\u53cd\u5e94\u7684\u540d\u5b57\u3002\u4e00\u672c\u539a\u539a\u7684\u201c\u4eba\u540d\u53cd\u5e94\u201d\u624b\u518c\u662f\u6240\u6709\u6709\u673a\u5316\u5b66\u7814\u7a76\u751f\u5fc5\u5907\u7684\u53c2\u8003\u4e66\uff0c\u73b0\u5728\u751a\u81f3\u8fd8\u6709\u4eba\u540d\u53cd\u5e94\u901f\u67e5\u7684iPhone\u8f6f\u4ef6\u3002\u7528\u4eba\u540d\u6765\u547d\u540d\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u7814\u7a76\u5708\u5b50\u7684\u4e00\u4e2a\u72ec\u7279\u73b0\u8c61\u3002\u6ca1\u4eba\u8003\u7a76\u8fc7\u8fd9\u4e00\u4f20\u7edf\u662f\u5982\u4f55\u5f62\u6210\u7684\uff0c\u4f46\u662f\u53ef\u4ee5\u60f3\u8c61\uff0c\u9ebb\u70e6\u7684\u53cd\u5e94\uff0c\u5f88\u5feb\u4f1a\u88ab\u540e\u4eba\u5fd8\u5374\uff1b\u800c\u90a3\u4e9b\u975e\u5e38\u53d7\u6b22\u8fce\u7684\u53cd\u5e94\uff0c\u5219\u4e00\u5b9a\u4f1a\u88ab\u7ecf\u5e38\u63d0\u8d77\u3002\u7528\u4e00\u4e2a\u540d\u5b57\u6765\u4ee3\u66ff\uff0c\u603b\u6bd4\u6bcf\u6b21\u90fd\u4ece\u53cd\u5e94\u7269\u5230\u4ea7\u7269\u63cf\u8ff0\u4e00\u904d\u6765\u5f97\u7b80\u5355\u591a\u4e86\u3002\u81f3\u4e8e\u4f7f\u7528\u53cd\u5e94\u7684\u53d1\u73b0\u8005\u6765\u547d\u540d\uff0c\u4e5f\u662f\u51fa\u4e8e\u5c0a\u91cd\u524d\u4eba\u52b3\u52a8\u3002\u4e45\u800c\u4e45\u4e4b\uff0c\u4eba\u540d\u53cd\u5e94\u5b9e\u9645\u4e0a\u5c31\u53d8\u6210\u4e86\u6709\u673a\u5408\u6210\u5316\u5b66\u5bb6\u7684\u5b9e\u7528\u201c\u5de5\u5177\u7bb1\u201d\uff0c\u7559\u4e0b\u6765\u7684\u5168\u662f\u7cbe\u534e\u3002<\/p>\n<p>2010\u5e74\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u5f97\u4e3b\u4e4b\u4e00R. Heck\u7684\u540d\u5b57\u4e5f\u88ab\u7528\u4e8e\u4ed6\u53d1\u73b0\u7684\u53cd\u5e94\u4e86\u3002\u9664\u4e86\u53eb\u201cHeck\u53cd\u5e94\u201d\u4e4b\u5916\uff0c\u4e5f\u6709\u76f8\u5f53\u4e00\u90e8\u5206\u4eba\u7528\u201cMizoroki-Heck\u53cd\u5e94\u201d\u3002\u8fd9\u4e2aMizoroki\u662f\u4e00\u4f4d\u65e5\u672c\u4eba\u7684\u540d\u5b57\uff08Tsutomu Mizoroki\uff0c\u6c9f\u5415\u6728\u52c9\uff09\u3002<\/p>\n<div id=\"attachment_1625\" style=\"width: 310px\" class=\"wp-caption alignnone\"><a href=\"http:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/periodic-table.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-1625\" data-attachment-id=\"1625\" data-permalink=\"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/1610\/periodic-table\" data-orig-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/periodic-table.jpg\" data-orig-size=\"1161,688\" data-comments-opened=\"1\" data-image-meta=\"{&quot;aperture&quot;:&quot;0&quot;,&quot;credit&quot;:&quot;&quot;,&quot;camera&quot;:&quot;&quot;,&quot;caption&quot;:&quot;&quot;,&quot;created_timestamp&quot;:&quot;0&quot;,&quot;copyright&quot;:&quot;&quot;,&quot;focal_length&quot;:&quot;0&quot;,&quot;iso&quot;:&quot;0&quot;,&quot;shutter_speed&quot;:&quot;0&quot;,&quot;title&quot;:&quot;&quot;}\" data-image-title=\"\u5143\u7d20\u5468\u671f\u8868\" data-image-description=\"\" data-image-caption=\"&lt;p&gt;\u5143\u7d20\u5468\u671f\u8868&lt;\/p&gt;\n\" data-large-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/periodic-table-1024x606.jpg\" src=\"http:\/\/www.andrewsun.net\/xiangge\/wp-content\/uploads\/2010\/10\/periodic-table-300x177.jpg\" alt=\"\u5143\u7d20\u5468\u671f\u8868\" title=\"\u5143\u7d20\u5468\u671f\u8868\" width=\"300\" height=\"177\" class=\"size-medium wp-image-1625\" srcset=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/periodic-table-300x177.jpg 300w, https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/periodic-table-1024x606.jpg 1024w, https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/periodic-table.jpg 1161w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><p id=\"caption-attachment-1625\" class=\"wp-caption-text\">\u5143\u7d20\u5468\u671f\u8868<\/p><\/div>\n<p>R. Heck\u5728\u4e0a\u4e16\u7eaa\u7684\u516d\u5341\u5e74\u4ee3\u5728\u7f8e\u56fdHercules\u516c\u53f8\u8fdb\u884c\u7814\u7a76\u5de5\u4f5c\u3002\u4ed6\u957f\u671f\u5bf9\u5c11\u4eba\u95ee\u6d25\u7684\u8fc7\u6e21\u6001\u91d1\u5c5e\uff08\u5c31\u662f\u5143\u7d20\u5468\u671f\u8868\u4e2d\u95f4\u9ec4\u8272\u7684\u90a3\u90a3\u5806\u5143\u7d20\uff09\u5341\u5206\u611f\u5174\u8da3\u30021968\u5e74\uff0cHeck\u5728\u7f8e\u56fd\u5316\u5b66\u5b66\u4f1a\u4f1a\u520a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u901a\u8fc7\u94af\u50ac\u5316\u5242\u7684\u8f85\u52a9\u5f62\u6210\u78b3-\u78b3\u952e\u7684\u8bba\u6587\uff08<i>J. Am. Chem. Soc.<\/i> <b>1968<\/b>, <i>90<\/i>, 5518\u20135526\uff09\uff0c\u4f46\u662f\u5728\u8fd9\u7bc7\u8bba\u6587\u91cc\u7684\u4f8b\u5b50\u4e2d\uff0c\u4f7f\u7528\u5230\u4e86\u542b\u6c5e\u548c\u9521\u7684\u5316\u5408\u7269\uff08\u6709\u6bd2\uff09\uff0c\u800c\u4e14\u9700\u8981\u8f83\u5927\u91cf\u7684\u94af\uff08\u6602\u8d35\uff09\uff0c\u56e0\u6b64\u867d\u7136\u8be5\u53cd\u5e94\u5341\u5206\u5e72\u51c0\u5229\u843d\u4f46\u8fd8\u662f\u4e0d\u5c3d\u4eba\u610f\u3002<\/p>\n<p>\u65f6\u9694\u4e24\u5e74\uff0c\u5927\u6d0b\u5f7c\u5cb8\u7684\u65e5\u672c\u4e1c\u4eac\u5de5\u4e1a\u5927\u5b66\u7684\u526f\u6559\u6388\u6c9f\u5415\u6728\u52c9\u5728\u65e5\u672c\u5316\u5b66\u4f1a\u5fd7\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u8bba\u6587\uff08<i>Bull. Chem. Soc. Jpn.<\/i> <b>1971<\/b>, <i>44<\/i>, 581\uff09\uff0c\u65e2\u907f\u514d\u4e86\u6c5e\u5316\u5408\u7269\u7684\u4f7f\u7528\uff0c\u53c8\u5927\u5927\u964d\u4f4e\u4e86\u94af\u7684\u7528\u91cf\uff0c\u6210\u4e3a\u4e86Heck\u53cd\u5e94\u7684\u7b2c\u4e00\u4e2a\u5b8c\u7f8e\u7684\u8303\u4f8b\uff0c\u4e5f\u662f\u76f4\u5230\u4eca\u5929\u4e00\u76f4\u88ab\u4f7f\u7528\u7684\u7248\u672c\u3002\u56e0\u6b64\uff0c\u4ece\u67d0\u79cd\u610f\u4e49\u4e0a\u8bf4\uff0cHeck\u53cd\u5e94\u7684\u6210\u529f\u662f\u6c9f\u5415\u6728\u52c9\u5b9e\u73b0\u7684\uff0c\u79f0\u4e3aMizoroki-Heck\u53cd\u5e94\u5f53\u4e4b\u65e0\u6127\u3002\u5c3d\u7ba1R. Heck\u5728\u6b64\u540e\u53d1\u8868\u7684\u6587\u7ae0\u4e2d\u90fd\u8bda\u5b9e\u5730\u5f15\u7528\u4e86\u6c9f\u5415\u6728\u52c9\u7684\u5de5\u4f5c\uff0c\u7136\u800c\u5728\u5f53\u65f6\uff0c\u8fd8\u662fHeck\u7684\u540d\u5b57\u660e\u663e\u66f4\u52a0\u54cd\u91cf\u3002\u76f4\u523090\u5e74\u4ee3\uff0c\u65e5\u672c\u5316\u5b66\u5bb6\u8fbb\u6b21\u90ce\u5728\u7f16\u5199\u4e00\u672c\u5173\u4e8e\u94af\u50ac\u5316\u53cd\u5e94\u7684\u4e13\u8457\u65f6\uff0c\u91c7\u7528\u4e86\u201cMizoroki-Heck\u53cd\u5e94\u201d\u7684\u8bf4\u6cd5\u3002\u8fbb\u6b21\u90ce\u89e3\u91ca\u8bf4\uff0c\u5728\u516d\u4e03\u5341\u5e74\u4ee3\uff0c\u300a\u65e5\u672c\u5316\u5b66\u4f1a\u5fd7\u300b\u662f\u4e00\u4e2a\u6bd4\u8f83\u51b7\u95e8\u7684\u671f\u520a\uff0c\u5c3d\u7ba1Heck\u5728\u6b64\u540e\u53d1\u8868\u7684\u8bba\u6587\u4e2d\u90fd\u6ce8\u610f\u5f15\u7528\u4e86\u6c9f\u5415\u6728\u52c9\u7684\u5de5\u4f5c\uff0c\u4f46\u5728\u897f\u65b9\u5316\u5b66\u754c\uff0c\u770b\u8fc7Heck\u8bba\u6587\u7684\u4eba\u8fd8\u662f\u8fdc\u6bd4\u770b\u8fc7\u6c9f\u5415\u6728\u52c9\u8bba\u6587\u7684\u8981\u591a\u5f97\u591a\u3002<\/p>\n<p>\u800c\u6c9f\u5415\u6728\u52c9\u5374\u5728\u8bba\u6587\u53d1\u8868\u76849\u5e74\u4e4b\u540e\uff0c\u8fc7\u65e9\u5730\u6b7b\u4e8e\u80f0\u817a\u764c\u3002<\/p>\n<p>R. Heck\u6b64\u540e\u7684\u4eba\u751f\u4e5f\u5e76\u4e0d\u7f8e\u6ee1\u3002\u5c3d\u7ba1\u81ea\u516b\u5341\u5e74\u4ee3\u8d77\u4ee5Mizoroki-Heck\u53cd\u5e94\u4e3a\u7075\u611f\u7684\u94af\u50ac\u5316\u4ea4\u53c9\u5076\u5408\u53cd\u5e94\u7814\u7a76\u5e7f\u6cdb\u5730\u6210\u4e3a\u70ed\u95e8\uff0c\u4f46Heck\u672c\u4eba\u5374\u7531\u4e8e\u65e0\u6cd5\u7533\u8bf7\u5230\u79d1\u7814\u7ecf\u8d39\uff0c\u4e8e1989\u5e74\u63d0\u65e9\u9000\u51fa\u4e86\u79d1\u7814\u5708\u3002\u5e78\u8fd0\u7684\u662f\uff0c\u4ed6\u4e00\u76f4\u6d3b\u5230\u4e86\u4eca\u5e74\uff0c\u5c3d\u7ba1\u51e0\u4e4e\u6574\u4e2a\u5316\u5b66\u754c\u90fd\u8ba4\u4e3a\u7ed9Heck\u7684\u8bfa\u8d1d\u5c14\u5956\u5316\u5b66\u5956\u9881\u5f97\u592a\u8fdf\u3002<\/p>\n<p>Heck\u8fd9\u6837\u63cf\u8ff0\u5df2\u6545\u540c\u884c\u6c9f\u5415\u6728\u52c9\u7684\u5de5\u4f5c\uff1a<\/p>\n<blockquote>\n<p>\u79f0\u4e3aHeck\u53cd\u5e94\u8fd8\u662fMizoroki-Heck\u53cd\u5e94\u5176\u5b9e\u90fd\u6ca1\u6240\u8c13\u3002\u786e\u5b9e\uff0c\u6c9f\u5415\u6728\u5148\u751f\u9996\u6b21\u53d1\u73b0\u4e86\u8fd9\u4e00\u53cd\u5e94\uff0c\u4f46\u662f\u6211\u4e5f\u6ca1\u843d\u540e\u592a\u591a\uff0c\u5e76\u7ee7\u7eed\u8fdb\u884c\u94af\u50ac\u5316\u53cd\u5e94\u7684\u7814\u7a76\u3002\u800c\u4ed6\u4f3c\u4e4e\u5e76\u6ca1\u6709\u9a6c\u4e0a\u8ba4\u8bc6\u5230\u8fd9\u4e00\u53cd\u5e94\u7684\u4ef7\u503c\u3002<b>\u53ef\u60dc\u4ed6\u53bb\u4e16\u5f97\u592a\u65e9\u4e86\uff0c\u5426\u5219\u4eca\u5929\u8fd9\u4e2a\u53cd\u5e94\u53ef\u80fd\u5c31\u4f1a\u88ab\u76f4\u63a5\u79f0\u4e3aMizoroki\u53cd\u5e94\u3002<\/b><\/p>\n<\/blockquote>\n<p><div id=\"attachment_1628\" style=\"width: 310px\" class=\"wp-caption alignnone\"><a href=\"http:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/heck-jACS.png\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-1628\" data-attachment-id=\"1628\" data-permalink=\"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/1610\/heck-jacs\" data-orig-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/heck-jACS.png\" data-orig-size=\"487,339\" data-comments-opened=\"1\" data-image-meta=\"{&quot;aperture&quot;:&quot;0&quot;,&quot;credit&quot;:&quot;&quot;,&quot;camera&quot;:&quot;&quot;,&quot;caption&quot;:&quot;&quot;,&quot;created_timestamp&quot;:&quot;0&quot;,&quot;copyright&quot;:&quot;&quot;,&quot;focal_length&quot;:&quot;0&quot;,&quot;iso&quot;:&quot;0&quot;,&quot;shutter_speed&quot;:&quot;0&quot;,&quot;title&quot;:&quot;&quot;}\" data-image-title=\"heck jACS\" data-image-description=\"\" data-image-caption=\"&lt;p&gt;R. Heck\u7684\u8bba\u6587&lt;\/p&gt;\n\" data-large-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/heck-jACS.png\" src=\"http:\/\/www.andrewsun.net\/xiangge\/wp-content\/uploads\/2010\/10\/heck-jACS-300x208.png\" alt=\"R. Heck\u7684\u8bba\u6587\" title=\"heck jACS\" width=\"300\" height=\"208\" class=\"size-medium wp-image-1628\" srcset=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/heck-jACS-300x208.png 300w, https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/heck-jACS.png 487w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><p id=\"caption-attachment-1628\" class=\"wp-caption-text\">R. Heck\u7684\u8bba\u6587<\/p><\/div><br \/>\n<div id=\"attachment_1634\" style=\"width: 310px\" class=\"wp-caption alignnone\"><a href=\"http:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/muzoroki.png\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-1634\" data-attachment-id=\"1634\" data-permalink=\"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/1610\/muzoroki\" data-orig-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/muzoroki.png\" data-orig-size=\"906,391\" data-comments-opened=\"1\" data-image-meta=\"{&quot;aperture&quot;:&quot;0&quot;,&quot;credit&quot;:&quot;&quot;,&quot;camera&quot;:&quot;&quot;,&quot;caption&quot;:&quot;&quot;,&quot;created_timestamp&quot;:&quot;0&quot;,&quot;copyright&quot;:&quot;&quot;,&quot;focal_length&quot;:&quot;0&quot;,&quot;iso&quot;:&quot;0&quot;,&quot;shutter_speed&quot;:&quot;0&quot;,&quot;title&quot;:&quot;&quot;}\" data-image-title=\"\u6c9f\u5415\u6728\u52c9\u7684\u8bba\u6587\" data-image-description=\"\" data-image-caption=\"&lt;p&gt;\u6c9f\u5415\u6728\u52c9\u7684\u8bba\u6587&lt;\/p&gt;\n\" data-large-file=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/muzoroki.png\" src=\"http:\/\/www.andrewsun.net\/xiangge\/wp-content\/uploads\/2010\/10\/muzoroki-300x129.png\" alt=\"\u6c9f\u5415\u6728\u52c9\u7684\u8bba\u6587\" title=\"\u6c9f\u5415\u6728\u52c9\u7684\u8bba\u6587\" width=\"300\" height=\"129\" class=\"size-medium wp-image-1634\" srcset=\"https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/muzoroki-300x129.png 300w, https:\/\/www.andrewsun.net\/panta_rhei\/wp-content\/uploads\/2010\/10\/muzoroki.png 906w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><p id=\"caption-attachment-1634\" class=\"wp-caption-text\">\u6c9f\u5415\u6728\u52c9\u7684\u8bba\u6587<\/p><\/div><\/p>\n<!-- kcite active, but no citations found -->\n<\/div> <!-- kcite-section 1610 -->","protected":false},"excerpt":{"rendered":"<p>\u300a\u65b0\u77e5\u5ba2\u300b\u7ea6\u7a3f\uff0c\u52ff\u8f6c\uff01 \u4eca\u5e74\u7684\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u9881\u7ed9\u4e86\u4e09\u4f4d\u4e0e\u94af\u50ac\u5316\u53cd\u5e94\u76f8\u5173\u7684\u4e09\u4f4d\u5316\u5b66\u5bb6\uff1a\u94c3\u6728\u7ae0\uff08Akira Suzuki\uff09\u3001\u6839\u5cb8\u82f1\u4e00\uff08Ei-ichi Negishi\uff09\u548c\u7406\u67e5\u00b7\u8d6b\u514b\uff08Richard F. Heck\uff09\u3002 \u6709\u673a\u5408\u6210\u6709\u591a\u96be\uff1f 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