{"id":1552,"date":"2010-09-22T04:11:53","date_gmt":"2010-09-21T20:11:53","guid":{"rendered":"http:\/\/www.andrewsun.net\/xiangge\/?p=1552"},"modified":"2011-03-20T15:38:24","modified_gmt":"2011-03-20T07:38:24","slug":"%e5%86%99%e5%8d%9a%e5%ae%a2%e7%9a%84%e6%97%b6%e9%97%b4%e9%97%ae%e9%a2%98","status":"publish","type":"post","link":"https:\/\/www.andrewsun.net\/panta_rhei\/archives\/1552","title":{"rendered":"\u5199\u535a\u5ba2\u7684\u65f6\u95f4\u95ee\u9898"},"content":{"rendered":"<div class=\"kcite-section\" kcite-section-id=\"1552\">\n<p>\u5f88\u660e\u663e\u662f\u7531\u4e8e\u4e2a\u4eba\u524d\u9014\u582a\u5fe7\u7684\u7f18\u6545\u6211\u624d\u5f04\u4e86\u4e2a<a href=\"http:\/\/www.andrewsun.net\">\u4e2a\u4eba\u4e3b\u9875<\/a>\u3002\u8fd9\u4e2a\u4e3b\u9875\u662f\u82f1\u6587\u7248\u7684\uff0c\u4e3b\u8981\u4ecb\u7ecd\u6211\u7684\u4e13\u4e1a\uff0c\u4e3a\u4e86\u8ba9\u540c\u884c\u8d4f\u8bc6\u6216\u8005\u9119\u89c6\u6211\u3002\u6211\u575a\u6301\u540c\u884c\u8bc4\u8bae\u7cbe\u795e\uff0c\u5728\u4e13\u4e1a\u65b9\u9762\u53ea\u63a5\u53d7\u540c\u884c\u7684\u9119\u89c6\u3002\u6240\u4ee5\u60f3\u9119\u89c6\u6211\u4f46\u53c8\u4e0d\u662f\u4e13\u5bb6\u7684\u53ef\u7231\u7684\u8349\u6839\u8001\u767e\u59d3\u7f51\u53cb\u4eec\u5c31\u4e0d\u8981\u5230\u90a3\u513f\u53bb\u6c61\u67d3\u4e86\uff0c\u6211\u4f1a\u539a\u989c\u65e0\u803b\u5730\u865a\u4f2a\u5730\u8fdb\u884c\u5220\u5e16\u7684\u3002<\/p>\n<p>\u4e2a\u4eba\u4e3b\u9875\u662f\u7528\u4e07\u80fd\u7684Wordpress\u7cfb\u7edf\u5efa\u7acb\u7684\u3002\u4ee5Page\u4e3a\u4e3b\uff0c\u505a\u6210\u4f20\u7edf\u7f51\u7ad9\u7684\u5f62\u5f0f\uff0c\u4f46\u4e5f\u542b\u6709\u4e00\u4e2aBlog\uff0c\u51c6\u5907\u6e05\u4e00\u8272\u5730\u8ba8\u8bba\u79d1\u5b66\u76f8\u5173\u7684\u8bdd\u9898\uff0c\u4e3b\u8981\u662f\u6d41\u53d8\u5b66\uff08\u867d\u7136<a href=\"http:\/\/www.andrewsun.net\/?p=155\">\u7b2c\u4e00\u7bc7\u6587\u7ae0<\/a>\u662f\u8c08\u4e2d\u56fd\u7684\u201c31%\u527d\u7a83\u201d\u4e8b\u4ef6\uff09<\/p>\n<p>\u65e0\u8bba\u662f\u8fd8\u662f\u4e0d\u662f\u4e13\u5bb6\u90fd\u53ef\u4ee5\u9119\u89c6\u7684\u4e00\u70b9\u5c31\u662f\uff0c\u6211\u7684publication\u4e3a\u96f6\u3002\u6295\u4e86\u4e00\u7bc7Polymer\uff0c\u53ef\u662f\u88abhold\u4e86\u4e24\u4e2a\u591a\u6708\uff08Polymer\u6709\u8fd9\u4e48\u6162\u4e48\uff1f\uff09\u73b0\u5728\u6bd5\u4e1a\u6210\u95ee\u9898\u4e86\uff0c\u8d76\u7d27\u8fd8\u8981\u5199\u4e00\u7bc7\u6295\u4e2a<i>Rheol. 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Network\u793e\u533a\uff0c\u82f1\u8bed\u535a\u5ba2\u5c06\u5728\u6211\u7684\u4e3b\u9875\u548c<a href=\"http:\/\/blogs.nature.com\/andrewsun\">Nature 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Neil\u7684\u7406\u8bba\u6709\u673a\u5316\u5b66\uff0c\u4ee5\u53ca\u4e00\u672c\u73b0\u5728\u6211\u5fd8\u8bb0\u4f5c\u8005\u7684\u6709\u673a\u5408\u6210\u3002\u5f53\u65f6\u6211\u80fd\u627e\u5230\u7684\u5916\u6587\u6559\u6750\u9009\u62e9\u662f\u5f88\u6709\u9650\u7684\uff0c\u5f88\u591a\u540e\u6765\u77e5\u9053\u7684\u7ecf\u5178\u6559\u6750\uff0c\u4e66\u5e97\u4e0d\u662f\u6ca1\u5f97\u5356\u5c31\u662f\u53ea\u6709\u5f88\u8d35\u7684\u5f71\u5370\u7248\uff0c\u800c\u56fe\u4e66\u9986\u5f80\u5f80\u662f\u9605\u89c8\u5ba4\u6709\u90a3\u4e48\u4e00\u672c\uff0c\u80fd\u501f\u51fa\u6765\u7684\u5f00\u67b6\u4e66\u5e93\u662f\u6ca1\u6709\u7684\u3002\u6240\u4ee5\u6211\u6700\u7ec8\u62ff\u6765\u770b\u7684\u6559\u6750\u540e\u6765\u624d\u4e86\u89e3\u5230\u5e76\u975e\u662f\u5bb9\u6613\u8bfb\u7684\uff0c\u4f46\u5f53\u65f6\u6211\u90fd\u5174\u81f4\u52c3\u52c3\u5730\uff08\u4e5f\u4f3c\u61c2\u975e\u61c2\u5730\uff09\u5543\u4e86\u4e0b\u6765\uff0c\u4e8b\u5b9e\u4e0a\u8fd9\u4e9b\u4e66\u5bf9\u6211\u5b9e\u9645\u7684\u5b9e\u9a8c\u5e76\u6ca1\u6709\u76f4\u63a5\u7684\u5e2e\u52a9\u3002\u7855\u58eb\u671f\u95f4\u5f88\u957f\u4e00\u6bb5\u65f6\u95f4\u91cc\uff0c\u6211\u5c31\u50cf\u662f\u6765\u8fd9\u4e2a\u5b66\u6821\u8bfb\u4e66\u7684\uff0c\u4e0d\u662f\u6765\u505a\u5b9e\u9a8c\u7684\u3002 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Chemistry\u3002\u4ece\u8fd9\u672c\u4e66\u91cc\u6211\u9996\u6b21\u63a5\u89e6\u5230\u201c\u6b63\u89c4\u7684\u5316\u5b66\u5b9e\u9a8c\u5ba4\u201d\u7684\u65b9\u65b9\u9762\u9762\uff0c\u5e76\u5c3d\u53ef\u80fd\u7684\u5728\u6211\u8eab\u8fb9\u7684\u73af\u5883\u4e2d\u5b9e\u73b0\u3002\u6211\u4e5f\u662f\u5728\u8fd9\u672c\u4e66\u4e0a\u77e5\u9053\u201c\u5347\u534e\u201d\u8fd9\u79cd\u7eaf\u5316\u65b9\u6cd5\u5177\u4f53\u600e\u4e48\u505a\u3002\u901a\u8fc7\u5347\u5316\u6211\u7684\u5355\u4f53\u7279\u522b\u7eaf\uff0c\u53c8\u52a0\u4e0a\u6309\u8fd9\u672c\u4e66\u63a8\u8350\u7684\u505a\u6cd5\u642d\u7684\u65e0\u6c34\u65e0\u6c27\u53cd\u5e94\u5668\uff0c\u6211\u7855\u58eb\u671f\u95f4\u505a\u7684\u5d4c\u6bb5\u5171\u805a\u7269\u8fd8\u662f\u6bd4\u8f83\u6210\u529f\u7684\u3002\u8fd9\u4e00\u70b9\u4f7f\u5f97\u6211\u867d\u7136\u6ca1\u6709\u5b9e\u73b0\u6211\u6240\u8bf4\u7684\u6240\u8c13\u201c\u73af\u7cca\u7cbe\u5305\u5408\u7269\u201d\uff0c\u4f46\u662f\u5374\u5f97\u5230\u4e86\u4e00\u7cfb\u5217\u5206\u5b50\u91cf\u548c\u5d4c\u6bb5\u7ec4\u6210\u7684\u7a84\u5206\u5e03\u6837\u54c1\u3002\u5728\u7855\u58eb\u7684\u6700\u540e\u4e00\u5e74\u91cc\uff0c\u56e0\u4e3a\u5b9e\u9a8c\u5de5\u4f5c\u91cf\u6709\u70b9\u4e0d\u8db3\uff0c\u6211\u5c31\u53bb\u62ff\u6211\u8fd9\u4e9b\u6837\u54c1\u505a\u4e86\u4e00\u5806DSC\u51d1\u6570\u636e\u3002 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Neils\u7684\u7269\u7406\u6709\u673a\u5316\u5b66\u65f6\uff0c\u6211\u5c31\u61c2\u5f97\u53bb\u56fe\u4e66\u9986\u67e5\u7eb8\u7248\u4e86\uff0c\u6240\u4ee5\u7b97\u662f\u4eb2\u773c\u770b\u8fc7\u201cLewis\u78b1\u201d\u7684\u90a3\u4e00\u4f4dLewis\u3001\u201cBr\u00f8nsted\u9178\u201d\u7684\u90a3\u4f4dBr\u00f8nsted\u7684\u539f\u59cb\u8bba\u6587\u3002\u8fd9\u4e9b\u539f\u59cb\u8bba\u6587\u5bf9\u6211\u89e6\u52a8\u5f88\u5927\uff0c\u6211\u611f\u89c9\u6211\u6e3a\u5c0f\u7684\u4e2a\u4f53\u8ddf\u4eba\u7c7b\u7684\u5386\u53f2\u8054\u7cfb\u4e86\u8d77\u6765\u3002\u81f3\u4e8e\u7855\u58eb\u6bd5\u8bbe\u671f\u95f4\u770b\u5230\u7684Flory\u7b49\u4eba\u7684\u8bba\u6587\u6548\u679c\u5219\u5f88\u5b9e\u9645\uff0c\u4e0d\u4ec5\u8ba9\u6211\u53c8\u75af\u72c2\u5730\u91cd\u65b0\u7ffb\u8d77\u4e86\u300a\u7269\u7406\u5316\u5b66\u300b\u8bfe\u672c\u4e2d\u5173\u4e8e\u70ed\u529b\u5b66\u7684\u53ef\u601c\u7684\u90a3\u51e0\u9875\uff08\u8fd8\u987a\u5e26\u53d1\u73b0\u4e86\u80e1\u82f1\u7248\u4e2d\u7684\u4e00\u4e2a\u5c0f\u9519\u8bef\uff09\uff0c\u8fd8\u8ba9\u6211\u9996\u6b21\u77e5\u9053\u4e86\u7269\u7406\u4e0a\uff08\u5177\u4f53\u5c31\u662f\u70ed\u529b\u5b66\uff09\u7684\u8ba8\u8bba\u8303\u5f0f\uff0c\u5373\u60f3\u8981\u4ece\u7406\u8bba\u4e0a\u7814\u7a76\u4e00\u4e2a\u95ee\u9898\u7684\u51fa\u53d1\u70b9\u3001\u89c2\u70b9\u3002\u6211\u4e0d\u4ec5\u770b\u4e86\u5173\u4e8e\u5d4c\u6bb5\u76f8\u5bb9\u6027\u7684\u70ed\u529b\u5b66\uff0c\u8fd8\u770b\u4e86\u5927\u91cf\u5173\u4e8e\u6eb6\u6db2\u4e2d\u5f62\u6210\u80f6\u675f\u7684\u70ed\u529b\u5b66\u7684\u5185\u5bb9\u3002 \u5177\u4f53\u5bf9\u4e8e\u6211\u505a\u7684\u8fd9\u4e00\u5806DSC\u6570\u636e\uff0c\u6211\u770b\u4e86R. Scott\u6839\u636eFLory-Huggins\u4f3c\u6676\u683c\u6a21\u578b\u5bfc\u51fa\u7684\u4e8c\u7ec4\u5206\u805a\u5408\u7269\u6df7\u5408\u4f53\u7cfb\u7684\u6df7\u5408\u81ea\u7531\u80fd\u8868\u8fbe\u5f0f\uff08J. Chem. Phys. 1949, 17:279\uff09\uff0c\u4ee5\u53caT. Nishi\u7b49\u5411\u6db2\u56fa\u4e24\u76f8\u5171\u5b58\u7684\u63a8\u5e7f\uff08Macromolecules 1975, 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members\u662f\u521a\u8fdb\u5b9e\u9a8c\u5ba4\u9700\u8981\u505a\u7684\u4e00\u4e9b\u767b\u8bb0\uff0c\u8fd8\u6709\u4e00\u4e9b\u89c4\u7ae0\u5236\u5ea6\uff0c\u7136\u540eFacilities\u91cc\u662f\u7ec4\u5185\u7684\u4eea\u5668\u7ba1\u7406\u548c\u57f9\u8bad\u3002\u53ef\u80fdWeitz\u7f51\u7ad9\u6ca1\u6709\u5168\u90e8\u5217\u51fa\uff0c\u53ea\u6709\u6d41\u53d8\u4eea\u4e2d\u5fc3\u548c\u9ad8\u901f\u6444\u50cf\u673a\u7684\u4f7f\u7528\u8bf4\u660e\uff0c\u8fd8\u6709\u516c\u7528\u6253\u5370\u673a\u7b49\u3002\u7b2c\u4e09\u90e8\u5206Techniques and Tutorials\u5219\u662f\u5404\u79cd\u7814\u7a76\u6280\u672f\u7684\u6559\u7a0bPPT\uff0c\u4e5f\u8bb8\u8fd9\u4e9b\u57f9\u8bad\u4e00\u76f4\u90fd\u5728\u505a\uff0c\u4e5f\u8bb8\u4e5f\u53ea\u5269\u4e0b\u8fd9\u4e9bPPT\u4e0b\u8f7d\uff0c\u6ca1\u4eba\u8bb2\u4e86\uff0c\u56e0\u4e3a\u6709\u5f88\u591aPPT\u7684\u4f5c\u8005\uff08\u5982Hans 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Amplitude Oscillatory Shearing, LAOS\uff09\u4e86\uff0c\u5728\u56fd\u5185\u597d\u50cf\u5c31\u5468\u6301\u5174\u8bfe\u9898\u7ec4\u641e\u8fd9\u4e00\u5757\u3002\u672c\u6765\u662f\u4f59\u709c\u4e3b\u8bb2\u7684\uff0c\u4f46\u662f\u53ef\u80fd\u4f59\u709c\u6709\u4e8b\uff0c\u5c31\u7531\u5468\u6301\u5174\u7684\u535a\u58eb\u751f\u8bb2\u3002\u8bf4\u5b9e\u8bdd\uff0c\u6bd5\u7adf\u662f\u5b66\u751f\uff0c\u7406\u89e3\u5f97\u90fd\u4e0d\u6df1\uff0c\u5f88\u591a\u5730\u65b9\u8bb2\u5f97\u4e0d\u597d\u3002\u6211\u7684\u8bfe\u9898\u6070\u597d\u5c31\u662f\u8fd9\u4e00\u5757\u3002\u867d\u7136\u6211\u8fd8\u5728\u505a\u5b9e\u9a8c\uff0c\u6ca1\u6709\u6587\u7ae0\uff0c\u4f46\u662f\u8fd9\u4e00\u9886\u57df\u6211\u4e5f\u5df2\u7ecf\u4e86\u89e3\u5230\u4e86\u6211\u6240\u80fd\u4e86\u89e3\u5230\u7684\u7a0b\u5ea6\u4e86\u3002\u800c\u4e14\u6211\u8fd8\u7ed9\u672c\u79d1\u751f\u79d1\u666e\u8fc7\u8fd9\u4e2a\uff0c\u6240\u4ee5\u6211\u81ea\u4fe1\u5982\u679c\u7531\u6211\u8bb2\u8fd9\u8282\u8bfe\u6211\u4f1a\u8bb2\u5f97\u6bd4\u4ed6\u597d\u3002\u8bb2\u7684\u5185\u5bb9\u4e5f\u8fd8\u6709\u95ee\u9898\uff0c\u90a3\u5c31\u662f\u5bf9\u524d\u4eba\u5de5\u4f5c\u4e0d\u591f\u5c0a\u91cd\u3002ppt\u91cc\u6709\u5f88\u591a\u662f\u5fb7\u56fd\u9a6c\u666e\u6240M. Wilhelm\u7684\u5f00\u521b\u6027\u5de5\u4f5c\uff0c\u6709\u56fe\u6709\u771f\u76f8\u3002\u4f46ppt\u91cc\u9762\u6ca1\u6709\u5f15\uff0c\u8bb2\u7684\u65f6\u5019\u4e5f\u6ca1\u6709\u63d0\uff0c\u4e00\u76f4\u5230\u8bb2\u5b8c\u540e\uff0c\u4f1a\u4e0b\u6709\u4eba\u5728\u903b\u8f91\u7684\u6765\u9f99\u53bb\u8109\u4e0a\u6311\u523a\uff0c\u4e3b\u8bb2\u4eba\u624d\u8bf4\u8fd9\u4e0d\u662f\u4ed6\u7684\u5de5\u4f5c\u3002\u8fd8\u6709\uff0c\u5bf9\u8c10\u6ce2\u5206\u6790\u7684\u201c\u5e94\u529b\u5206\u89e3\u201d\uff08stress decomposition\uff09\u65b9\u6cd5\uff0c\u5e94\u8be5\u662f\u97e9\u56fd\u4ebaCho\u5f00\u521b\u7684\uff0cMIT\u7684McKinley\u8bfe\u9898\u7ec4\u4f5c\u4e86\u91cd\u8981\u7684\u6539\u8fdb\uff0c\u628a\u539f\u6765\u4f7f\u7528\u4e0d\u6b63\u4ea4\u7684\u5e42\u7ea7\u6570\uff0c\u6539\u7528\u6b63\u4ea4\u7684Chebyshev\u591a\u9879\u5f0f\u3002\u5468\u6301\u5174\u8bfe\u9898\u7ec4\u7684\u4f59\u709c\u6700\u8fd1\u53c8\u4f5c\u4e86\u91cd\u8981\u53d1\u5c55\uff0c\u628a\u672c\u6765\u5947\u5bf9\u79f0\u7684\u5047\u8bbe\u63a8\u5e7f\u5230\u4e00\u822c\u7684\u60c5\u51b5\uff0c\u628a\u5076\u6b21\u8c10\u6ce2\u4e5f\u7eb3\u5165\u5230\u7814\u7a76\u5bf9\u8c61\u7684\u8303\u56f4\uff0c\u79f0\u4e4b\u4e3a\u201c\u5e7f\u4e49\u5e94\u529b\u5206\u89e3\u201d\uff08general SD\uff09\uff0c\u6211\u770b\u5230\u8fd9\u91cc\u5e94\u529b\u5206\u89e3\u8fd9\u4e2a\u65b9\u6cd5\u7b97\u662f\u5dee\u4e0d\u591a\u4e86\u3002\u5de5\u4f5c\u662f\u5f88\u6f02\u4eae\u7684\uff0c\u4f46\u662f\u4e3b\u8bb2\u4eba\u5728\u4ecb\u7ecd\u8fd9\u4e00\u65b9\u6cd5\u7684\u65f6\u5019\uff0c\u8bf4\u5e94\u529b\u5206\u89e3\u662f\u7531\u4f59\u709c\u8001\u5e08\u72ec\u521b\u7684\uff0c\u8fd9\u5c31\u5bf9Cho\u6709\u70b9\u4e0d\u516c\u5e73\u4e86\u3002\u81f3\u5c11\u5e94\u8be5\u8bf4\u201c\u5e7f\u4e49\u5e94\u529b\u5206\u89e3\u201d\u662f\u4f59\u709c\u8001\u5e08\u72ec\u521b\u7684\u3002\u5176\u5b9e\u8981\u8bf4\u5230\u72ec\u521b\uff0c\u6700\u5148\u60f3\u5230\u5206\u89e3\u7684Cho\u624d\u53eb\u72ec\u521b\u3002Cho\u5173\u4e8e\u5e94\u529b\u5206\u89e3\u7684\u6587\u7ae0\u53ea\u6709\u4e24\u7bc7\uff0c\u4e00\u7bc7\u662fJ. Rheol\u4e0a\u7684\uff0c\u4e00\u7bc7\u662fKorea-Austr. Rheol. J.\u4e0a\u7684\uff0c\u4fe1\u606f\u975e\u5e38\u5c11\uff0c\u4e3a\u4e86\u5b66\u4e60\u548c\u5b9e\u8df5\uff0c\u6211\u90fd\u5feb\u628a\u8fd9\u4e24\u7bc7Paper\u8bfb\u70c2\u4e86\u3002\u800cMcKinley\u8bfe\u9898\u7ec4\u7684\u5de5\u4f5c\u7684\u53ef\u656c\u4e4b\u5904\u5728\u4e8e\u4ee5\u540e\u6765\u5b66\u4e60\u8005\u7684\u89d2\u5ea6\u89e3\u91ca\u4e86\u5f88\u591a\u95ee\u9898\uff0c\u5305\u62ec\u5982\u4f55\u5728\u6d41\u53d8\u4eea\u8f6f\u4ef6\u4e0a\u5b9e\u73b0\u7684\u95ee\u9898\uff0c\u4ee5\u53ca\u5176\u4e0eM. 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